Citation: Geng GUO, Juan LI, Ya WU, Wen-Min DING, Shu-Zhen ZHANG, Yin-Xia SUN. Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1113-1124. doi: 10.11862/CJIC.2021.124 shu

Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: Yin-Xia SUN, sun_yinxia@163.com
Received Date: 30 September 2020
Revised Date: 19 March 2021

Figures(7)

Mononuclear Zn²⁺, Co²⁺ complexes and binuclear Ni²⁺ complex based on coumarin Schiff base ligands, [Zn(L¹)₂] (1) (HL¹=6-((4-diethylamino-2-hydroxy-benzylidene)-amino)-benzopyran-2-one), [Co(L²)₂] (2) (HL²=6-((4-methoxy-2-hydroxy-benzylidene)-amino)-benzopyran-2-one) and[Ni₂(L³)₂(CH₃OH)₄] (3) (H₂L³=4-hydroxy-3-((4-methoxy-2-hydroxy-benzylidene)-amino)-benzopyran-2-one), were synthesized and characterized by elemental analysis, IR, UV-Vis, fluorescence spectra and X-ray single crystal diffraction analysis. The crystal structure analysis represents that the complexes 1 and 2 possess mononuclear structure composed of one metal ion (Zn²⁺ or Co²⁺) and two ligand units ((L¹)^- or (L²)^-). Whereas complex 3 had binuclear structure, containing two Ni²⁺ ions, two ligand units (L³)^2- and four coordination methanol molecules. The crystals of complexes 1, 2 and 3 are solved as monoclinic space group C2/c, triclinic space group P1 and triclinic space group P2₁/n, respectively. The spatial configurations of the central metal Zn²⁺ and Co²⁺ ions are four-coordinated tetrahedrons, and the Ni²⁺ ion is six-coordinated twisted octahedrons. In addition, UV-Vis studies demonstrate that the free ligands HL¹ in DMF/H₂O (4:1, V/V) solution and HL² in DMSO/H₂O (4:1, V/V) solution could selectively recognize Hg²⁺ and Zn²⁺, respectively. The detection limits were calculated to be 7.45 and 6.10 μmol·L^-1, respectively. Fluorescence studies indicate that HL² exhibits ability of selective recognition Zn²⁺ against other common cationic including Ag⁺, Ba²⁺, Ca²⁺, Cd²⁺, Cr³⁺, Cu²⁺, Fe³⁺, Mg²⁺, Mn²⁺ and Hg²⁺ in DMSO/H₂O (4:1, V/V), and the detection limit was calculated to be 2.91 μmol·L^-1.
- coumarin Schiff-base,
- transition metal complex,
- crystal structure,
- spectral property
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Self-Assembled Zn2+, Co2+ and Ni2+ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties

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通讯作者: 陈斌, bchen63@163.com

Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties