Citation: HONG Xin, LI Yun-he, GAO Chang, FAN Bo, PANG Yu-ying, ZHANG Dan, TANG Ke. Synthesis of ZSM-5 zeolites with different silica/alumina ratios and their performance in the removal of aniline and pyridine from model fuel through adsorption[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(10): 1184-1192. shu

Synthesis of ZSM-5 zeolites with different silica/alumina ratios and their performance in the removal of aniline and pyridine from model fuel through adsorption

School of Chemical and Environmental Engineering, Liaoning University of Technology, Jinzhou 121001, China

Corresponding author: TANG Ke, tangke0001@163.com
Received Date: 30 May 2018
Revised Date: 14 August 2018

Fund Project: the Liaoning Provincial Natural Science Foundation of China 20180550639The project was supported by the Liaoning Provincial Natural Science Foundation of China (20180550639)

Figures(9)

A series of ZSM-5 zeolites with different silica/alumina ratios were synthesized and characterized by means of XRD, FT-IR, ICP, SEM, NH₃-TPD and N₂ sorption; their performance in the removal of aniline and pyridine from a model fuel through adsorption was then investigated. The results indicated that all the as-synthesized ZSM-5 zeolites have the MFI structure, although the actual silica/alumina ratio in the as-synthesized ZSM-5 zeolites is somewhat lower than that in the corresponding synthesis mixture. As expected, the acid amount of ZSM-5 zeolites decreases with the increase of the silica/alumina ratio. The adsorption denitrogenation performance of ZSM-5(1) and ZSM-5(2) with relatively lower silica/alumina ratios is superior to that of other two zeolite samples; meanwhile, the removal efficiency for pyridine over all ZSM-5 samples is higher than that for aniline. Moreover, adsorption isotherms of aniline and pyridine over ZSM-5(2) accord with the Langmuir-Freundlich adsorption model.
- ZSM-5,
- silica-alumina ratio,
- aniline,
- pyridine,
- model fuel,
- adsorption denitrogenation
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