Citation: YAN Ning, ZHOU An-ning, ZHANG Ya-gang, YANG Zhi-yuan, HE Xin-fu, ZHANG Ya-ting. Morphologic effect of CeO₂ on the catalytic performance of Ni/CeO₂ in CO methanation[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 466-475. shu

Morphologic effect of CeO₂ on the catalytic performance of Ni/CeO₂ in CO methanation

YAN Ning ¹ ,
ZHOU An-ning ^1,2,, ,
ZHANG Ya-gang ^1,2 ,
YANG Zhi-yuan ^1,2 ,
HE Xin-fu ^1,2 ,
ZHANG Ya-ting ^1,2

1.
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
2.
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Xi'an 710021, China

Corresponding author: ZHOU An-ning, psu564@139.com
Received Date: 30 December 2019
Revised Date: 26 March 2020

Fund Project: the Shaanxi Key Industry Innovation Chain Industrial Field Project 2017ZDCXL-GY-10-01-02The project was supported by the Shaanxi Key Industry Innovation Chain Industrial Field Project (2017ZDCXL-GY-10-01-02)

Figures(10)

CeO₂ supports with different morphologies (including spherical CeO₂-S, bud-shaped CeO₂-F, and polyhedral CeO₂-P) were synthesized and the supported Ni/CeO₂ catalysts were prepared by ammonia-water coordination impregnation method; the effect of CeO₂ morphology on the catalytic performance of Ni/CeO₂ in CO methanation was then investigated. The results indicate that CeO₂-S, CeO₂-F, and CeO₂-P supports are rather different in the exposed crystal planes and oxygen vacancies, which have a significant effect on the catalytic performance of Ni/CeO₂ in CO methanation. In particular, CeO₂-S has the most oxygen vacancies; for CO methanation over the Ni/CeO₂-S catalyst, the conversion of CO and selectivity to CH₄ at 350 ℃ reach 99.19% and 88.88%, respectively. After 10 h thermal stability test, the Ni/CeO₂-S catalyst displays lowest carbon deposit (2.5%); the selectivity to CH₄ over the Ni/CeO₂-S catalyst remains above 80%, which is 1.3 times of that over Ni/CeO₂-F and 17.6 times of that over Ni/CeO₂-P. The excellent catalytic performance of Ni/CeO₂-S may be ascribed to that CeO₂-S support has large surface area and mainly exposes the [111] crystal plane with a large amount of oxygen vacancies, which can enhance the interaction between the support and the active center and alleviate the carbon deposition.
- CO methanation,
- Ni/CeO₂,
- support structure,
- morphology,
- preparation method
1. [1]
  YANG X Z, WANG X, GAO G J, WENDURIMA , LIU E M, SHI Q Q, ZHANG J N, HAN C H, WANG J, LU H L, LIU J, TONG M. Nickel on a macro-mesoporous Al₂O₃@ZrO₂ core/shell nanocomposite as a novel catalyst for CO methanation[J]. Int J Hydrogen Energy, 2013,38(32):13926-13937. doi: 10.1016/j.ijhydene.2013.08.083
2. [2]
  BOESCH F T. Synthesis of reliable networks:A survey[J]. IEEE Trans Reliab, 2007,35(3):240-246.
3. [3]
  GALLETTI C, SPECCHIA S, SARACCO G, SPECCHIA V. Co-selective methanation over Ru-γAl₂O₃ catalysts in H₂-rich gas for PEM-FC applications[J]. Chem Eng Sci, 2008,65(1):590-596.
4. [4]
  TRIMM D, ILSENÖNSAN Z. Onboard fuel conversion for hydrogen-fuel-cell-driven vehicles[J]. Catal Rev, 2000,43(1/2):31-84.
5. [5]
  LI Mao-hua, YANG Bo, LU Yi, LIU Yu-mei. Research advance in methanation catalysts for synthetic natural gas and their catalytic mechanisms[J]. Ind Catal, 2014,22(1):10-24. doi: 10.3969/j.issn.1008-1143.2014.01.002
6. [6]
  AHMAD ZAMANI AB HALIM, RUSMIDAH ALI, WAN AZELEE WAN ABU BAKAR. CO₂/H₂ methanation over M*/Mn/Fe-Al₂O₃ (M*:Pd, Rh, and Ru) catalysts in natural gas; optimization by response surface methodology-central composite design[J]. Clean Technol Environ, 2015,17(3):627-636. doi: 10.1007/s10098-014-0814-8
7. [7]
  LI Chun-qi. Preparation of a novel catalyst of La₂O₃-ZrO₂-Ni/Al₂O₃ and its performance in syngas methanation[J]. Chem Ind Eng Prog, 2019,38(6):2776-2783.
8. [8]
  WANG Hui, ZHANG Jun-feng, BAI Yun-xing, WANG Wen-feng, TAN Yi-sheng, HAN Yi-zhuo. NiO@SiO₂ core-shell catalyst for low-temperature methanation of syngas in slurry reactor[J]. J Fuel Chem Technol, 2016,44(5):548-556. doi: 10.3969/j.issn.0253-2409.2016.05.006
9. [9]
  LE T A, KANG J K, PARK E D. CO and CO₂ methanation over Ni/SiC and Ni/SiO₂ catalysts[J]. Top Catal, 2018,61(15/17):1537-1544.
10. [10]
  HAN Y, WEN B, ZHU M Y, DAI B. Lanthanum incorporated in MCM-41 and its application as a support for a stable Ni-based methanation catalyst[J]. J Rare Earth, 2018,36(4):367-373.
11. [11]
  ZHOU Ting, GUO Fang, XU Jun-qiang, CHEN Zhi, LI Jun, LIU Qi. Research progress in the Ni-based molecular sieve catalysts for the methanation of carbon dioxide[J]. J Funct Mater, 2017,48(6):6029-6033.
12. [12]
  LIN Y, ZHU Y, PAN X, BAO X. Modulating the methanation activity of Ni by the crystal phase of TiO₂[J]. Catal Sci Technol, 2017,7.
13. [13]
  LIU Q, LIAO L, LIU Z, DONG X. Effect of ZrO₂ crystalline phase on the performance of Ni-B/ZrO₂ catalyst for the CO selective methanation[J]. Chin J Chem Eng, 2011,19(3):434-438.
14. [14]
  ZYRYANOVA M M, SNYTNIKOV P V, GULYAEV R V, AMOSOV Y I, BORONIN A I, SOBYANIN V A. Performance of Ni/CeO₂ catalysts for selective CO methanation in hydrogen-rich gas[J]. Chem Eng J, 2014,238:189-197. doi: 10.1016/j.cej.2013.07.034
15. [15]
  ZHANG X, RUI N, JIA X, HU X, LIU C. Effect of decomposition of catalyst precursor on Ni/CeO₂ activity for CO methanation[J]. Chin J Catal, 2019,40(4):495-503. doi: 10.1016/S1872-2067(19)63289-4
16. [16]
  WANG J B, TAI Y L, DOW W P, HUANG T J. Study of ceria-supported nickel catalyst and effect of yttria doping on carbon dioxide reforming of methane[J]. Appl Catal A:Gen, 2001,218(1/2):69-79.
17. [17]
  ODEDAIRO T, CHEN J, ZHU Z. Metal-support interface of a novel Ni-CeO₂ catalyst for dry reforming of methane[J]. Catal Commun, 2013,31(Complete):25-31.
18. [18]
  ZHANG Tao, ZHANG Ya-wen. Research advances on strong metal-support interactions at metal-oxide interfaces and their roles in regulating catalytic properties of noble metal-ceria supported catalysts[J]. J Rare Earth, 2014,32(2):129-142.
19. [19]
  MAI H X, SUN L D, ZHANG Y W, SI R, FENG W, ZHANG H P, LIU H C, YAN C H. Shape-selective synthesis and oxygen storage behavior of ceria nanopolyhedra, nanorods, and nanocubes[J]. J Phys Chem B, 2005,109(51):24380-24385. doi: 10.1021/jp055584b
20. [20]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, BAI Jin, CHEN Lin, LIU Dao sheng. Effect of CeO₂ morphology on the performance of CuO/CeO₂ catalysts for methanol steam reforming[J]. Fine Chem, 2018,35(12):71-77+112.
21. [21]
  LIU Hao-wen, LIU He-fen, YUE Qi, HAN Xiao-yan. Microwave synthesis of butterfly-type superfine CeO₂ and its properties[J]. J South-Cent Univ Natl (Nat Sci Ed), 2016,35(3):17-20.
22. [22]
  LE T A, KIM M S, LEE S H, KIM T W, PARK E D. CO and CO₂ methanation over supported Ni catalysts[J]. Catal Today, 2016,293(4):1-7.
23. [23]
  SHAN W, LUO M, YING P, SHEN W, LI C. Reduction property and catalytic activity of Ce_1-xNi_xO₂ mixed oxide catalysts for CH₄ oxidation[J]. Appl Catal A:Gen, 2003,246(1):1-9. doi: 10.1016/S0926-860X(02)00659-2
24. [24]
  WANG L H, LIU H, LIU Y, CHEN Y, YANG S Q. Effect of precipitants on Ni-CeO₂ catalysts prepared by a co-precipitation method for the reverse water-gas shift reaction[J]. J Rare Earth, 2013,31969. doi: 10.1016/S1002-0721(13)60014-9
25. [25]
  TAN H Y, WANG J, YU S Z, ZHOU K B. Support morphology-dependent catalytic activity of Pd/CeO₂ for formaldehyde oxidation[J]. Environ Sci Technol, 2015,49(14):8675-82. doi: 10.1021/acs.est.5b01264
26. [26]
  GROSVENOR A P, BIESINGER M C, SMART R S C, MCINTYRE N S. New interpretations of XPS spectra of nickel metal and oxides[J]. Surf Sci, 2006,600(9):1771-1779. doi: 10.1016/j.susc.2006.01.041
27. [27]
  ZHANG S, HUANG Z Q, MA Y, GAO W, LI J, CAO F. Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO₂[J]. Nat Commun, 2017,815266. doi: 10.1038/ncomms15266
28. [28]
  HENDERSON M A, PERKINS C L, ENGELHARD M H, THEVUTHASN S, PEDEN C H F. Redox properties of water on the oxidized and reduced surfaces of CeO₂(111)[J]. Surf Sci, 2003,526(1):1-18.
29. [29]
  MCCARTY J G, WISE H. Hydrogenation of surface carbon on alumina-supported nickel[J]. J Catal, 1979,57(3):406-416. doi: 10.1016/0021-9517(79)90007-1
30. [30]
  YANG Xia, TIAN Da-yong, SUN Shou-li, SUN Qi. Effect of CeO₂ on the performance of nickel-based catalysts for methanation[J]. Ind Catal, 2014,22(2):137-143. doi: 10.3969/j.issn.1008-1143.2014.02.012
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Morphologic effect of CeO2 on the catalytic performance of Ni/CeO2 in CO methanation

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Morphologic effect of CeO₂ on the catalytic performance of Ni/CeO₂ in CO methanation