Citation: YU Jie, WANG Jing-yun, WANG Zhen, ZHOU Ming-dong, WANG Hai-yan. Catalytic performance of silicalite-1 modified HY zeolite in the hydrolysis of cellulose[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(12): 1447-1453. shu

Catalytic performance of silicalite-1 modified HY zeolite in the hydrolysis of cellulose

YU Jie ^1,2,3 ,
WANG Jing-yun ² ,
WANG Zhen ² ,
ZHOU Ming-dong ^2,, ,
WANG Hai-yan ^1,2,,

1.
College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China
2.
School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China
3.
Shenyang Paraffin Chemical Co Ltd, Shenyang 110141, China

Corresponding author: ZHOU Ming-dong, haiyanwang@lnpu.edu.cn WANG Hai-yan, haiyanwang@lnpu.edu.cn
Received Date: 29 June 2018
Revised Date: 10 August 2018

Fund Project: the National Science Foundation of China 21101085the Fushun Science & Technology Program FSKJHT 201423Talent Scientific Research Fund of LSHU 2016XJJ-063Natural Science Foundation of Liaoning Province 20170540590Natural Science Foundation of Liaoning Province 2015020196The project was supported by the National Science Foundation of China(21101085), Natural Science Foundation of Liaoning Province(2015020196, 20170540590), the Fushun Science & Technology Program(FSKJHT 201423), the Liaoning Excellent Talents Program in University(LJQ2012031) and Talent Scientific Research Fund of LSHU(2016XJJ-063)the Liaoning Excellent Talents Program in University LJQ2012031

Figures(4)

A core-shell composite zeolite (HY/silicalite-1) was prepared by modifying HY zeolite with silicalite-1 and characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM), N₂ sorption and IR spectra of pyridine adsorption (Py-FTIR); the catalytic performance of HY/silicalite-1 composite zeolite in the hydrolysis of cellulose was then investigated in comparison with that of HY. The results show that the crystallization time has a significant influence on the crystal growth of the HY/silicalite-1 composite zeolite and the relative content of two components. With the optimum crystallization time of 16-24 h, a core-shell structure for the HY/silicalite-1 composite zeolite is achieved, where the silicalite-1 crystal grows over the surface of HY zeolite; with the prolongation of the crystallization time, the morphology of the composite zeolite changes from rough turbid to smooth and eventually to scale-like surface. The amount of Br nsted acid sites decreases first and then increases with the increase of the crystallization time, whereas the amount of Lewis acid sites changes in the opposite direction. In particular, the HY/silicalite-1 composite zeolite obtained with a crystallization time of 24 h exhibits excellent catalytic performance in the hydrolysis of cellulose to glucose; over it, the yield of glucose reaches 45.8% at 130℃, much higher than the value of 28.0% over the HY zeolite.
- composite zeolite,
- silicalite-1,
- HY,
- cellulose,
- hydrolysis,
- crystallization time
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