Citation: QIAO Wei-jun, ZHANG Kai-wen, ZHANG Na, ZHANG Lei, QING Shao-jun, GAO Zhi-xian. Study on CuAl₂O₄ catalytic material for methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(8): 980-985. shu

Study on CuAl₂O₄ catalytic material for methanol steam reforming

1.
Institute of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemical Engineering, Fushun Vocational Technology Institute, Fushun 113122, China
3.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com GAO Zhi-xian, gaozx@sxicc.ac.cn
Received Date: 9 July 2020
Revised Date: 28 July 2020

Fund Project: Scientific Research Funds project of Liaoning Education Department L2019038the National Natural Science Foundation of China 21376237the Natural Science Fund in Liaoning Province 2019-MS-221The project was supported by the National Natural Science Foundation of China (21376237), Scientific Research Funds project of Liaoning Education Department (L2019038), the Natural Science Fund in Liaoning Province (2019-MS-221)

Figures(5)

The CuAl₂O₄ catalytic material was in-situ synthesized using γ-Al₂O₃ as raw material. The catalytic material was characterized by XRF, XRD, BET and H₂-TPR. The effect of the copper-aluminum molar ratios on the structure and properties of CuAl₂O₄ spinel catalytic material and its performance in hydrogen production from methanol steam reforming were investigated. The results show that the copper-aluminum molar ratios affects reduction performance of copper species, which affects its performance in catalyzing methanol steam reforming to produce hydrogen. When the copper-aluminum molar ratios is 1:2, CuAl₂O₄ catalytic material has better catalytic performance. When the reaction temperature is 260℃, with a water-methanol molar ratio of 1.2 and methanol gas hourly space velocity of 800 h^-1, the methanol conversion reaches 100%, the hydrogen production rate is 895 mL/(kg·s).
- CuAl₂O₄,
- methanol steam reforming,
- hydrogen,
- in-situ synthesis
1. [1]
  LIN L, ZHOU W, GAO R, YAO S, ZHANG X, XU W. Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts[J]. Nature, 2017,544(7648):80-83. doi: 10.1038/nature21672
2. [2]
  CLAUDE L. From hydrogen production by water electrolysis to its utilization in a PEM fuel cell or in a SO fuel cell:Some considerations on the energy efficiencies[J]. Int J Hydrogen Energy, 2016,41(34):15415-15425. doi: 10.1016/j.ijhydene.2016.04.173
3. [3]
  HOSSAIN M A, JEWARATNAM J, GANESAN P. Prospect of hydrogen production from oil palm biomass by thermochemical process-A review[J]. Int J Hydrogen Energy, 2016,41(38):16637-16655. doi: 10.1016/j.ijhydene.2016.07.104
4. [4]
  SA S, SILVA H, BRANDAO L, SOUSA J M, MENDES A. Catalysts for methanol steam reforming-A review[J]. Appl Catal B:Environ, 2010,99(1/2):43-57.
5. [5]
  LYTKINA A A, ZHILYAEVA N A, ERMILOVA M M, OREKHOVA N V, YAROSLAVTSEV A B. Influence of the support structure and composition of Ni-Cu-based catalysts on hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy, 2015,40(31):9677-9684. doi: 10.1016/j.ijhydene.2015.05.094
6. [6]
  HE J P, YANG Z X, ZHANG L, LI Y, PAN L W. Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method on γ-Al₂O₃ as catalytic material with high catalytic activity for methanol steam reforming[J]. Int J Hydrogen Energy, 2017,42(15):9930-9937. doi: 10.1016/j.ijhydene.2017.01.229
7. [7]
  CHOI H J, KANG M. Hydrogen production from methanol/water decomposition in a liquid photosystem using the anatase structure of Cu loaded[J]. Int J Hydrogen Energy, 2007,32(16):3841-3848. doi: 10.1016/j.ijhydene.2007.05.011
8. [8]
  SANCHES S G, FLORES J H, DA SILVA M I P. Cu/ZnO and Cu/ZnO/ZrO₂ catalysts used for methanol steam reforming[J]. Mol Catal, 2018,454:55-62. doi: 10.1016/j.mcat.2018.05.012
9. [9]
  DAS D, LLORCA J, DOMINGUEZ M, COLUSSI S, TROVARELLI A, GAYEN A. Methanol steam reforming behavior of copper impregnated over CeO₂-ZrO₂ derived from a surfactant assisted coprecipitation route[J]. Int J Hydrogen Energy, 2015,40(33):10463-10479. doi: 10.1016/j.ijhydene.2015.06.130
10. [10]
  XU T K, ZOU J, TAO W T, ZHANG S Y, CUI L, ZENG F L, WANG D Z, CAI W J. I Co-nanocasting synthesis of Cu based composite oxide and its promoted catalytic activity for methanol steam reforming[J]. Fuel, 2018,183:238-244.
11. [11]
  HUANG Y H, WANG S F, TSAI A P, KAMEOKA S. Catalysts prepared from copper-nickel ferrites for the steam reforming of methanol[J]. J Power Sources, 2015,281:138-145. doi: 10.1016/j.jpowsour.2015.01.168
12. [12]
  QIN Fa-jie, LIU Ya-jie, QING Shao-jun, HOU Xiao-ning, GAO Zhi-xian. Study on Cu-Al spinel slow-release catalyst for methanol-to-hydrogen production the effect of different copper sources[J]. J Fuel Chem Technol, 2017,45(12):84-91.
13. [13]
  XI Hong-juan, LI Guang-jun, QING Shao-jun, HOU Xiao-ning, ZHAO Jin-zhen, LIU Ya-jie, GAO Zhi-xian. Solid-state synthesis of copper-aluminum spinel catalyzed methanol reforming reaction[J]. J Fuel Chem Technol, 2013,41(8):998-1002.
14. [14]
  LI Guang-jun, XI Hong-juan, ZHANG Su-hong, GU Chuan-tao, QING Shao-jun, HOU Xiao-ning, GAO Zhi-xian. Characteristics of spinel CuM₂O₄ (M=Al, Fe, Cr) catalyzed methanol reforming reaction[J]. J Fuel Chem Technol, 2012,40(12):60-65.
15. [15]
  YAHIRO H, NAKAYA K, YAMAMOTO T, SAIKI K, YAMAURA H. Effect of calcination temperature on the catalytic activity of copper supported on γ-alumina for the water-gas-shift reaction[J]. Catal Commun, 2006,7(4):228-231. doi: 10.1016/j.catcom.2005.11.004
16. [16]
  XI H J, HOU X N, LIU Y J, QING S J, GAO Z X. Cu-Al spinel oxide as an efficient catalyst for methanol steam reforming[J]. Angew Chem Int Edit, 2014,126:12080-12083. doi: 10.1002/ange.201405213
17. [17]
  SU Shi-long, ZHANG Lie, ZHANG Yan, LEI Jun-teng, GUI Jian-zhou, LIU Dan, LIU Dao-sheng, PAN Li-wei. Thermodynamic simulation of hydrogen production process from kilowatt PEMFC methanol steam reforming[J]. J Petro Univ, 2015,28(2):21-25.
18. [18]
  YANG S Q, ZHOU F, LIU Y J, ZHANG L, YU C, WANG H H, TIAN Y, ZHANG C S, LIU D S. Morphology effect of ceria on the performance of CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy, 2019,44(14):7252-7261. doi: 10.1016/j.ijhydene.2019.01.254
19. [19]
  YANG Shu-qian, HE Jian-ping, ZHANG Na, SUI Xiao-wei, ZHANG Lie, YANG Zhan-xu. Effect of rare-earth element modification on the performance of Cu/ZnAl catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(2):179-188.
20. [20]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lie, WANG Hong-hao, CHEN Lin, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Effect of carrier roasting atmosphere on CuO/CeO₂ catalyst for methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(8):992-999.
21. [21]
  ZHANG L, PAN L W, NI C J, SUN T J, ZHAO S S, WANG S D, WANG A J, HU Y K. CeO₂-ZrO₂-promoted CuO/ZnO catalyst for methanol steam reforming[J]. Int J Hydrogen Energy, 2013,38(11):4397-4406. doi: 10.1016/j.ijhydene.2013.01.053
22. [22]
  SONG Q L, MEN Y, WANG J G, LIU S, CHAI S S, AN W, WANG K, LI Y Y, TANG Y H. Methanol steam reforming for hydrogen production over ternary composite Zn_yCe₁Zr₉O_x catalysts[J]. Int J Hydrogen Energy, 2020,45(16):9592-9602. doi: 10.1016/j.ijhydene.2020.01.175
1. [1]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
2. [2]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
3. [3]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
4. [4]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
5. [5]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
6. [6]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
7. [7]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
8. [8]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
9. [9]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
10. [10]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
11. [11]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
12. [12]
  Xiaofang Li , Zhigang Wang . Modulating d_z²-orbital occupancy of Au cocatalysts for enhanced photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-. doi: 10.1016/j.actphy.2025.100080
13. [13]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
14. [14]
  Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
15. [15]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
16. [16]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
17. [17]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
18. [18]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
19. [19]
  Sikai Wu , Xuefei Wang , Huogen Yu . Hydroxyl-enriched hydrous tin dioxide-coated BiVO4 with boosted photocatalytic H2O2 production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100457-100457. doi: 10.1016/j.cjsc.2024.100457
20. [20]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1710)
HTML views(286)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Study on CuAl2O4 catalytic material for methanol steam reforming

Metrics

通讯作者: 陈斌, bchen63@163.com

Study on CuAl₂O₄ catalytic material for methanol steam reforming