Citation: YANG Hao, LI Hui-gu, XIE Xing-yue, WANG Qiao, DUAN Yi-ping, HUANG Li-hong. Layered double hydroxide-derived catalyst of Zn-Ni-Al-Fe-O for hydrogen production via auto-thermal reforming of acetic acid[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(11): 1352-1358. shu

Layered double hydroxide-derived catalyst of Zn-Ni-Al-Fe-O for hydrogen production via auto-thermal reforming of acetic acid

College of Materials and Chemistry & Chemical Engineering, Chengdu Univerisity of Technology, Chengdu 610059, China

Corresponding author: LI Hui-gu, 584045893@qq.com HUANG Li-hong, huanglihong06@cdut.cn
Received Date: 20 June 2018
Revised Date: 7 August 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21276031) and the International Cooperation Program Sponsored by the S & T Department of Sichuan Province of China (2015HH0013)the International Cooperation Program Sponsored by the S & T Department of Sichuan Province of China 2015HH0013the National Natural Science Foundation of China 21276031

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Zn_2.4Ni_0.6Al_xFe_1-xO_4.5±δ catalysts were prepared by co-precipitation, tested in auto-thermal reforming (ATR) of HAc, and characterized by XRD, H₂-TPR, BET and XPS. The result showed that the Zn_2.4Ni_0.6Al_0.5Fe_0.5O_4.5±δ catalyst presented a better performance in ATR of HAc. The HAc conversion and hydrogen yield remained at 100% and 2.39 mol-H₂/mol-HAc, respectively. The characterization results indicated that the better performance can be attributed to the addition of Fe, which was helpful to increase surface area and formation of FeNiZn alloy after reduction, while resistance to oxidation and coking was improved as well.
- FeNiZn alloy,
- hydrotalcite-like nickel-based catalyst,
- auto-thermal reforming of acetic acid for hydrogen production
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