Citation: Xin WANG, Meng-Fan WANG, Min-Jie ZHANG, Chen CAO, Zheng NIU, Jian-Ping LANG. Synthesis, Structure, and Luminescence Properties of Coordination Polymers Containing Conjugated Triene Pyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1771-1780. doi: 10.11862/CJIC.2022.197 shu

Synthesis, Structure, and Luminescence Properties of Coordination Polymers Containing Conjugated Triene Pyridine Ligands

Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: Zheng NIU, zhengniu@suda.edu.cn Jian-Ping LANG, jplang@suda.edu.cn
Received Date: 30 April 2022
Revised Date: 23 May 2022

Figures(6)

Solvothermal reactions of the conjugated triene pyridine ligand 1, 6-bis(4-pyridyl)-l, 3, 5-hexatriene (bphte) and Cd salts in the presence of auxiliary carboxylic acid ligands (2, 5-furandicarboxylic acid (2, 5-H₂FDC) and 1, 3, 5-trimesic acid (1, 3, 5-H₃BTC)) gave rise to two coordination polymers [Cd(2, 5-FDC)(bphte)(H₂O)]_n (1) and [Cd(1, 3, 5-HBTC)(bphte)]_n (2), respectively. Both complexes were characterized by elemental analysis, IR, single-crystal X-ray diffraction, powder X - ray diffraction, and thermogravimetric analysis. Complex 1 has a 3D framework with an spl topological structure, while complex 2 holds another 3D architecture formed by bridging 1D [Cd₂(1, 3, 5-HBTC)₂]_n chains via bphte ligands. Both complexes exhibited luminescence emission in the solid state. Complex 2 showed an emission quenching phenomenon in Fe³⁺ aqueous solution, and thus was used as an excellent fluorescence probe to selectively detect Fe³⁺ in water with a low detection limit of 0.013 μmol·L^-1. The above emission quenching mecha-nism is likely due to the overlap between the absorption band of the Fe³⁺ ion and the excitation band of 2.
- coordination polymers,
- conjugated triene pyridine ligand,
- crystal structures,
- luminescent probe
1. [1]
  Barba-Bon A, Costero A M, Gil S, Parra M, Soto J, Martínez-Máñez R, Sancenón F. A New Selective Fluorogenic Probe for Trivalent Cations[J]. Chem. Commun., 2012,48(24):3000-3002. doi: 10.1039/c2cc17184h
2. [2]
  Sorace L, Benelli C, Gatteschi D. Lanthanides in Molecular Magnetism: Old Tools in a New Field[J]. Chem. Soc. Rev., 2011,40(6):3092-3104. doi: 10.1039/c0cs00185f
3. [3]
  Wang H, Wang Y Y, Yang G P, Wang C J, Wen G L, Shi Q Z, Batten S R. A Series of Intriguing Metal-Organic Frameworks with 3, 3', 4, 4'-Benzophenonetetracarboxylic Acid: Structural Adjustment and pH-Dependence[J]. CrystEngComm, 2008,10(11):1583-1594. doi: 10.1039/b805727c
4. [4]
  Chen C, Zhang X L, Gao P, Hu M. A Water Stable Europium Coordi-nation Polymer as Fluorescent Sensor for Detecting Fe³⁺, CrO₄2-, and Cr₂O₇^2- Ions[J]. J. Solid. State. Chem., 2018,258:86-92. doi: 10.1016/j.jssc.2017.10.004
5. [5]
  Zhao T, Hou X D, Xie Y N, Wu L, Wu P. Phosphorescent Sensing of Cr3+ with Protein Functionalized Mn-Doped ZnS Quantum Dots[J]. Analyst, 2013,138(21):6589-6594. doi: 10.1039/c3an01213a
6. [6]
  Xue H, Tang X J, Wu L Z, Zhang L P, Tung C H. Highly Selective Colorimetric and Electrochemical Pb2+ Detection Based on TTF - π -Pyridine Derivatives[J]. J. Org. Chem., 2005,70(24):9727-9734. doi: 10.1021/jo051091r
7. [7]
  Demirel G B, Daglar B, Bayindir M. Extremely Fast and Highly Selective Detection of Nitroaromatic Explosive Vapours Using Fluorescent Polymer Thin Films[J]. Chem. Commun., 2013,49(55):6140-6142. doi: 10.1039/c3cc43202e
8. [8]
  Liu J Q, Luo Z D, Pan Y, Singh A K, Trivedi M, Kumar A. Recent Developments in Luminescent Coordination Polymers: Designing Strategies, Sensing Application and Theoretical Evidences[J]. Coord. Chem. Rev., 2020,406213145. doi: 10.1016/j.ccr.2019.213145
9. [9]
  Wang Y N, Yu J H, Xu J Q. Porous Cd2+ Supramolecular Network Constructed from 2, 3, 5, 6-Pyridinetetracarboxylhydrazide[J]. J. Cluster Sci., 2018,29(4):633-639. doi: 10.1007/s10876-018-1378-2
10. [10]
  Wang Y N, Wang S D, Qi H, Wang W J, Hao X X. Two New Zn2+/Cd2+ Metal-Organic Frameworks(MOFs) Constructed from Asymmet-rical Tricarboxylic Acid Ligands[J]. J. Mol. Struct., 2020,1205127620. doi: 10.1016/j.molstruc.2019.127620
11. [11]
  Wang Y N, Wang R Y, Yang Q F, Yu J H. Acylhydrazidate-Based Porous Coordination Polymers and Reversible I₂ Adsorption Properties[J]. Arab. J. Chem., 2020,13(1):2722-2733. doi: 10.1016/j.arabjc.2018.07.004
12. [12]
  Liang Z B, Qu C, Xia D G, Zou R Q, Xu Q. Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion[J]. Angew. Chem. Int. Ed., 2018,57(31):9604-9633. doi: 10.1002/anie.201800269
13. [13]
  Xie K, Fu Q, Webley P A, Qiao G G. MOF Scaffold for a High-Performance Mixed-Matrix Membrane[J]. Angew. Chem. Int. Ed., 2018,57(28):8597-8602. doi: 10.1002/anie.201804162
14. [14]
  Rosi N L, Eckert J, Eddaoudi M, Vodak D T, Kim J, O'Keeffe M, Yaghi O M. Hydrogen Storage in Microporous Metal-Organic Frameworks[J]. Science, 2003,300(5622):1127-1129. doi: 10.1126/science.1083440
15. [15]
  Li X Y, Ma L N, Liu Y, Hou L, Wang Y Y, Zhu Z H. Honeycomb Metal-Organic Framework with Lewis Acidic and Basic Bifunctional Sites: Selective Adsorption and CO₂ Catalytic Fixation[J]. ACS Appl. Mater. Interfaces, 2018,10(13):10965-10973. doi: 10.1021/acsami.8b01291
16. [16]
  Wilson M, Barrientos P S N, Stevens P C, Mitchell N L, Oswald G, Nagaraja C M, Badyal J P S. Substrate-Independent Epitaxial Growth of the Metal-Organic Framework MOF-508a[J]. ACS Appl. Mater. Interfaces, 2018,10(4):4057-4065. doi: 10.1021/acsami.7b16029
17. [17]
  Chen M M, Zhou X, Li H X, Yang X X, Lang J P. Luminescent Two-Dimensional Coordination Polymer for Selective and Recyclable Sensing of Nitroaromatic Compounds with High Sensitivity in Water[J]. Cryst. Growth Des., 2015,15(6):2753-2760. doi: 10.1021/acs.cgd.5b00095
18. [18]
  Niu Z, Bhagya G W D C, Sun Q, Lan P C, Perman J, Ma J G, Cheng Y C, Aguila B, Ma S Q. Metal -Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis[J]. Chem, 2018,4(11):2587-2599. doi: 10.1016/j.chempr.2018.08.018
19. [19]
  Niu Z, Cui X L, Pham T, Lan P C, Xing H B, Forrest K A, Wojtas L, Space B, Ma S Q. A Metal-Organic Framework Based Methane Nano-Trap for the Capture of Coal-Mine Methane[J]. Angew. Chem. Int. Ed., 2019,58(30):10138-10141. doi: 10.1002/anie.201904507
20. [20]
  Zhang L, Jiang K, Yang L F, Li L B, Hu E L, Yang L, Shao K, Xing H B, Cui Y J, Yang Y, Li B, Chen B L, Qian G D. Benchmark C₂H₂/CO₂ Separation in an Ultra -Microporous Metal-Organic Framework via Copper-Alkynyl Chemistry[J]. Angew. Chem. Int. Ed., 2021,60(29):15995-16002. doi: 10.1002/anie.202102810
21. [21]
  Dong Q B, Zhang X, Liu S, Lin R B, Guo Y, Ma Y, Yonezu A, Krishna R, Liu G P, Duan J G, Matsuda R, Jin W, Chen B L. Tuning Gate-Opening of a Flexible Metal -Organic Framework for Ternary Gas Sieving Separation[J]. Angew. Chem. Int. Ed., 2020,59(50):22756-22762. doi: 10.1002/anie.202011802
22. [22]
  Oveisi M, Asli M A, Mahmoodi N M. MIL-Ti Metal-Organic Frameworks(MOFs) Nanomaterials as Superior Adsorbents: Synthesis and Ultrasound-Aided Dye Adsorption from Multicomponent Wastewater Systems[J]. J. Hazard. Mater., 2018,347:123-140. doi: 10.1016/j.jhazmat.2017.12.057
23. [23]
  Zhang M, Wang L W, Zeng T Y, Shang Q G, Zhou H, Pan Z Q, Cheng Q R. Two Pure MOF -Photocatalysts Readily Prepared for the Degradation of Methylene Blue Dye under Visible Light[J]. Dalton Trans., 2018,47(12):4251-4258. doi: 10.1039/C8DT00156A
24. [24]
  Park J, Oh M. Construction of Flexible Metal-Organic Framework(MOF) Papers through MOF Growth on Filter Paper and Their Selective Dye Capture[J]. Nanoscale, 2017,9(35):12850-12854. doi: 10.1039/C7NR04113F
25. [25]
  Lin R B, Liu S Y, Ye J W, Li X Y, Zhang J P. Photoluminescent Metal-Organic Frameworks for Gas Sensing[J]. Adv. Sci., 2016,3(7)1500434. doi: 10.1002/advs.201500434
26. [26]
  Stassen I, Burtch N, Talin A, Falcaro P, Allendorf M, Ameloot R. An Updated Roadmap for the Integration of Metal-Organic Frameworks with Electronic Devices and Chemical Sensors[J]. Chem. Soc. Rev., 2017,46(11):3185-3241. doi: 10.1039/C7CS00122C
27. [27]
  Xia T F, Cui Y J, Yang Y, Qian G D. A Luminescent Ratiometric Thermometer Based on Thermally Coupled Levels of a Dy-MOF[J]. J. Mater. Chem. C, 2017,5(21):5044-5047. doi: 10.1039/C7TC00921F
28. [28]
  Horcajada P, Chalati T, Serre C, Gillet B, Sebrie C, Baati T, Eubank J F, Heurtaux D, Clayette P, Kreuz C, Chang J S, Hwang Y K, Marsaud V, Bories P N, Cynober L, Gil S, Férey G, Couvreur P, Gref R. Porous Metal-Organic-Framework Nanoscale Carriers as a Potential Platform for Drug Delivery and Imaging[J]. Nat. Mater., 2010,9(2):172-178. doi: 10.1038/nmat2608
29. [29]
  Kumar G, Guda R, Husain A, Bodapati R, Das S K. A Functional Zn Metallacycle Formed from an N-Heterocyclic Carbene Precursor: A Molecular Sensor for Selective Recognition of Fe³⁺ and IO₄-Ions[J]. Inorg. Chem., 2017,56(9):5017-5025. doi: 10.1021/acs.inorgchem.7b00098
30. [30]
  Wu S Y, Min H, Shi W, Cheng P. Multicenter Metal-Organic Framework-Based Ratiometric Fluorescent Sensors[J]. Adv. Mater., 2020,32(3)1805871. doi: 10.1002/adma.201805871
31. [31]
  Guan L L, Jiang Z W, Cui Y J, Yang Y, Yang D R, Qian G D. An MOF-Based Luminescent Sensor Array for Pattern Recognition and Quantification of Metal Ions[J]. Adv. Opt. Mater., 2021,9(9)2002180. doi: 10.1002/adom.202002180
32. [32]
  Zhou X, Shi Y X, Cao C, Ni C Y, Ren Z G, Young D J, Lang J P. Nickel -Based Two-Dimensional Coordination Polymer Displaying Superior Capabilities for Selective Sensing of Cr Ions in Water[J]. Cryst. Growth Des., 2019,19(6):3518-3528. doi: 10.1021/acs.cgd.9b00376
33. [33]
  Čarsky P, Hünig S, Stemmler I, Scheutzow D. Über Zweistufige Redoxsysteme, Ⅹ Ⅹ Ⅶ. Vinyloge Bipyridyle und Bichinolyle; Syn-thesen und UV/Vis-Spektren. Liebigs Ann. Chem., 1980(2): 291 -304
  Čarsky P, Hünig S, Stemmler I, Scheutzow D. On Two-Stage Redox Systems, ⅩⅩⅦ. Vinylogous Bipyridyls and Biquinolyls; Syntheses and UV/Vis Spectra. Liebigs Ann. Chem., 1980(2): 291-304
34. [34]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
35. [35]
  Sheldrick G M. Crystal Structure Refinement with SHELXL[J]. Acta Crystallogr. Sect. C, 2015.
36. [36]
  Pahari G, Bhattacharya B, Reddy C M, Ghoshal D. A Reversible Photochemical Solid-State Transformation in an Interpenetrated 3D Metal-Organic Framework with Mechanical Softness[J]. Chem. Commun., 2019,55(83):12515-12518. doi: 10.1039/C9CC04765D
37. [37]
  Lv R, Wang J Y, Zhang Y P, Li H, Yang L Y, Liao S Y, Gu W, Liu X. An Amino-Decorated Dual-Functional Metal-Organic Framework for Highly Selective Sensing of Cr and Cr Ions and Detection of Nitroaromatic Explosives[J]. J. Mater. Chem. A, 2016,4(40):15494-15500. doi: 10.1039/C6TA05965A
38. [38]
  Wen L L, Zheng X F, Lv K L, Wang C G, Xu X Y. Two Amino-Decorated Metal-Organic Frameworks for Highly Selective and Quantitatively Sensing of Hg and Cr in Aqueous Solution[J]. Inorg. Chem., 2015,54(15):7133-7135. doi: 10.1021/acs.inorgchem.5b00098
39. [39]
  Donges D, Nagle J K, Yersin H. Intraligand Charge Transfer in Pt(qol)₂[J]. Characterization of Electronic States by High-Resolution Shpol'skii Spectroscopy. Inorg. Chem., 1997,36(14):3040-3048.
40. [40]
  Vogler A, Kunkely H. Ligand-to-Ligand and Intraligand Charge Transfer and Their Relation to Charge Transfer Interactions in Organic Zwitterions[J]. Coord. Chem. Rev., 2007,251(3):577-583.
41. [41]
  CHEN H X, LIU C Y, ZHOU X, CHEN M M, NI C Y, LANG J P. One -Dimensional Coordination Polymers Based on a Tripyridine Olefin Ligand: Synthesis, Structures and Photoelectronic Properties[J]. Chinese J. Inorg. Chem., 2019,35(11):2038-2044. doi: 10.11862/CJIC.2019.228
42. [42]
  LIANG C X, LIU Z, LIANG Q Q, TANG Q, LI H Y, ZHANG S F. Syntheses, Crystal Structures and Properties of Bis-Schiff Bases Containing Carboxyl and Their Copper Complexes[J]. Chinese J. Inorg. Chem., 2019,35(7):1130-1138.
43. [43]
  Gu T Y, Dai M, Young D J, Ren Z G, Lang J P. Luminescent Zn Coordination Polymers for Highly Selective Sensing of Cr and Cr in Water[J]. Inorg. Chem., 2017,56(8):4668-4678. doi: 10.1021/acs.inorgchem.7b00311
44. [44]
  Wang J, Lu L, Ding Q J, Zhang S L, Wang J, Singh A, Kumar A, Ma A Q. Multi -Responsive Luminescent 2D Zn-Based Coordination Polymer for Detection of Trinitrophenol and Fe³⁺[J]. J. Coord. Chem., 2020,73(2):307-316. doi: 10.1080/00958972.2020.1720002
45. [45]
  Hu F L, Shi Y X, Chen H H, Lang J P. A Zn Coordination Polymer and Its Photocycloaddition Product: Syntheses, Structures, Selective Luminescence Sensing of Iron Ions and Selective Absorption of Dyes[J]. Dalton Trans., 2015,44(43):18795-18803. doi: 10.1039/C5DT03094C
46. [46]
  Li W X, Gu J H, Li H X, Dai M, Young D J, Li H Y, Lang J P. Post-Synthetic Modification of a Two-Dimensional Metal-Organic Framework via Photodimerization Enables Highly Selective Luminescent Sensing of Aluminum[J]. Inorg. Chem., 2018,57(21):13453-13460. doi: 10.1021/acs.inorgchem.8b02049
47. [47]
  Das D, Biradha K. Luminescent Coordination Polymers of Naphthalene Based Diamide with Rigid and Flexible Dicarboxylates: Sensing of Nitro Explosives, Fe Ion, and Dyes[J]. Cryst. Growth Des., 2018,18(6):3683-3692. doi: 10.1021/acs.cgd.8b00498
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