Citation: Min SHU, Hai-Tao LIU, Sheng PENG, Zhi-Rong WU, Rui ZHANG, Feng LI, Jian LIU. Research Progress of Electrochromic Materials Based on Fe(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1690-1706. doi: 10.11862/CJIC.2022.182 shu

Research Progress of Electrochromic Materials Based on Fe(Ⅱ) Coordination Polymers

Min SHU ¹ ,
Hai-Tao LIU ¹ ,
Sheng PENG ¹ ,
Zhi-Rong WU ¹ ,
Rui ZHANG ¹ ,
Feng LI ^2,, ,
Jian LIU ^1,,

1.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Shandong Penisula Engineering Research Center of Comprehensive Brine Utilization, Weifang University of Science and Technology, Weifang, Shandong 262700, China

Corresponding author: Feng LI, fengli81@163.com Jian LIU, liu.jian@njfu.edu.cn
Received Date: 15 May 2022
Revised Date: 14 July 2022

Figures(26)

Electrochromism is a phenomenon exhibiting color changes under an external electrical stimulus. Electrochromic materials can switch reversibly between different redox and/or oxidation states, resulting in new absorption bands in the visible or near?infrared region. So far, electrochromic materials mainly included transition metal oxides, transition metal coordination polymers, viologens, organic conjugated polymers, and so on. Transition metal coordination polymers-based electrochromic materials possessed the combined advantages of both inorganic materials and organic materials and showed a wide application prospect. Ferric coordination polymers were excellent electrochromic materials with good redox properties and abundant electronic transitions. In this paper, the research progress of electrochromic materials of ferric coordination polymers is reviewed, mainly from the aspects of arm shape, type, and spacer group of organic ligands.
- electrochromic,
- Fe-complex,
- coordination polymer,
- organic ligand
1. [1]
  Fu W A, Chen H J, Han Y Y, Wang W Y, Zhang R, Liu J. Electropolymerization of D-A-D Type Monomers Consisting of Triphenylamine and Substituted Quinoxaline Moieties for Electrochromic Devices[J]. New J. Chem., 2021,45(40):19082-19087. doi: 10.1039/D1NJ04074J
2. [2]
  Chen H J, Wang W Y, Zhu J J, Han Y Y, Liu J. Electropolymerization of D-A Type EDOT-Based Monomers Consisting of Camphor Substituted Quinoxaline Unit for Electrochromism with Enhanced Performance[J]. Polymer, 2022,240124485. doi: 10.1016/j.polymer.2021.124485
3. [3]
  Zhu J J, Wang W Y, Chen H J, Han Y Y, Liu J. Electropolymerization of D - A - D Type Monomers Consisting of Thiophene and Quionaxline Moieties for Electrochromic Devices and Supercapacitors[J]. J. Solid State Chem., 2022,307122739. doi: 10.1016/j.jssc.2021.122739
4. [4]
  Yen H J, Lin K Y, Liou G S. High T_g, Ambipolar, and Near-Infrared Electrochromic Anthraquinone - Based Aramids with Intervalence Charge-Transfer Behavior[J]. J. Polym. Sci. Pol. Chem., 2012,50(1):61-69. doi: 10.1002/pola.24980
5. [5]
  Cong S, Geng F X, Zhao Z G. Tungsten Oxide Materials for Optoelectronic Applications[J]. Adv. Mater., 2016,28(47):10518-10528. doi: 10.1002/adma.201601109
6. [6]
  Guo W B, Cong Z F, Guo Z H, Zhang P P, Chen Y H, Hu W G, Wang Z L, Pu X. Multifunctional Self-Charging Electrochromic Supercapacitors Driven by Direct - Current Triboelectric Nanogenerators[J]. Adv. Funct. Mater., 2021,31(36)2104348. doi: 10.1002/adfm.202104348
7. [7]
  Zhong Y, Chai Z S, Liang Z M, Sun P, Xie W G, Zhao C X, Mai W J. Electrochromic Asymmetric Supercapacitor Windows Enable Direct Determination of Energy Status by the Naked Eye[J]. ACS Appl. Mater. Interfaces, 2017,9(39):34085-34092. doi: 10.1021/acsami.7b10334
8. [8]
  Qu S Q, Guan J, Cai D Q, Wang Q S, Wang X Y, Song W, Ji W. An Electrochromic Ag - Decorated WO_3-x Film with Adjustable Defect States for Electrochemical Surface - Enhanced Raman Spectroscopy[J]. Nanomaterials, 2022,12(10)1637. doi: 10.3390/nano12101637
9. [9]
  Jo M H, Kim K H, Ahn H J. P - Doped Carbon Quantum Dot Graft - Functionalized Amorphous WO₃ for Stable and Flexible Electrochromic Energy-Storage Devices[J]. Chem. Eng. J., 2022,445136826. doi: 10.1016/j.cej.2022.136826
10. [10]
  Wang B S, Huang Y, Han Y, Zhang W S, Zhou C H, Jiang Q Y, Chen F X, Wu X K, Li R, Lyu P, Zhao S M, Wang F, Zhang R F. A Facile Strategy to Construct Au@V_xO₂ _x₊₁ Nanoflowers as a Multicolor Electrochromic Material for Adaptive Camouflage[J]. Nano Lett., 2022,22(9):3713-3720. doi: 10.1021/acs.nanolett.2c00600
11. [11]
  Cai J Y, Yu D B, Zhang Y, Yao S Z, Zhang X R, Cui J W, Wang Y, Liu J Q, Yu C P, Sun X C, Wu Y C. A Facile Synthesis of Porous Amorphous/Crystalline TiO₂ Hybrids for Enhanced Electrochromic Performances[J]. J. Electroanal. Chem., 2022,914116304. doi: 10.1016/j.jelechem.2022.116304
12. [12]
  Cui B B, Yao C J, Yao J N, Zhong Y W. Electropolymerized Films as a Molecular Platform for Volatile Memory Devices with Two Near - Infrared Outputs and Long Retention Time[J]. Chem. Sci., 2014,5(3):932-941. doi: 10.1039/C3SC52815D
13. [13]
  Oka S, Ozawa H, Yoshikawa K, Ikeda T, Haga M. Hydrogen-Bonded Metallo-Supramolecular Polymers Based on Ruthenium or Iron Complexes for the Selective Extraction of Single - Walled Carbon Nanotubes[J]. Dalton Trans., 2018,47(40):14195-14203. doi: 10.1039/C8DT01573B
14. [14]
  Banasz R, Wałęsa - Chorab M. Polymeric Complexes of Transition Metal Ions as Electrochromic Materials: Synthesis and Properties[J]. Coord. Chem. Rev., 2019,389:1-18. doi: 10.1016/j.ccr.2019.03.009
15. [15]
  Li X F, Perera K, He J Z, Gumyusenge A, Mei J G. Solution-Processable Electrochromic Materials and Devices: Roadblocks and Strategies towards Large - Scale Applications[J]. J. Mater. Chem. C, 2019,7:12761-12789. doi: 10.1039/C9TC02861G
16. [16]
  Chen F, Ren Y Y, Guo J N, Yan F. Thermo - and Electro - Dual Responsive Poly(ionic liquid) Electrolyte Based Smart Windows[J]. Chem. Commun., 2017,53(10):1595-1598. doi: 10.1039/C6CC08924K
17. [17]
  Lu H C, Kao S Y, Yu H F, Chang T H, Kung C W, Ho K C. Achieving Low - Energy Driven Viologens - Based Electrochromic Devices Utilizing Polymeric Ionic Liquids[J]. ACS Appl. Mater. Interfaces, 2016,8(44):30351-30361. doi: 10.1021/acsami.6b10152
18. [18]
  Hu C W, Lu H C, Kao S Y, Lee K M, Vittal R, Yu H F, Chen P W, Jan D J, Ho K C. A Transparent-Green-Blue Electrochromic Device Based on 2, 2, 6, 6-Tetramethyl-1-piperidinyloxy (TEMPO), Polyaniline, and HV(BF₄)₂[J]. Sol. Energy Mater. Sol. Cells, 2019,200109993. doi: 10.1016/j.solmat.2019.109993
19. [19]
  Wu W N, Yu H F, Yeh M H, Ho K C. Incorporating Electrospun Nanofibers of TEMPO-Grafted PVDF-HFP Polymer Matrix in Viologen - Based Electrochromic Devices[J]. Sol. Energy Mater. Sol. Cells, 2020,208110375. doi: 10.1016/j.solmat.2019.110375
20. [20]
  Neo W T, Cho C M, Shi Z G, Chua S J, Xu J W. Modulating High-Energy Visible Light Absorption to Attain Neutral-State Black Electrochromic Polymers[J]. J. Mater. Chem. C, 2016,4(1):28-32. doi: 10.1039/C5TC02883C
21. [21]
  Lo C K, Shen D E, Reynolds J R. Fine-Tuning the Color Hue of π-Conjugated Black - to - Clear Electrochromic Random Copolymers[J]. Macromolecules, 2019,52(17):6773-6779. doi: 10.1021/acs.macromol.9b01443
22. [22]
  He J Z, You L Y, Mei J G. Self - Bleaching Behaviors in Black - to - Transmissive Electrochromic Polymer Thin Films[J]. ACS Appl. Mater. Interfaces, 2017,9(39):34122-34130. doi: 10.1021/acsami.7b09140
23. [23]
  Savagian L R, Österholm A M, Shen D E, Christiansen D T, Kuepfert M, Reynolds J R. Conjugated Polymer Blends for High Contrast Black - to - Transmissive Electrochromism[J]. Adv. Opt. Mater., 2018,6(19)1800594. doi: 10.1002/adom.201800594
24. [24]
  Banasz R, Kubicki M, Walesa - Chorab M. Yellow - to - Brown and Yellow - to - Green Electrochromic Devices Based on Complexes of Transition Metal Ions with a Triphenylamine - Based Ligand[J]. Dalton Trans., 2020,49(42):15041-15053. doi: 10.1039/D0DT03232H
25. [25]
  Napierała S, Wałęsa - Chorab M. On - Substrate Postsynthetic Metal Ion Exchange as a Tool for Tuning Electrochromic Properties of Materials[J]. Eur. Polym. J., 2020,140110052. doi: 10.1016/j.eurpolymj.2020.110052
26. [26]
  Napierala S, Kubicki M, Walesa-Chorab M. Toward Electrochromic Metallopolymers: Synthesis and Properties of Polyazomethines Based on Complexes of Transition-Metal Ions[J]. Inorg. Chem., 2021,60(18):14011-14021. doi: 10.1021/acs.inorgchem.1c01249
27. [27]
  Guven N, Sultanova H, Ozer B, Yucel B, Camurlu P. Tuning of Electrochromic Properties of Electrogenerated Polythiophenes through Ru Complex Tethering and Backbone Derivatization[J]. Electrochim. Acta, 2020,329135134. doi: 10.1016/j.electacta.2019.135134
28. [28]
  Mondal S, Yoshida T, Maji S, Ariga K, Higuchi M. Transparent Supercapacitor Display with Redox - Active Metallo - Supramolecular Polymer Films[J]. ACS Appl. Mater. Interfaces, 2020,12(14):16342-16349. doi: 10.1021/acsami.9b23123
29. [29]
  Mondal S, Yoshida T, Rana U, Bera M K, Higuchi M. Thermally Stable Electrochromic Devices Using Fe-Based Metallo-Supramolecular Polymer[J]. Sol. Energy Mater. Sol. Cells, 2019,200110000. doi: 10.1016/j.solmat.2019.110000
30. [30]
  Higuchi M. Stimuli - Responsive Metallo - Supramolecular Polymer Films: Design, Synthesis and Device Fabrication[J]. J. Mater. Chem. C, 2014,2(44):9331-9341. doi: 10.1039/C4TC00689E
31. [31]
  Schott M, Lorrmann H, Szczerba W, Beck M, Kurth D G. State - of - the-Art Electrochromic Materials Based on Metallo-Supramolecular Polymers[J]. Sol. Energy Mater. Sol. Cells, 2014,126:68-73. doi: 10.1016/j.solmat.2014.03.032
32. [32]
  Keisar H, de Ruiter G, Velders A H, Milko P, Gulino A, Evmenenko G, Shimon L J W, Diskin - Posner Y, Lahav M, van der Boom M E. Sorting of Molecular Building Blocks from Solution to Surface[J]. J. Am. Chem. Soc., 2018,140(26):8162-8171. doi: 10.1021/jacs.8b02968
33. [33]
  Yao C J, Zhong Y W, Nie H J, Abruna H D, Yao J N. Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1, 2, 4, 5-Tetra(2-pyridyl)benzene[J]. J. Am. Chem. Soc., 2011,133(51):20720-20723. doi: 10.1021/ja209620p
34. [34]
  Laschuk N O, Ahmad R, Ebralidze I I, Poisson J, Easton E B, Zenkina O V. Multichromic Monolayer Terpyridine - Based Electrochromic Materials[J]. ACS Appl. Mater. Interfaces, 2020,12(37):41749-41757. doi: 10.1021/acsami.0c11478
35. [35]
  Cai G F, Chen J W, Xiong J Q, Eh A L, Wang J X, Higuchi M, Lee P S. Molecular Level Assembly for High-Performance Flexible Electrochromic Energy-Storage Devices[J]. ACS Energy Lett, 2020,5(4):1159-1166. doi: 10.1021/acsenergylett.0c00245
36. [36]
  Roy S, Chakraborty C. Sub - second Electrochromic Switching and Ultra-High Coloration Efficiency in Halloysite Nanoclay Incorporated Metallo - Supramolecular Polymer Nano - Hybrid Based Electrochromic Device[J]. Sol. Energy Mater. Sol. Cells, 2020,208110392. doi: 10.1016/j.solmat.2019.110392
37. [37]
  Malik N, Dov N E, de Ruiter G, Lahav M, van der Boom M E. On - Surface Self - Assembly of Stimuli - Responsive Metallo - Organic Films: Automated Ultrasonic Spray - Coating and Electrochromic Devices[J]. ACS Appl. Mater. Interfaces, 2019,11(25):22858-22868. doi: 10.1021/acsami.9b05512
38. [38]
  Schott M, Szczerba W, Posset U, Vuk A S, Beck M, Riesemeier H, Thunemann A F, Kurth D G. In Operando XAFS Experiments on Flexible Electrochromic Devices Based on Fe(Ⅱ)- Metallo - Supramolecular Polyelectrolytes and Vanadium Oxide[J]. Sol. Energy Mater. Sol. Cells, 2016,147:61-67. doi: 10.1016/j.solmat.2015.10.015
39. [39]
  Shao J Y, Yao C J, Cui B B, Gong Z L, Zhong Y W. Electropolymerized Films of Redox - Active Ruthenium Complexes for Multistate Near - Infrared Electrochromism, Ion Sensing, and Information Storage[J]. Chin. Chem. Lett., 2016,27(8):1105-1114. doi: 10.1016/j.cclet.2016.05.018
40. [40]
  Nie H J, Zhong Y W. Near-Infrared Electrochromism in Electropolymerized Films of a Phen - 1, 4 - diyl - Bridged Diruthenium Complex[J]. Inorg. Chem., 2014,53(20):11316-11322. doi: 10.1021/ic5019967
41. [41]
  Li Z J, Yao C J, Zhong Y W. Near-Infrared Electrochromism of Multilayer Films of a Cyclometalated Diruthenium Complex Prepared by Layer - by - Layer Deposition on Metal Oxide Substrates[J]. Sci. China Chem., 2019,62(12):1675-1685. doi: 10.1007/s11426-019-9640-1
42. [42]
  Bera M K, Chakraborty C, Rana U, Higuchi M. Electrochromic Os(Ⅱ) - Based Metallo-Supramolecular Polymers[J]. Macromol. Rapid Commun., 2018,39(22)1800415. doi: 10.1002/marc.201800415
43. [43]
  Li H F, Zhang L S, Fan X L, Zhao Y. Theoretical Studies on the Redox - Stimulated Isomerization in Electrochromic Osmium Sulfoxide Complexes[J]. J. Phys. Chem. A, 2015,119(18):4244-4251. doi: 10.1021/acs.jpca.5b02134
44. [44]
  Yoshida T, Bera M K, Narayana Y S L V, Mondal S, Abe H, Higuhi M. Electrochromic Os - Based Metallo - Supramolecular Polymers: Electronic State Tracking by In Situ XAFS, IR, and Impedance Spectroscopies[J]. RSC Adv., 2020,10(41):24691-24696. doi: 10.1039/D0RA03236K
45. [45]
  Liu Y R, Sakamoto R, Ho C L, Nishihara H, Wong W Y. Electrochromic Triphenylamine-Based Cobalt Complex Nanosheets[J]. J. Mater. Chem. C, 2019,7(30):9159-9166. doi: 10.1039/C9TC02257K
46. [46]
  Atar A B, Jeong J Y, Kim N, Park J S. Metallo-Supramolecular Polymers Made of Cobalt and 3, 4 - Propylenedioxythiophene - Bisterpyridine Complexes for Electrochromic Applications[J]. Macromol. Res., 2018,26(9):814-818. doi: 10.1007/s13233-018-6107-z
47. [47]
  Laschuk N O, Ebralidze I I, Easton E B, Zenkina O V. Osmium-and Cobalt-Terpyridine-Based Electrochromic Devices for "Smart" Signage Application: The Effect of Lighting on Color Perception[J]. Adv. Electron. Mater., 2021,7(10)2100460. doi: 10.1002/aelm.202100460
48. [48]
  Hossain M D, Sato T, Higuchi M. A Green Copper - Based Metallo - Supramolecular Polymer: Synthesis, Structure, and Electrochromic Properties[J]. Chem. Asian J., 2013,8(1):76-79. doi: 10.1002/asia.201200668
49. [49]
  Kimura M, Yasuta K, Adachi N, Tatewaki Y, Fukawa T, Shirai H. Electrochromic Polymeric Films Derived from (Diphenylamino) phenyl-substituted Metallophthalocyanines[J]. Chem. Lett., 2009,38(1):82-83. doi: 10.1246/cl.2009.82
50. [50]
  Deshmukh M A, Gicevicius M, Ramanaviciene A, Shirsat M D, Viter R, Ramanavicius A. Hybrid Electrochemical/Electrochromic Cu(Ⅱ) Ion Sensor Prototype Based on PANI/ITO-Electrode[J]. Sens. Actuator B-Chem., 2017,248:527-535. doi: 10.1016/j.snb.2017.03.167
51. [51]
  Balgley R, Algavi Y M, Dov N E, Lahav M, van der Boom M E. Light-Triggered Release of Trapped Charges in Molecular Assemblies[J]. Angew. Chem. Int. Ed., 2018,57(41):13459-13464. doi: 10.1002/anie.201807453
52. [52]
  Laschuk N O, Ebralidze I I, Poisson J, Egan J G, Quaranta S, Allan J T S, Cusden H, Gaspari F, Naumkin F Y, Easton E B, Zenkina O V. Ligand Impact on Monolayer Electrochromic Material Properties[J]. ACS Appl. Mater. Interfaces, 2018,10(41):35334-35343. doi: 10.1021/acsami.8b10666
53. [53]
  Qu D W, Liu L W, Li X, Chen K, Zheng Y P, Xue Y M, Chen G M. Fabrication of Metal-Supramolecular Polymers of FeL/Carbon Nanomaterials with Enhanced Electrochromic Properties[J]. Compos. Sci. Technol., 2020,198108252. doi: 10.1016/j.compscitech.2020.108252
54. [54]
  Ionescu A, Lento R, Mastropietro T F, Aiello I, Termine R, Golemme A, Ghedini M, Bellec N, Pini E, Rimoldi I, Godbert N. Electropolymerized Highly Photoconductive Thin Films of Cyclopalladated and Cycloplatinated Complexes[J]. ACS Appl. Mater. Interfaces, 2015,7(7):4019-4028. doi: 10.1021/am506984m
55. [55]
  Higuchi M. Electrochromic Organic-Metallic Hybrid Polymers: Fundamentals and Device Applications[J]. Polym. J., 2009,41(7):511-520. doi: 10.1295/polymj.PJ2009053
56. [56]
  Dov N E, Shankar S, Cohen D, Bendikov T, Rechav K, Shimon L J W, Lahav M, van der Boom M E. Electrochromic Metallo - Organic Nanoscale Films: Fabrication, Color Range, and Devices[J]. J. Am. Chem. Soc., 2017,139(33):11471-11481. doi: 10.1021/jacs.7b04217
57. [57]
  Malik N, Lahav M, van der Boom M E. Electrochromic Metallo - Organic Nanoscale Films: A Molecular Mix and Match Approach to Thermally Robust and Multistate Solid-State Devices[J]. Adv. Electron. Mater, 2020,6(10)2000407. doi: 10.1002/aelm.202000407
58. [58]
  Hamo Y N, Lahav M, van der Boom M E. Bifunctional Nanoscale Assemblies: Multistate Electrochromics Coupled with Charge Trapping and Release[J]. Angew. Chem. Int. Ed., 2020,59(7):2612-2617. doi: 10.1002/anie.201912333
59. [59]
  WANG W Y, CHEN H J, ZHANG G, ZHANG R, LIU J. Synthesis and Properties of Donor - Acceptor Type Electrochromic Materials Based on Triphenylamine and Quinoxaline[J]. Chin. J. Org. Chem., 2020,40(8):2513-2519.
60. [60]
  Ding Z H, Chen H J, Han Y Y, Liu J. Molecular Engineering of π-Extended Viologens Consisting of Quinoxaline - Based Bridges for Tunable Electrochromic Devices[J]. J. Mol. Struct., 2022,1262133073. doi: 10.1016/j.molstruc.2022.133073
61. [61]
  Shankar S, Lahav M, Boom M E. Coordination - Based Molecular Assemblies as Electrochromic Materials: Ultra - High Switching Stability and Coloration Efficiencies[J]. J. Am. Chem. Soc., 2015,137(12):4050-4053. doi: 10.1021/jacs.5b00429
62. [62]
  Bao X Y, Zhao Q, Wang H W, Liu K C, Qiu D F. Metallopolymer Electrochromic Film Prepared by Oxidative Electropolymerization of a Fe Complex with Arylamine Functionalized Terpyridine Ligand[J]. Inorg. Chem. Commun., 2013,38:88-91. doi: 10.1016/j.inoche.2013.10.008
63. [63]
  XING J N, SHU M, WANG W Y, ZHANG R, LIU J. Synthesis and Properties of Electrochromic Material Based on Phenanthroline Fe(Ⅱ) Complex with Triphenylamine Moiety[J]. Chinese J. Inorg. Chem., 2021,37(10):1847-1852. doi: 10.11862/CJIC.2021.212
64. [64]
  Fan C B, Ye C Q, Wang X M, Chen Z G, Zhou Y Y, Liang Z Q, Tao X T. Synthesis and Electrochromic Properties of New Terpyridine - Triphenylamine Hybrid Polymers[J]. Macromolecules, 2015,48(18):6465-6473. doi: 10.1021/acs.macromol.5b00493
65. [65]
  Liang Y W, Strohecker D, Lynch V, Holliday B J, Jones R A. A Thiophene - Containing Conductive Metallopolymer Using an Fe(Ⅱ) Bis(terpyridine) Core for Electrochromic Materials[J]. ACS Appl. Mater. Interfaces, 2016,8(50):34568-34580. doi: 10.1021/acsami.6b11657
66. [66]
  Bera M K, Mori T, Yoshida T, Ariga K, Higuchi M. Construction of Coordination Nanosheets Based on Tris(2, 2'-bipyridine)-Iron (Fe²⁺) Complexes as Potential Electrochromic Materials[J]. ACS Appl. Mater. Interfaces, 2019,11(12):11893-11903. doi: 10.1021/acsami.8b22568
67. [67]
  Mondal S, Santra D C, Ninomiya Y, Yoshida T, Higuchi M. Dual - Redox System of Metallo - Supramolecular Polymers for Visible - to - Near - IR Modulable Electrochromism and Durable Device Fabrication[J]. ACS Appl. Mater. Interfaces, 2020,12(52):58277-58286. doi: 10.1021/acsami.0c18109
68. [68]
  Pai S, Moos M, Schreck M H, Lambert C, Kurth D G. Green-to -Red Electrochromic Fe(Ⅱ) Metallo - Supramolecular Polyelectrolytes Self - Aassembled from Fluorescent 2, 6 - Bis(2 - pyridyl)pyrimidine Bithiophene[J]. Inorg. Chem., 2017,56(3):1418-1432. doi: 10.1021/acs.inorgchem.6b02496
69. [69]
  Bera M K, Ninomiya Y, Higuchi M. Constructing Alternated Heterobimetallic [Fe(Ⅱ)/Os(Ⅱ)] Supramolecular Polymers with Diverse Solubility for Facile Fabrication of Voltage - Tunable Multicolor Electrochromic Devices[J]. ACS Appl. Mater. Interfaces, 2020,12(12):14376-14385. doi: 10.1021/acsami.9b21966
70. [70]
  Hu C W, Sato T, Zhang J, Moriyama S, Higuchi M. Multi - Colour Electrochromic Properties of Fe/Ru-Based Bimetallo-Supramolecular Polymers[J]. J. Mater. Chem. C, 2013,1(21):3408-3413. doi: 10.1039/c3tc30440j
71. [71]
  Hossain M D, Zhang J, Pandey R K, Sato T, Higuchi M. A Heterometallo - Supramolecular Polymer with Cu^Ⅰ and Fe^Ⅱ Ions Introduced Alternately[J]. Eur. J. Inorg. Chem., 2014(23):3763-3770.
72. [72]
  Chakraborty C, Pandey R K, Rana U, Kanao M, Moriyama S, Higuchi M. Geometrically Isomeric Pt(Ⅱ)/Fe(Ⅱ) - Based Heterometallo-Supramolecular Polymers with Organometallic Ligands for Electrochromism and the Electrochemical Switching of Raman Scattering[J]. J. Mater. Chem. C, 2016,4(40):9428-9437. doi: 10.1039/C6TC02929A
73. [73]
  Pai S, Schott M, Niklaus L, Posset U, Kurth D G. A Study of the Effect of Pyridine Linkers on the Viscosity and Electrochromic Properties of Metallo - Supramolecular Coordination Polymers[J]. J. Mater. Chem. C, 2018,6(13):3310-3321. doi: 10.1039/C7TC04177B
74. [74]
  Han F S, Higuchi M, Kurth D G. Metallo-Supramolecular Polymers Based on Functionalized Bis - Terpyridines as Novel Electrochromic Materials[J]. Adv. Mater., 2007,19(22):3928-3931. doi: 10.1002/adma.200700931
75. [75]
  Schott M, Niklaus L, Clade J, Posset U. Electrochromic Metallo - Supramolecular Polymers Showing Visible and Near - Infrared Light Transmittance Modulation[J]. Sol. Energy Mater. Sol. Cells, 2019,200110001. doi: 10.1016/j.solmat.2019.110001
76. [76]
  Xing J N, Yue Y F, Zhang R, Liu J. Molecular Engineering of Head-Tail Terpyridine - Fe(Ⅱ) Coordination Polymers Employing Alkyl Chain Linkers toward Enhanced Electrochromic Performance[J]. Dyes Pigment., 2021,189109233. doi: 10.1016/j.dyepig.2021.109233
77. [77]
  Arockiam J B, Son H, Han S H, Balamurugan G, Kim Y H, Park J S. Iron Phthalocyanine Incorporated Metallo - Supramolecular Polymer for Superior Electrochromic Performance with High Coloration Efficiency and Switching Stability[J]. ACS Appl. Energy Mater., 2019,2(12):8416-8424. doi: 10.1021/acsaem.9b01022
78. [78]
  Narayana Y S L V, Mondal S, Rana U, Ninomiya Y, Santra D C, Yoshida T, Higuchi M. One-Step Synthesis of a Three -Dimensionally Hyperbranched Fe(Ⅱ) -Based Metallo-Supramolecular Polymer Using an Asymmetrical Ditopic Ligand for Durable Electrochromic Films with Wide Absorption, Large Optical Contrast, and High Coloration Efficiency[J]. ACS Appl. Electron. Mater., 2021,3(5):2044-2055. doi: 10.1021/acsaelm.1c00061
79. [79]
  Mondal S, Ninomiya Y, Yoshida T, Mori T, Bera M K, Ariga K, Higuchi M. Dual-Branched Dense Hexagonal Fe(Ⅱ) -Based Coordination Nanosheets with Red-to-Colorless Electrochromism and Durable Device Fabrication[J]. ACS Appl. Mater. Interfaces, 2020,12(28):31896-31903. doi: 10.1021/acsami.0c05921
80. [80]
  Takada K, Sakamoto R, Yi S T, Katagiri S, Kambe T, Nishihara H. Electrochromic Bis(terpyridine)metal Complex Nanosheets[J]. J. Am. Chem. Soc., 2015,137(14):4681-4689. doi: 10.1021/ja510788b
81. [81]
  Hu C W, Sato T, Zhang J, Moriyama S, Higuchi M. Three-Dimensional Fe(Ⅱ) - Based Metallo - Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency[J]. ACS Appl. Mater. Interfaces, 2014,6(12):9118-9125. doi: 10.1021/am5010859
82. [82]
  Kuai Y, Li W J, Dong Y J, Wong W Y, Yan S M, Dai Y Y, Zhang C. Multi - Color Electrochromism from Coordination Nanosheets Based on a Terpyridine-Fe(Ⅱ) Complex[J]. Dalton Trans., 2019,48(40):15121-15126. doi: 10.1039/C9DT02980J
83. [83]
  Roy S, Chakraborty C. Interfacial Coordination Nanosheet Based on Nonconjugated Three - Arm Terpyridine: A Highly Color - Efficient Electrochromic Material to Converge Fast Switching with Long Optical Memory[J]. ACS Appl. Mater. Interfaces, 2020,12(31):35181-35192. doi: 10.1021/acsami.0c06045
84. [84]
  Kuai Y, Yang T, Yuan F Y, Dong Y J, Song Q B, Zhang C, Wong W Y. Self-Assembled Flexible Metallo-Supramolecular Film Based on Fe(Ⅱ) Ion and Triphenylamine-Substituted (The original text is'subsituted') Alkyl Terpyridine towards Electrochromic Application[J]. Dyes Pigment., 2021,194109623. doi: 10.1016/j.dyepig.2021.109623
85. [85]
  Beneto A J, Jeong J Y, Park J S. Sub - phthalocyanine- Incorporated Fe(Ⅱ) Metallo - Supramolecular Polymer Exhibiting Blue - to - Transmissive Electrochromic Transition with High Transmittance and Coloration Efficiency[J]. Dalton Trans, 2018,47(45):16036-16039. doi: 10.1039/C8DT03587C
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沈阳化工大学材料科学与工程学院沈阳 110142

Research Progress of Electrochromic Materials Based on Fe(Ⅱ) Coordination Polymers

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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