Citation: Xiong WANG, Rui WANG, Qiao-Ling KANG, Dong-Yun LI, Yang XU, Hong-Liang GE, Feng GAO, Qing-Yi LU. Research Progress on Structural Design and Intrinsic Activity Modulation of Co-Based Oxides for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1673-1689. doi: 10.11862/CJIC.2022.179 shu

Research Progress on Structural Design and Intrinsic Activity Modulation of Co-Based Oxides for Lithium-Ion Batteries

Xiong WANG ¹ ,
Rui WANG ^1,, ,
Qiao-Ling KANG ^1,, ,
Dong-Yun LI ^1,, ,
Yang XU ¹ ,
Hong-Liang GE ¹ ,
Feng GAO ³ ,
Qing-Yi LU ^2,,

1.
College of Materials and Chemistry, China Jiliang University, Hangzhou 310018, China
2.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
3.
College of Engineering and Applied Sciences, Nanjing University, Nanjing 210023, China

Corresponding author: Rui WANG, wangrui@cjlu.edu.cn Qiao-Ling KANG, Dong-Yun LI, Qing-Yi LU,
Received Date: 27 March 2022
Revised Date: 18 June 2022

Figures(12)

At present, the capacity of commercial graphite anode materials for lithium-ion batteries is close to the theoretical value, which limits the development of power batteries. Therefore, it is particularly important to develop anode materials with high capacity, good stability, long cycle life, and excellent rate performance. Co-based oxide materials are one of the ideal anode materials for lithium-ion batteries due to their high specific capacity. In this review, the influence of the increase of active sites of Co-based oxides to promote lithium storage performance is reviewed from the structural design including the construction of one-dimensional structures, two-dimensional structures, three-dimensional structures, hollow structures, carbon material support structures, and heterostructures. The control of intrinsic activity includes the introduction of amorphous structure, non-metallic heteroatom doping, metal heteroatom doping, and the construction of high-entropy oxides. Finally, the future development of Co-based oxides in the field of lithium-ion batteries is prospected.
- lithium-ion battery,
- Co-based oxide,
- structural regulation,
- electronic regulation,
- anode material
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