Citation: Zhao-Yu WANG, Jun-Li XU, Ming-Wen ZHANG, Wen-Tao CHEN. Direct Z-Scheme LaNiO 3/Mn_0.2Cd_0.8S Heterojunction Photocatalysts: Enhanced Photocatalytic Performance for H₂ Evolution and Investigation of Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1809-1818. doi: 10.11862/CJIC.2021.215 shu

Direct Z-Scheme LaNiO 3/Mn_0.2Cd_0.8S Heterojunction Photocatalysts: Enhanced Photocatalytic Performance for H₂ Evolution and Investigation of Mechanism

1.
Fujian Provincial Key Lab of Coastal Basin Environment, Fujian Polytechnic Normal University, Fuqing, Fujian 350000, China
2.
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350002, China

Corresponding author: Zhao-Yu WANG, 1058238843@qq.com
Received Date: 11 May 2021
Revised Date: 6 August 2021

Figures(11)

Direct Z-scheme LaNiO₃/Mn_0.2Cd_0.8S heterojunction photocatalysts were synthesized in situ by the introduction of Mn²⁺ ions in the hydrothermal preparation of CdS using LaNiO₃ nanoparticles matrix and fully characterized by field emission scanning electron microscope, powder X-ray diffraction, X-ray photoelectron spectroscopy, UV-Vis diffuse reflectance spectra, N₂ adsorption-desorption test and electrochemistry test. LaNiO₃/Mn_0.2Cd_0.8S heterojunction photocatalysts showed improved photocatalytic H₂ evolution and stability. The photocatalytic H₂ evolution over LaNiO₃/Mn_0.2Cd_0.8S heterojunction photocatalysts reached to 1 190.3 μmol in 5 h, which was 25-fold and 10-fold enhanced compared with pure CdS and Mn_0.2Cd_0.8S. The enhanced performance of LaNiO₃/Mn_0.2Cd_0.8S heterojunction photocatalysts was ascribed to the formation of heterojunction between LaNiO₃ and Mn_0.2Cd_0.8S as well as the introduced Mn²⁺ ion, which both can inhibit the recombination of the photoinduced electron-hole. Based on the above results, the direct Z-scheme photocatalytic reaction mechanism was proposed to elucidate the improved performance of LaNiO₃/Mn_0.2Cd_0.8S heterojunction photocatalysts.
- direct Z-scheme heterojunction,
- LaNiO₃/Mn_0.2Cd_0.8S,
- photocatalytic H₂ evolution,
- photocorrosion,
- stability
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Direct Z-Scheme LaNiO 3/Mn0.2Cd0.8S Heterojunction Photocatalysts: Enhanced Photocatalytic Performance for H2 Evolution and Investigation of Mechanism

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通讯作者: 陈斌, bchen63@163.com

Direct Z-Scheme LaNiO 3/Mn_0.2Cd_0.8S Heterojunction Photocatalysts: Enhanced Photocatalytic Performance for H₂ Evolution and Investigation of Mechanism