Citation: Sai-Nan CHENG, Kun DING, Shuang-Teng SONG, Tie ZHANG, Zhi-Xu ZHANG, Yi ZHANG, Da-Wei FU. Dielectric Phase Transition Induced by Halogen Substitution Based on 1, 4-Diazabicyclo[2.2.2]octane-Derivatives[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 961-967. doi: 10.11862/CJIC.2021.130 shu

Dielectric Phase Transition Induced by Halogen Substitution Based on 1, 4-Diazabicyclo[2.2.2]octane-Derivatives

Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China

Corresponding author: Yi ZHANG, yizhang1980@seu.edu.cn Da-Wei FU, dawei@seu.edu.cn
Received Date: 5 March 2021
Revised Date: 17 April 2021

Figures(6)

We successfully synthesized (X-EtHDabco)[ZnBr₄] (X=H, F, Cl for compound 1, 2, and 3, EtDabco=N-ethyl-1, 4-diazoniabicyclo[2.2.2]octane) through precise molecular design. Systematic measurements (powder X-ray diffraction, differential scanning calorimetry measurements, dielectric measurements) were performed on these compounds. It is noteworthy that, no hint of heat anomaly was observed for 1, while both 2 and 3 displayed intriguing isostructural order-disorder phase transition near 230 K. Through the analysis of the crystal structure, the order-disorder transformation of organic ammonium plays a major role in the phase transition, in addition, the displacement of the inorganic framework also contributes to dielectric response.
- halogen substitution,
- organic-inorganic hybrid,
- reversible phase transition,
- dielectric properties,
- single crystal
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