Citation: Yuhao Xiong, Jian Zhang, Yue Sun, Boyuan Hu, Wei Wang, Yuanyuan Yin, Debin Xia, Kaifeng Lin, Yulin Yang, Evgeny Tretyakov. Metal-organic frameworks in perovskite solar cells: Harnessing structural diversity for enhanced photovoltaic performance[J]. Chinese Journal of Structural Chemistry, ;2026, 45(3): 100842. doi: 10.1016/j.cjsc.2025.100842 shu

Metal-organic frameworks in perovskite solar cells: Harnessing structural diversity for enhanced photovoltaic performance

In recent years, metal-organic frameworks (MOFs) have emerged as promising materials in modifying perovskite solar cells (PSCs) due to their unique porous structures, exceptional specific surface area, tunable organic–inorganic coordination environments, and abundant modification sites. These features endowed MOFs with the ability to regulate the crystallization rate of perovskite films, promote uniform crystal growth, and passivate both surface and grain boundary defects. This review systematically categorizes the applications of MOFs in PSCs based on MOF types and their corresponding functional mechanisms, while exploring the selection criteria for MOFs with different structures from five key dimensions: pores, framework structures, functional groups, MOF composites, and MOF derivatives. Focusing on the structural design of MOFs, this review further aims to forecast the development trends of MOFs at the MOF/PSCs interface and provide guidance for the rational design and selection of MOFs for propelling next-generation photovoltaic technologies.
- Metal-organic frameworks,
- Perovskite solar cells,
- Crystallization regulation,
- Defect passivation,
- Interface
1. [1]
  Rongjun Zhao , Tai Wu , Yong Hua , Yude Wang . Improving performance of perovskite solar cells enabled by defects passivation and carrier transport dynamics regulation via organic additive. Chinese Chemical Letters, 2025, 36(2): 109587-. doi: 10.1016/j.cclet.2024.109587
2. [2]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
3. [3]
  Chen Lu , Zefeng Yu , Jing Cao . Advancement in porphyrin/phthalocyanine compounds-based perovskite solar cells. Chinese Journal of Structural Chemistry, 2024, 43(3): 100240-100240. doi: 10.1016/j.cjsc.2024.100240
4. [4]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
5. [5]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
6. [6]
  Xiaohan Wang , Xue Guo , Zhuo Song , Chen Guan , Chengyu Yang , Tianyang Li , Yukun Zhu , Yan Xu . Interface engineering of Co9S8/Ni3S2 heterojunction with robust stability for boosting peroxymonosulfate activation. Chinese Journal of Structural Chemistry, 2026, 45(2): 100771-100771. doi: 10.1016/j.cjsc.2025.100771
7. [7]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
8. [8]
  Pengfu Gao , Yuan Geng , Wei Gong . Homochiral metal-organic frameworks bearing privileged ligands for heterogeneous asymmetric catalysis. Chinese Journal of Structural Chemistry, 2025, 44(10): 100719-100719. doi: 10.1016/j.cjsc.2025.100719
9. [9]
  Chao Jia , Min Ren , Yingdi Jin , Xingxing Li . Hydrogen migration induced magnetic phase transitions in two-dimensional Fe-porphyrinoid metal-organic frameworks. Chinese Journal of Structural Chemistry, 2026, 45(2): 100801-100801. doi: 10.1016/j.cjsc.2025.100801
10. [10]
  Chengye Lou , Yu Hu , Yunjia Jiang , Lingyao Wang , Yuanbin Zhang . Borane cage hybrid supramolecular metal-organic frameworks (BSFs): Design, synthesis and gas separation performance. Chinese Journal of Structural Chemistry, 2026, 45(2): 100789-100789. doi: 10.1016/j.cjsc.2025.100789
11. [11]
  Jun-Xian Chen , Xian-Xian Xiao , Libo Li , Jinping Li , Rui-Biao Lin , Xiao-Ming Chen . Fine-tuning of Hofmann-type metal-organic frameworks for highly efficient separation of C4 olefins. Chinese Journal of Structural Chemistry, 2025, 44(12): 100744-100744. doi: 10.1016/j.cjsc.2025.100744
12. [12]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
13. [13]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
14. [14]
  Sihong Li , Weiping Deng , Qijie Mo , Haili Song , Chunying Chen , Li Zhang . Engineering S-coordinated Ru single-atoms in a porphyrinic metal-organic framework for CO2 photoreduction. Chinese Journal of Structural Chemistry, 2026, 45(3): 100841-100841. doi: 10.1016/j.cjsc.2025.100841
15. [15]
  Zhiqi Hu , Lingling Wu , Duo Zhang , Yixue An , Jiao Wang , Binbin Zhao , Robert Chunhua Zhao , Rong Cao , Xue Yang . Ultrathin transparent metal-organic framework-based nanocomposite membranes for antibacterial wound healing. Chinese Journal of Structural Chemistry, 2025, 44(12): 100749-100749. doi: 10.1016/j.cjsc.2025.100749
16. [16]
  Mengjin Li , Tian Xia , Mengyu Wang , Yujie Peng , Sihan Zhang , Xueliang Jiang , Huan Yang . Biocarbon-Confined Bimetallic FeCo Metal-Organic Framework Orthogonal Nanosheet Arrays for Industry-level Ethylene Glycol Oxidation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100627-100627. doi: 10.1016/j.cjsc.2025.100627
17. [17]
  Xi Feng , Ding-Yi Hu , Zi-Jun Liang , Mu-Yang Zhou , Zhi-Shuo Wang , Wen-Yu Su , Rui-Biao Lin , Dong-Dong Zhou , Jie-Peng Zhang . A metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100540-100540. doi: 10.1016/j.cjsc.2025.100540
18. [18]
  Yajie Yang , Mengde Zhai , Haoxin Wang , Cheng Chen , Ziyang Xia , Chengyang Liu , Yi Tian , Ming Cheng . Molecular engineering of dibenzo-heterocyclic core based hole-transporting materials for perovskite solar cells. Chinese Chemical Letters, 2025, 36(5): 110700-. doi: 10.1016/j.cclet.2024.110700
19. [19]
  Liang Wang , Weitao Li , Lei Zheng , Mengmin Jia , Dai-Huo Liu , Dongmei Dai , Zhuangzhuang Zhang , Chunyu Ma , Bao Wang , Shengli Zhang , Li Su , Bao Li . Hemin with strong adsorption on zinc anode as a multi-functional interface layer for highly reversible Zn-ion batteries. Chinese Chemical Letters, 2026, 37(1): 111458-. doi: 10.1016/j.cclet.2025.111458
20. [20]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933

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