Citation: Juan Chen, Jin-Ni Zhao, Guo-Yu Yang. Four zinc borates: From acentric chain to centric porous layer[J]. Chinese Journal of Structural Chemistry, ;2026, 45(2): 100788. doi: 10.1016/j.cjsc.2025.100788 shu

Four zinc borates: From acentric chain to centric porous layer

Four zinc borates, MNa9ZnB16O28(OH)4 (M = K, Rb, Cs; 1−3) and Na3ZnB5O10 (4) have been made under solvothermal conditions. Compounds 1−3 are isostructural and contain an unprecedented [B16O28(OH)4]12− cluster constructed from eight B3O3 rings sharing BO4 tetrahedra. The clusters further link with ZnO4 tetrahedra to form one-dimensional (1-D) chains, which further assemble into a 3-D supramolecular framework through hydrogen bonds. 4 was made by raising the reaction temperature of 1 and features a porous-layer structure composed of [B4O9]6−clusters, BO3 units and ZnO4 tetrahedra. All compounds exhibit short deep ultraviolet (DUV) cutoff edges below 190 nm. Notably, 1−3 crystallize in the acentric space group I−4 and display second harmonic generation (SHG) responses of approximately 1.26, 1.30 and 1.32 times that of KH2PO4 (KDP), respectively, highlighting their potential as DUV nonlinear optical materials.
- Zinc borates,
- Nonlinear optical properties,
- Deep-ultraviolet,
- Second harmonic generation
1. [1]
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2. [2]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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