Citation: Yangfeifei Ou, Xiao-Liang Zhou, You-Zhao Lan, Jian-Wen Cheng. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions[J]. Chinese Journal of Structural Chemistry, ;2025, 44(9): 100708. doi: 10.1016/j.cjsc.2025.100708 shu

Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

Short-wavelength nonlinear optical (NLO) crystals can convert a specific wavelength of light to ultraviolet (UV) and deep-UV region. To date, most of the commercialized UV and deep-UV NLO materials are borate crystals. By combining the merits of borates and silicates, borosilicates exhibit some unique advantages of rich structural types, moderate second harmonic generation (SHG) response, and high UV transmittance. This paper summarizes the known NLO borosilicates which can be grouped into two types according to the linkage modes of B–O and Si–O units: (1) borosilicates with B–O–Si covalent bond, and (2) borosilicates with isolated B–O and Si–O units. The structural features, SHG intensities, and UV cutoff edges of these borosilicates are discussed. Finally, future perspectives in this field are presented.
- Borosilicate,
- Borate,
- Nonlinear optical,
- Deep-ultraviolet
1. [1]
  Piao Tang , Xin Wen , Jindong Chen , Ning Ye , Guang Peng . Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite non-linear optical crystal featuring novel zigzag layered structure. Chinese Journal of Structural Chemistry, 2026, 45(1): 100763-100763. doi: 10.1016/j.cjsc.2025.100763
2. [2]
  Juan Chen , Jin-Ni Zhao , Guo-Yu Yang . Four zinc borates: From acentric chain to centric porous layer. Chinese Journal of Structural Chemistry, 2026, 45(2): 100788-100788. doi: 10.1016/j.cjsc.2025.100788
3. [3]
  Peng Guo , Shicheng Dong , Xiang-Gui Zhang , Bing-Bin Yang , Jun Zhu , Ke-Yin Ye . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates. Chinese Chemical Letters, 2025, 36(4): 110052-. doi: 10.1016/j.cclet.2024.110052
4. [4]
  Yu Zhou , Lin-Tao Jiang , Xiao-Ming Jiang , Bin-Wen Liu , Guo-Cong Guo . Mixed-anion square-pyramid [SbS₃I₂] units causing strong second-harmonic generation intensity and large birefringence. Chinese Chemical Letters, 2025, 36(4): 109740-. doi: 10.1016/j.cclet.2024.109740
5. [5]
  Peng-Fei Li , Chun-Li Hu , Bo Zhang , Jiang-Gao Mao , Fang Kong . From HgGa₂(SeO₃)₄ to Hg₂Ga(SeO₃)₂F: The first Hg^Ⅰ-based selenite birefringent crystal triggered by linear groups and fluoride ions. Chinese Chemical Letters, 2026, 37(2): 110588-. doi: 10.1016/j.cclet.2024.110588
6. [6]
  Hongyuan Sha , Dongling Yang , Yanran Shang , Zujian Wang , Rongbing Su , Chao He , Xiaoming Yang , Xifa Long . Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra. Chinese Chemical Letters, 2025, 36(4): 109730-. doi: 10.1016/j.cclet.2024.109730
7. [7]
  Jiajing Wu , Ru-Ling Tang , Sheng-Ping Guo . Three types of promising functional building units for designing metal halide nonlinear optical crystals. Chinese Journal of Structural Chemistry, 2024, 43(6): 100291-100291. doi: 10.1016/j.cjsc.2024.100291
8. [8]
  Lihua Gao , Yinglei Han , Chensheng Lin , Huikang Jiang , Guang Peng , Guangsai Yang , Jindong Chen , Ning Ye . Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides. Chinese Chemical Letters, 2024, 35(12): 109529-. doi: 10.1016/j.cclet.2024.109529
9. [9]
  Yijia Chen , Wendan Luo , Ke Liu , Taihong Liu , Liping Ding , Yu Fang . Diverse roles of indacenodithiophene in push-pull chromophores for enhanced two-photon absorption and efficient nonlinear optical limiting. Chinese Journal of Structural Chemistry, 2025, 44(10): 100704-100704. doi: 10.1016/j.cjsc.2025.100704
10. [10]
  Ying Xu , Yan Pu , Qiong Zhang , Xi Kang , Manzhou Zhu . Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters. Chinese Journal of Structural Chemistry, 2025, 44(10): 100735-100735. doi: 10.1016/j.cjsc.2025.100735
11. [11]
  Li Zhou , Fengyu Li , Zhou Lu , Yingwei Wang , Jun He . Two-dimensional atomic crystals for third-order nonlinear optical modulation. Chinese Journal of Structural Chemistry, 2026, 45(2): 100772-100772. doi: 10.1016/j.cjsc.2025.100772
12. [12]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
13. [13]
  Yuwei Kang , Can Yang , Jun Zhang , Qi Wu . Synergistic triple-site engineering in ABX₃-type hybrid halides for high-performance nonlinear optical crystals. Chinese Chemical Letters, 2026, 37(1): 111385-. doi: 10.1016/j.cclet.2025.111385
14. [14]
  Tianyang Dong , Xingyuan Wen , Xingzhi Wu , Ying Jiang , Chong Wang , Ruizhi Liu , Junyi Li , Wenfa Zhou , Yinglin Song , Xiaofeng Shi , Rui Wen , Chunru Wang , Li Jiang , Chunli Bai . Ionic covalent organic frameworks enable laser-pulse-duration-dependent high third-order nonlinear optical responses. Chinese Journal of Structural Chemistry, 2025, 44(10): 100733-100733. doi: 10.1016/j.cjsc.2025.100733
15. [15]
  Fan Liu , Pifu Gong , Zheshuai Lin , Lei Kang . REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects. Chinese Journal of Structural Chemistry, 2026, 45(3): 100844-100844. doi: 10.1016/j.cjsc.2025.100844
16. [16]
  Hongshan Wang , Zhenglong Li , Ran An , Zhenyou Wang , Juanjuan Lu , Guansong Zheng , Zhihua Yang , Yu Chu , Junjie Li . NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2. Chinese Journal of Structural Chemistry, 2025, 44(12): 100757-100757. doi: 10.1016/j.cjsc.2025.100757
17. [17]
  Yu-Qin Xia , Shui-Ming Jing , Li-Mei Chang , Zhi-Gang Gu , Jian Zhang . Luminescent covalent organic frameworks: Classification to optical applications. Chinese Journal of Structural Chemistry, 2026, 45(1): 100731-100731. doi: 10.1016/j.cjsc.2025.100731
18. [18]
  Can Wang , Zhe Sun , Donghan Ma . Review of imaging buffers used in stochastic optical reconstruction microscopy. Chinese Chemical Letters, 2025, 36(9): 110677-. doi: 10.1016/j.cclet.2024.110677
19. [19]
  Weinan Hu , Li Li , Xinyu Wang , Yongqiang Zhang , Maoping Song , Linlin Shi , Xinqi Hao , Siyu Lu . Carbonized polymer dots: Illuminating synthesis pathways, optical frontiers, and photoelectronic breakthroughs. Chinese Chemical Letters, 2025, 36(11): 111612-. doi: 10.1016/j.cclet.2025.111612
20. [20]
  Chen Liu , Tianqi Zhao , Jialing Zhou , Xiaoyun Hu , Dinghao Pan , Jinlong Li , Wei Li , Zhihui Dai . Optical lateral flow immune assay technology for body fluid sensing. Chinese Chemical Letters, 2026, 37(1): 110967-. doi: 10.1016/j.cclet.2025.110967

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(129)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return