Citation: Yan-Jia Lin, Qing-Xin Zeng, Xiao-Min Shen, Shou-Tian Zheng, Xin-Xiong Li. Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory[J]. Chinese Journal of Structural Chemistry, ;2025, 44(10): 100702. doi: 10.1016/j.cjsc.2025.100702 shu

Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory

Crystalline metal cluster-based organic-inorganic hybrid materials have emerged as a significant frontier in materials chemistry due to their unique structural designability and tunable properties. The bifunctional ligand 2-(hydroxymethyl)-2-(4-pyridyl)-1,3-propanediol (H3L), featuring both hard hydroxyl donors on one side and a soft pyridyl group on the other side, enables selective metal coordination via hard-soft acid-base (HSAB) theory and directs hierarchical metal cluster assembly. This review systematically summarizes the recent advances on metal cluster-based materials coordinated by H3L, including their syntheses, crystal structures, and related physicochemical properties.
- Tripodal alcohol ligand,
- Metal cluster,
- Polyoxometalate,
- Cluster-organic frameworks
1. [1]
  Qing Li , Fangyu Fu , Mengyun Zhao , Yeqin Feng , Manzhou Chi , Zichen Zhao , Hongjin Lv , Guo-Yu Yang . Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate. Chinese Chemical Letters, 2025, 36(7): 110090-. doi: 10.1016/j.cclet.2024.110090
2. [2]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
3. [3]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
4. [4]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
5. [5]
  Li-Min Cui , Wei-Hui Fang , Jian Zhang . Polyoxometalates containing aluminum atoms. Chinese Chemical Letters, 2025, 36(10): 110386-. doi: 10.1016/j.cclet.2024.110386
6. [6]
  Jinlian SHI , Xiaoru LIU , Zhongxuan XU . Ligand-directed construction of cobalt-oxo cluster-based organic frameworks: Structural modulation, semiconductor, and antiferromagnetic properties. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 45-54. doi: 10.11862/CJIC.20250196
7. [7]
  Xianghe Kong , Xiaoli Liao , Zhenkun Huang , Lei Mei , Hongqing Wang , Kongqiu Hu , Weiqun Shi . Designed assembly of heterometallic cluster organic frameworks based on Th₆ cluster. Chinese Chemical Letters, 2024, 35(11): 109642-. doi: 10.1016/j.cclet.2024.109642
8. [8]
  Fahui Xiang , Lu Li , Zhen Yuan , Wuji Wei , Xiaoqing Zheng , Shimin Chen , Yisi Yang , Liangji Chen , Zizhu Yao , Jianwei Fu , Zhangjing Zhang , Shengchang Xiang . Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition. Chinese Chemical Letters, 2025, 36(3): 109672-. doi: 10.1016/j.cclet.2024.109672
9. [9]
  Haiming Wu , Gaya N. Andrew , Rajini Anumula , Zhixun Luo . Corrigendum to 'How ligand coordination and superatomic-states accommodate the structure and property of a metal cluster: Cu₄ (dppy)₄ Cl₂ vs. Cu₂₁ (dppy)₁₀ with altered photoluminescence' [Chin. Chem. Lett. 35 (2024) 108340]. Chinese Chemical Letters, 2024, 35(12): 109912-. doi: 10.1016/j.cclet.2024.109912
10. [10]
  Shenglan Zhou , Haijian Li , Hongyi Gao , Ang Li , Tian Li , Shanshan Cheng , Jingjing Wang , Jitti Kasemchainan , Jianhua Yi , Fengqi Zhao , Wengang Qu . Recent advances in metal-loaded MOFs photocatalysts: From single atom, cluster to nanoparticle. Chinese Chemical Letters, 2025, 36(1): 110142-. doi: 10.1016/j.cclet.2024.110142
11. [11]
  Zi-Jian Zhou , Xin-Ping Wu . Level-shifted embedded cluster method may offer a viable alternative for the simulation of metal oxides. Chinese Journal of Structural Chemistry, 2025, 44(5): 100471-100471. doi: 10.1016/j.cjsc.2024.100471
12. [12]
  Lin Geng , Wei-Hui Fang . From tailorable aluminum molecular rings to high-connectivity metal cluster-based COFs. Chinese Journal of Structural Chemistry, 2026, 45(2): 100746-100746. doi: 10.1016/j.cjsc.2025.100746
13. [13]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
14. [14]
  Qiu-Jie Chen , Tian-Ying Gu , Zhao-Bo Hu , Man-Bo Zhang , Zheng Yin , Ming-Hua Zeng . Tandem assembly-disassembly-reassembly of hierarchical Co19 coordination cluster facilitated by in-situ ligand transformation: Crystallography and ESI-MS revealed mechanism. Chinese Journal of Structural Chemistry, 2025, 44(9): 100659-100659. doi: 10.1016/j.cjsc.2025.100659
15. [15]
  Xiao-Hong Yi , Hong-Yu Chu , Chao-Yang Wang , Hang Ren , Li-hong Zhou , Yujie Zhao , Fu-Xue Wang , Hao Du , Yixuan Zhai , Tao Xia , Shaohua Guo , Xiaoning Wang , Yunlong Wang , Qian Wen , Ge Shen , Meng Yang , Yu-Hang Li , Mingjia Xu , Xiaoyuan Zhang , Hao Wang , Xudong Zhao , Yifei Sun , Yi-Lin Liu , Qingyi Zeng , Yuying Deng , Qi Wang , Xiaodong Zhang , Jie Li , Ning Liu , Chuanxi Yang , Jiansheng Li , Anping Wang , Xun Wang , Xuchun Qiu , Haodong Ji , Xuedong Du , Jiaxing Wu , Chong-Chen Wang . Metal-organic frameworks for clean water. Chinese Chemical Letters, 2026, 37(3): 112243-. doi: 10.1016/j.cclet.2025.112243
16. [16]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
17. [17]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
18. [18]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661
19. [19]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
20. [20]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249

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