Citation: Yan-Jia Lin, Qing-Xin Zeng, Xiao-Min Shen, Shou-Tian Zheng, Xin-Xiong Li. Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory[J]. Chinese Journal of Structural Chemistry, ;2025, 44(10): 100702. doi: 10.1016/j.cjsc.2025.100702 shu

Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory

Crystalline metal cluster-based organic-inorganic hybrid materials have emerged as a significant frontier in materials chemistry due to their unique structural designability and tunable properties. The bifunctional ligand 2-(hydroxymethyl)-2-(4-pyridyl)-1,3-propanediol (H3L), featuring both hard hydroxyl donors on one side and a soft pyridyl group on the other side, enables selective metal coordination via hard-soft acid-base (HSAB) theory and directs hierarchical metal cluster assembly. This review systematically summarizes the recent advances on metal cluster-based materials coordinated by H3L, including their syntheses, crystal structures, and related physicochemical properties.
- Tripodal alcohol ligand,
- Metal cluster,
- Polyoxometalate,
- Cluster-organic frameworks
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