Citation: Chao Wei, Zi-Yi Zhao, Jing-Jing Li, Jinli Zhang, Ming Lu, Xiao-Qin Liu, Guoliang Liu, Jiandong Pang, Lin-Bing Sun. Topology guided construction of MOF by linking Zr-MOLs with perylene diimide motifs for photocatalytic oxidation[J]. Chinese Journal of Structural Chemistry, ;2025, 44(8): 100625. doi: 10.1016/j.cjsc.2025.100625 shu

Topology guided construction of MOF by linking Zr-MOLs with perylene diimide motifs for photocatalytic oxidation

Metal-organic frameworks (MOFs) with new topologies and enhanced properties can be obtained by connecting metal-organic layers (MOLs) using multifunctional linkers. However, new topologies constructed by this method using linear-shaped ligands have not yet been explored. Herein, we present the design of NUT-123 by incorporating a near-linear perylene diimide (PDI) derivate, PDI–CH3–COOH, into the preselected zirconium-based MOLs. 3D electron diffraction confirms the successful construction of a novel topology in NUT-123. Furthermore, the uniformly dispersed PDI groups within the structure confer enhance photocatalytic capability while effectively circumventing the self-aggregation of PDI–CH3–COOH. NUT-123 exhibits enhanced efficiency and selectivity in sulfide oxidation and demonstrates excellent substrate compatibility, achieving 100% conversion of various organic sulfides. Mechanistic studies indicate that the formation of sulfoxides is facilitated by concurrent electron and energy transfer. This work fills the gap in constructing a new topology by connecting MOLs with linear-shaped linkers and provides a photocatalyst for selective sulfide oxidation.
- Metal-organic frameworks,
- Perylene diimide,
- New topology,
- Photocatalysis,
- Sulfide oxidation
1. [1]
  Ya-Ru Qu , Kai-Li Tian , Han-Jun Huang , Jia-Jun Tu , Ai-Hao Chen , Hai-Jun Sun , Maxim V. Bermeshev , Shao-Jie Wang , Wen-Bin Li , Xiang-Kui Ren . Fluorescence enhancement of perylene diimide: Design strategy and application. Chinese Journal of Structural Chemistry, 2025, 44(12): 100756-100756. doi: 10.1016/j.cjsc.2025.100756
2. [2]
  Mengjin Li , Tian Xia , Mengyu Wang , Yujie Peng , Sihan Zhang , Xueliang Jiang , Huan Yang . Biocarbon-Confined Bimetallic FeCo Metal-Organic Framework Orthogonal Nanosheet Arrays for Industry-level Ethylene Glycol Oxidation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100627-100627. doi: 10.1016/j.cjsc.2025.100627
3. [3]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
4. [4]
  Jia-Ru Li , Ning Li , Li-Ling He , Jun He . Fluorine-functionalized zirconium-organic cages for efficient photocatalytic oxidation of thioanisole. Chinese Chemical Letters, 2025, 36(1): 109934-. doi: 10.1016/j.cclet.2024.109934
5. [5]
  Pengfu Gao , Yuan Geng , Wei Gong . Homochiral metal-organic frameworks bearing privileged ligands for heterogeneous asymmetric catalysis. Chinese Journal of Structural Chemistry, 2025, 44(10): 100719-100719. doi: 10.1016/j.cjsc.2025.100719
6. [6]
  Chao Jia , Min Ren , Yingdi Jin , Xingxing Li . Hydrogen migration induced magnetic phase transitions in two-dimensional Fe-porphyrinoid metal-organic frameworks. Chinese Journal of Structural Chemistry, 2026, 45(2): 100801-100801. doi: 10.1016/j.cjsc.2025.100801
7. [7]
  Chengye Lou , Yu Hu , Yunjia Jiang , Lingyao Wang , Yuanbin Zhang . Borane cage hybrid supramolecular metal-organic frameworks (BSFs): Design, synthesis and gas separation performance. Chinese Journal of Structural Chemistry, 2026, 45(2): 100789-100789. doi: 10.1016/j.cjsc.2025.100789
8. [8]
  Yuhao Xiong , Jian Zhang , Yue Sun , Boyuan Hu , Wei Wang , Yuanyuan Yin , Debin Xia , Kaifeng Lin , Yulin Yang , Evgeny Tretyakov . Metal-organic frameworks in perovskite solar cells: Harnessing structural diversity for enhanced photovoltaic performance. Chinese Journal of Structural Chemistry, 2026, 45(3): 100842-100842. doi: 10.1016/j.cjsc.2025.100842
9. [9]
  Jun-Xian Chen , Xian-Xian Xiao , Libo Li , Jinping Li , Rui-Biao Lin , Xiao-Ming Chen . Fine-tuning of Hofmann-type metal-organic frameworks for highly efficient separation of C4 olefins. Chinese Journal of Structural Chemistry, 2025, 44(12): 100744-100744. doi: 10.1016/j.cjsc.2025.100744
10. [10]
  Shuhong Wu , Wanying Han , Ying Wang , Yan Zhuang , Hui Niu , Lurong Li , Junhui Wang , Yuan Liu , Huan Lin , Kaifeng Wu , Jinni Shen , Yingguang Zhang , Michael K. H. Leung , Jinlin Long . Close π-π stacking facilitated intermolecular charge separation in self-assembled perylene monoimide for photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2025, 44(6): 100592-100592. doi: 10.1016/j.cjsc.2025.100592
11. [11]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
12. [12]
  Changmin Liu , Ying Wang , Yongqi Bao , Yuqing Lin . Metal-organic framework mimetic enzymes: Exploring new horizons in brain chemistry. Chinese Chemical Letters, 2025, 36(9): 110652-. doi: 10.1016/j.cclet.2024.110652
13. [13]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
14. [14]
  Zhou Li , Mengxue Yu , Shixin Chang , Zhibin Huang , Zhenmin Cheng , Weibin Zhang , Sónia A. C. Carabineiro , Zhigao Xu , Kangle Lv . Enhancing the photocatalytic activity of crystalline g-C3N4 towards NO oxidation and CO2 reduction through K+-doping and cyano defect engineering. Chinese Journal of Structural Chemistry, 2026, 45(1): 100698-100698. doi: 10.1016/j.cjsc.2025.100698
15. [15]
  Cui Luo , Peng-Hui Li , Wei-Ming Liao , Qia-Chun Lin , Xiao-Xiang Zhou , Jun He . Strategic metal substitution for enhanced visible-light-driven oxygen evolution in heterometallic MOFs. Chinese Journal of Structural Chemistry, 2025, 44(7): 100621-100621. doi: 10.1016/j.cjsc.2025.100621
16. [16]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
17. [17]
  Sihong Li , Weiping Deng , Qijie Mo , Haili Song , Chunying Chen , Li Zhang . Engineering S-coordinated Ru single-atoms in a porphyrinic metal-organic framework for CO2 photoreduction. Chinese Journal of Structural Chemistry, 2026, 45(3): 100841-100841. doi: 10.1016/j.cjsc.2025.100841
18. [18]
  Zhiqi Hu , Lingling Wu , Duo Zhang , Yixue An , Jiao Wang , Binbin Zhao , Robert Chunhua Zhao , Rong Cao , Xue Yang . Ultrathin transparent metal-organic framework-based nanocomposite membranes for antibacterial wound healing. Chinese Journal of Structural Chemistry, 2025, 44(12): 100749-100749. doi: 10.1016/j.cjsc.2025.100749
19. [19]
  Xi Feng , Ding-Yi Hu , Zi-Jun Liang , Mu-Yang Zhou , Zhi-Shuo Wang , Wen-Yu Su , Rui-Biao Lin , Dong-Dong Zhou , Jie-Peng Zhang . A metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100540-100540. doi: 10.1016/j.cjsc.2025.100540
20. [20]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(416)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return