Citation: Yuanping Jiang, Haoqi Liu, Jiawei Zhang, Luying Jiao, Xiaoling Lin, Fuhua Zhang, Guoping Yang. Four tartaric acid-bridged tetra-europium(III)-containing antimonotungstate with catalytic oxidation of thioethers/alcohols[J]. Chinese Journal of Structural Chemistry, ;2025, 44(7): 100603. doi: 10.1016/j.cjsc.2025.100603 shu

Four tartaric acid-bridged tetra-europium(III)-containing antimonotungstate with catalytic oxidation of thioethers/alcohols

A novel tetra-europium(III)-containing antimonotungstate, Na8.2[H2N(CH3)2]9[Na10.8(tar)4(H2O)20(Eu2Sb2W21O72)2]·44.5H2O (EuSbW, H4tar = dl-tartaric acid), has been synthesized and characterized. The dimeric polyoxoanion of EuSbW consists of two Dawson-like {Eu2Sb2W21} units bridged by four dl-tartaric acid ligands. The adjacent carboxyl and hydroxy groups in each tartaric acid simultaneously chelate with W and Eu atoms from different {Eu2Sb2W21} units, thereby forming the dimeric structure. EuSbW represents an extremely rare polyoxometalate where four tartaric acid ligands function as connectors to bridge two {Eu2Sb2W21} units. Additionally, EuSbW exhibits excellent catalytic activity and reusability in the oxidation of thioethers and alcohols, achieving 100% conversion and > 99% selectivity for various thioethers, and 85–100% conversion with 90–99% selectivity for diverse alcohols under mild conditions.
- Antimonotungstate,
- Tartaric acid,
- Catalytic oxidation,
- Thioethers,
- Alcohols
1. [1]
  Guoping Yang , Zhoufu Lin , Xize Zhang , Jiawei Cao , Xuejiao Chen , Yufeng Liu , Xiaoling Lin , Ke Li . Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles. Chinese Chemical Letters, 2024, 35(12): 110274-. doi: 10.1016/j.cclet.2024.110274
2. [2]
  Yanyu Jin , Wenzhe Si , Xing Yuan , Hongjun Cheng , Bin Zhou , Li Cai , Yu Wang , Qibao Wang , Junhua Li . Tuning TM–O interaction by acid etching in perovskite catalysts boosting catalytic performance. Chinese Chemical Letters, 2025, 36(5): 110260-. doi: 10.1016/j.cclet.2024.110260
3. [3]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
4. [4]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
5. [5]
  Jindong Hao , Yufen Lv , Shuyue Tian , Chao Ma , Wenxiu Cui , Huilan Yue , Wei Wei , Dong Yi . Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P₄S₁₀ and alcohols. Chinese Chemical Letters, 2024, 35(9): 109513-. doi: 10.1016/j.cclet.2024.109513
6. [6]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
7. [7]
  Dongsheng Yang , Zixin Li , Yaoyao Lian , Ziyao Fu , Tianjiao Li , Pengtao Ma , Guoping Yang . A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone. Chinese Chemical Letters, 2025, 36(3): 109717-. doi: 10.1016/j.cclet.2024.109717
8. [8]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
9. [9]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
10. [10]
  Runzi Cao , Heng Shao , Xinjie Wang , Jian Wang , Enxiang Shang , Yang Li . Photocatalytic production of high-value-added fuels from biodegradable PBAT by Nb₂O₅/GCN heterojunction catalyst: Performance and mechanism. Chinese Chemical Letters, 2025, 36(7): 111029-. doi: 10.1016/j.cclet.2025.111029
11. [11]
  Jun Zhang , Zhiyao Zheng , Can Zhu . Stereochemical editing: Catalytic racemization of secondary alcohols and amines. Chinese Chemical Letters, 2024, 35(5): 109160-. doi: 10.1016/j.cclet.2023.109160
12. [12]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
13. [13]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
14. [14]
  Xiaokang Hou , Huanxin Ma , Mengmeng Zhao , Chunhua Feng , Shishu Zhu . Unveiling role of Cu(Ⅱ) in photochemical transformation and reactive oxygen species production of schwertmannite in the presence of tartaric acid. Chinese Chemical Letters, 2025, 36(7): 110332-. doi: 10.1016/j.cclet.2024.110332
15. [15]
  Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
16. [16]
  Xinyu Zeng , Zhuofan Zeng , Qingqing Hu , Kejun Liu , Lei Ming , Bei Cheng , Wang Wang , Guoqiang Luo , Shaowen Cao . Hierarchical Pt/NiO hollow nanofibers for catalytic oxidation of HCHO at room temperature. Chinese Journal of Structural Chemistry, 2025, 44(6): 100575-100575. doi: 10.1016/j.cjsc.2025.100575
17. [17]
  Jingtao Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Corrigendum to “Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation” [Chinese Chemical Letters 35 (2024) 109639]. Chinese Chemical Letters, 2025, 36(7): 110867-. doi: 10.1016/j.cclet.2025.110867
18. [18]
  Shuangyu Wu , Jian Peng , Yue Jiang , Sijie Lin . The overlooked promotional effects of alcohols to BiOBr catalysts in photocatalytic degradation of organic pollutants. Chinese Chemical Letters, 2025, 36(11): 110819-. doi: 10.1016/j.cclet.2025.110819
19. [19]
  Jie Li , Mengyun Hu , Tianpeng Liu , Xin Wang , Jun Yu , Changqing Ye , Yukou Du . Amorphous PdSe/crystalline Pt heterostructure enhances polyhydric alcohols electrooxidation. Chinese Chemical Letters, 2026, 37(2): 110828-. doi: 10.1016/j.cclet.2025.110828
20. [20]
  Zeyu Jiang , Yadi Wang , Changwei Chen , Chi He . Progress and challenge of functional single-atom catalysts for the catalytic oxidation of volatile organic compounds. Chinese Chemical Letters, 2024, 35(9): 109400-. doi: 10.1016/j.cclet.2023.109400

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