Citation: Bicheng Zhu, Jingsan Xu. S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation[J]. Chinese Journal of Structural Chemistry, ;2024, 43(8): 100327. doi: 10.1016/j.cjsc.2024.100327 shu

S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation

Bicheng Zhu ,
Jingsan Xu

These works validate the efficacy of S-scheme heterojunction photocatalysts in integrating H2 generation and organic synthesis. Meanwhile, the synergetic employment of various in situ characterization methods in the exploration of S-scheme photocatalytic mechanism is exemplified. The development of versatile heterojunction photocatalysts will be inaugurated. In future works, S-scheme photocatalysts are expected to achieve more combination of various redox reactions, such as H2O2 production coupled with organic synthesis, and Cr(VI) reduction hybridized with pollutant degradation. Besides, employing cocatalysts to decorate S-scheme heterojunctions can further boost the photocatalytic activity by accelerating charge separation and facilitating molecule adsorption.
1. [1]
  Mengzhao Liu , Jie Yin , Chengjian Wang , Weiji Wang , Yuan Gao , Mengxia Yan , Ping Geng . P doped Ni₃S₂ and Ni heterojunction bifunctional catalysts for electrocatalytic 5-hydroxymethylfurfural oxidation coupled hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(9): 111271-. doi: 10.1016/j.cclet.2025.111271
2. [2]
  Zheng Liu , Yuqing Bian , Graham Dawson , Jiawei Zhu , Kai Dai . Rational constructing of Zn_0.5Cd_0.5S-diethylenetriamine/g-C₃N₄ S-scheme heterojunction with enhanced photocatalytic H₂O₂ production. Chinese Chemical Letters, 2025, 36(9): 111272-. doi: 10.1016/j.cclet.2025.111272
3. [3]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
4. [4]
  Hongrui Zhang , Miaoying Cui , Yongjie Lv , Yongfang Rao , Yu Huang . A short review on research progress of ZnIn₂S₄-based S-scheme heterojunction: Improvement strategies. Chinese Chemical Letters, 2025, 36(4): 110108-. doi: 10.1016/j.cclet.2024.110108
5. [5]
  Xibao Li , Yiyang Wan , Fang Deng , Yingtang Zhou , Pinghua Chen , Fan Dong , Jizhou Jiang . Advances in Z-scheme and S-scheme heterojunctions for photocatalytic and photoelectrocatalytic H₂O₂ production. Chinese Chemical Letters, 2025, 36(10): 111418-. doi: 10.1016/j.cclet.2025.111418
6. [6]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
7. [7]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
8. [8]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
9. [9]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
10. [10]
  Xingyan Liu , Kaili Wu , Yacen Tang , Ning Qi , Yumeng Zhang , Youzhou He , Min Fu , Yanhui Ao . Ti₃C₂ MXene-derived TiO₂@C attached on Bi₂WO₆ with oxygen vacancies to fabricate S-scheme heterojunction for photocatalytic antibiotics degradation and NO removal. Chinese Chemical Letters, 2025, 36(11): 110882-. doi: 10.1016/j.cclet.2025.110882
11. [11]
  Chunyan Yang , Qiuyu Rong , Fengyin Shi , Menghan Cao , Guie Li , Yanjun Xin , Wen Zhang , Guangshan Zhang . Rationally designed S-scheme heterojunction of BiOCl/g-C₃N₄ for photodegradation of sulfamerazine: Mechanism insights, degradation pathways and DFT calculation. Chinese Chemical Letters, 2024, 35(12): 109767-. doi: 10.1016/j.cclet.2024.109767
12. [12]
  Tao Zhou , Xu Han , Wangwang Shen , Fang Ji , Menglong Liu , Yingyu Song , Wen-Wen He . Construction of NiS/CTF heterojunction photocatalyst with an outstanding photocatalytic hydrogen evolution performance. Chinese Chemical Letters, 2025, 36(11): 110415-. doi: 10.1016/j.cclet.2024.110415
13. [13]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
14. [14]
  Chengxin Chen , Hongfei Shi , Xiaoyan Cai , Liang Mao , Zhe Chen . Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction. Acta Physico-Chimica Sinica, 2025, 41(12): 100155-0. doi: 10.1016/j.actphy.2025.100155
15. [15]
  Yongmei Xia , Zuming He , Gang He , Lianxiang Chen , Juan Zhang , Jiangbin Su , Muhammad Saboor Siddique , Xiaofei Fu , Guihua Chen , Wei Zhou . Lead-free perovskite Cs₃Bi₂Br₉/FeS₂ hollow core-shell Z-scheme heterojunctions toward optimized photothermal-photocatalytic H₂ production. Chinese Chemical Letters, 2025, 36(10): 111521-. doi: 10.1016/j.cclet.2025.111521
16. [16]
  Linyu Zhu , Xu Tian , Guang Shi , Wenchi Zhang , Peisong Tang , Mohamed Bououdina , Sajjad Ali , Pengfei Xia . Assembling 3D cross-linked network by carbon nitride nanowires for visible-light photocatalytic H₂ evolution from dyestuffs wastewater. Chinese Chemical Letters, 2025, 36(12): 111088-. doi: 10.1016/j.cclet.2025.111088
17. [17]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
18. [18]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
19. [19]
  Xiaofan ZHANG , Yu DUAN , Meijie SHI , Nan LU , Renhong LI , Xiaoqing YAN . Z-scheme Co₃O₄/BiOBr heterojunction for efficient photoreduction CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1878-1888. doi: 10.11862/CJIC.20250079
20. [20]
  Kailu Guo , Jinzhi Jia , Huijiao Wang , Ziyu Hao , Yinjian Chen , Ke Shi , Haixia Wu , Cailing Xu . Structural tuning and reconstruction of CeO₂-coupled nickel selenides for robust water oxidation. Chinese Chemical Letters, 2025, 36(8): 110888-. doi: 10.1016/j.cclet.2025.110888

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1310)
HTML views(54)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return