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Citation: Wei-Bao He, Cui Xin, Xiuling Cui. Catalytic photoinduced deoxygenation via B(C₆F₅)₃-enabled oxygen atom transfer for aromatic C–H amination of alkylarenes[J]. Chinese Chemical Letters, ;2026, 37(11): 113041. doi: 10.1016/j.cclet.2026.113041 shu

Catalytic photoinduced deoxygenation via B(C₆F₅)₃-enabled oxygen atom transfer for aromatic C–H amination of alkylarenes

Wei-Bao He ^a ,
Cui Xin ^{b, *,} ,
Xiuling Cui ^{c, *,}

a.
Research Center for Technical and Vocational Education Studies, Hunan Chemical Vocational Technology College, Zhuzhou 412000, China
b.
Key Laboratory of Food & Environment & Drug Monitoring and Testing of Universities in Hunan Province, Hunan Police Academy, Changsha 410138, China
c.
Key Laboratory of Fujian Molecular Medicine, Key Laboratory of Precision Medicine and Molecular Diagnosis of Fujian Universities, Key Laboratory of Xiamen Marine and Gene Drugs, Engineering Research Centre of Molecular Medicine of Ministry of Education, School of Biomedical Sciences, Huaqiao University, Xiamen 361021, China

^*

xin-cui@163.com

cuixl@hqu.edu.cn

Received Date: 7 February 2026
Revised Date: 1 June 2026
Accepted Date: 5 June 2026
Available Online: 6 June 2026

Figures(2)

1. [1]
  L.J. Allen, P.J. Cabrera, M. Lee, M.S. Sanford, J. Am. Chem. Soc. 136 (2014) 5607–5610. doi: 10.1021/ja501906x
2. [2]
  G. Cecere, C.M. König, J.L. Alleva, D.W.C. MacMillan, J. Am. Chem. Soc. 135 (2013) 11521–11524. doi: 10.1021/ja406181e
3. [3]
  J. Davies, S.G. Booth, S. Essafi, R.A.W. Dryfe, D. Leonori, Angew. Chem. Int. Ed. 54 (2015) 14017–14021. doi: 10.1002/anie.201507641
4. [4]
  S.W. Lardy, V.A. Schmidt, J. Am. Chem. Soc. 140 (2018) 12318–12322. doi: 10.1021/jacs.8b06881
5. [5]
  Z. Pan, H. Qiu, L. Wang, R. Zheng, Y. Ma, Nat. Commun. 16 (2025) 1167.
1. [1]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
2. [2]
  Zhenguo Zhang , Lanyang Li , Xinlong Zong , Yongheng Lv , Shuanglei Liu , Liang Ji , Xuefei Zhao , Zhenhua Jia , Teck-Peng Loh . "Water" accelerated B(C₆F₅)₃-catalyzed Mukaiyama-aldol reaction: Outer-sphere activation model. Chinese Chemical Letters, 2025, 36(7): 110504-. doi: 10.1016/j.cclet.2024.110504
3. [3]
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4. [4]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
  Jinpeng Du , Junlin Chen , Yulong Shan , Tongliang Zhang , Yu Sun , Zhongqi Liu , Xiaoyan Shi , Wenpo Shan , Yunbo Yu , Hong He . Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts. Chinese Chemical Letters, 2025, 36(3): 110019-. doi: 10.1016/j.cclet.2024.110019
11. [11]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
12. [12]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
13. [13]
  Shan-Qing Yang , Lu-Lu Wang , Rajamani Krishna , Bo Xing , Lei Zhou , Fei-Yang Zhang , Qiang Zhang , Yi-Long Li , Chao-Sheng Bao , Tong-Liang Hu . Efficient C₃H₆/C₃H₈ separation within a bifunctional ultramicroporous metal-organic framework with high purity and record packing density. Chinese Chemical Letters, 2025, 36(12): 110556-. doi: 10.1016/j.cclet.2024.110556
14. [14]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
15. [15]
  Deng Pan , Chuan He , Genping Huang . Mechanism and origins of enantioselectivity of iridium-catalyzed atroposelective intermolecular C(sp²)-H silylation: A ligand-enabled axial chirality transfer strategy. Chinese Chemical Letters, 2026, 37(4): 111217-. doi: 10.1016/j.cclet.2025.111217
16. [16]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
17. [17]
  Entian Cui , Yulian Lu , Zhaoxia Li , Zhilei Chen , Chengyan Ge , Jizhou Jiang . Interfacial B-O bonding modulated S-scheme B-doped N-deficient C₃N₄/O-doped-C₃N₅ for efficient photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(1): 110288-. doi: 10.1016/j.cclet.2024.110288
18. [18]
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19. [19]
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20. [20]
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