Citation: Fangzhou Yang, Yangmin Ma, Siyue Ma, Linli Xu. Single-atom based graphdiyne catalysts support for CO₂ photo/electro-conversion[J]. Chinese Chemical Letters, ;2026, 37(10): 112516. doi: 10.1016/j.cclet.2026.112516 shu

Single-atom based graphdiyne catalysts support for CO₂ photo/electro-conversion

Fangzhou Yang ^{a, b} ,
Yangmin Ma ^{a, *,} ,
Siyue Ma ^a ,
Linli Xu ^{b, *,}

a.
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China
b.
Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hong Kong, China

mayangmin@sust.edu.cn

linli.xu@polyu.edu.hk

Received Date: 23 May 2025
Revised Date: 12 January 2026
Accepted Date: 10 February 2026
Available Online: 10 February 2026

Figures(8)

Climate change and global warming constitute formidable global challenges, predominantly driven by the excessive dependence on conventional fossil fuels, which results in substantial carbon dioxide (CO₂) emissions. Addressing these environmental issues is a paramount priority for researchers. Single-atom catalysts (SACs) have attracted significant attention due to their high atomic efficiency and unique performance in various catalytic reactions. As an emerging two-dimensional (2D) carbon material, graphdiyne (GDY) has gained favor in environmental remediation applications in recent years. GDY comprises sp- and sp²-hybridized carbon atoms, which form benzene rings and diacetylenic linkages (–C≡C–C≡C–) within a two-dimensional planar network, endowing it with high π-conjugation, distinctive and tunable electronic properties, and excellent chemical and thermal stability. In this review, we investigate the environmental catalytic reactions and applications of GDY-based SACs. We provide a detailed account of the current methodologies for synthesizing GDY and examine the catalytic applications of GDY-based SACs in CO₂ reduction reactions. Specifically, we systematically categorize the photocatalytic and electrocatalytic CO₂ reduction processes using metal-doped GDY and metal-free doped GDY. Finally, we discuss the challenges and future developments of GDY within the context of SACs.
- Single atom-based catalysts (SACs),
- Graphdiyne (GDY),
- CO₂ reduction reaction (CO₂RR),
- Photo/electro-conversion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Single-atom based graphdiyne catalysts support for CO2 photo/electro-conversion

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通讯作者: 陈斌, bchen63@163.com

Single-atom based graphdiyne catalysts support for CO₂ photo/electro-conversion