Photoexcited Ni-catalyzed regioselective cross-coupling of aryl chlorides with multifluoroarenes
-
*Corresponding authors.
E-mail addresses: mingjialin@cdu.edu.cn (J. Ming), dgyu@scu.edu.cn (D.-G. Yu).
Citation:
Jie Liu, Jialin Ming, Da-Gang Yu. Photoexcited Ni-catalyzed regioselective cross-coupling of aryl chlorides with multifluoroarenes[J]. Chinese Chemical Letters,
;2026, 37(5): 112260.
doi:
10.1016/j.cclet.2025.112260
R. Berger, G. Resnati, P. Metrangolo, et al., Chem. Soc. Rev. 40 (2011) 3496.
doi: 10.1039/c0cs00221f
P. Xiao, X. Pannecoucke, J.P. Bouillon, et al., Chem. Soc. Rev. 50 (2021) 6094–6151.
doi: 10.1039/d1cs00216c
Y.J. Chen, W.H. Deng, J.D. Guo, et al., J. Am. Chem. Soc. 144 (2022) 17261–17268.
doi: 10.1021/jacs.2c08068
Z.Y. Bo, S.S. Yan, T.Y. Gao, et al., Chin. J. Catal. 43 (2022) 2388–2394.
Z. Liu, C. Du, J. Han, et al., Nat. Chem. 17 (2025) 1655–1665.
doi: 10.1038/s41557-025-01962-1
Jiyang Liu , Xiangzhang Tao , Zhenlei Zou , Jia Xu , Hui Shu , Yi Pan , Weigang Zhang , Shengyang Ni , Yi Wang . Modular and practical synthesis of gem-difluoroalkenes via consecutive Ni-catalyzed reductive cross-coupling. Chinese Chemical Letters, 2025, 36(7): 110461-. doi: 10.1016/j.cclet.2024.110461
Yuhan Liu , Jingyang Zhang , Gongming Yang , Jian Wang . Highly enantioselective carbene-catalyzed δ-lactonization via radical relay cross-coupling. Chinese Chemical Letters, 2025, 36(1): 109790-. doi: 10.1016/j.cclet.2024.109790
Peng Guo , Shicheng Dong , Xiang-Gui Zhang , Bing-Bin Yang , Jun Zhu , Ke-Yin Ye . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates. Chinese Chemical Letters, 2025, 36(4): 110052-. doi: 10.1016/j.cclet.2024.110052
Junqi Su , Wenhao Liu , Jianjun Wang , Weifen Luo , Yangyang Ma , Leiyang Lv , Zhiping Li . Palladium-catalyzed ring-opening defluorinative cross-coupling of gem-difluorocyclopropanes with fluoromalonates or fluorobis(phenylsulfonyl)methane. Chinese Chemical Letters, 2026, 37(3): 111288-. doi: 10.1016/j.cclet.2025.111288
Rong-Nan Yi , Jun Jiang , Wei-Min He . Pd/NHC-catalyzed ring-opening cross-coupling of gem-difluorocyclopropanes via a 3,3′-reductive elimination pathway. Chinese Chemical Letters, 2026, 37(4): 112163-. doi: 10.1016/j.cclet.2025.112163
Fuyang Yue , Mingxing Li , Fei Yuan , Hongjian Song , Yuxiu Liu , Qingmin Wang . Deboronative cross-coupling enabled by nickel metallaphotoredox catalysis. Chinese Chemical Letters, 2025, 36(12): 111053-. doi: 10.1016/j.cclet.2025.111053
Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
Yang Li , Yanan Dong , Zhihong Wei , Changzeng Yan , Zhen Li , Lin He , Yuehui Li . Fluoride-promoted Ni-catalyzed cyanation of C–O bond using CO2 and NH3. Chinese Chemical Letters, 2025, 36(5): 110206-. doi: 10.1016/j.cclet.2024.110206
Qinghong Zhang , Qiao Zhao , Xiaodi Wu , Li Wang , Kairui Shen , Yuchen Hua , Cheng Gao , Yu Zhang , Mei Peng , Kai Zhao . Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chinese Chemical Letters, 2025, 36(2): 110167-. doi: 10.1016/j.cclet.2024.110167
Jialin Huang , Liying Fu , Zhanyong Tang , Xiaoqiang Ma , Xingda Zhao , Depeng Zhao . Cross-coupling of trifluoromethylarenes with alkynes C(sp)-H bonds and azoles C(sp2)-H bonds via photoredox/copper dual catalysis. Chinese Chemical Letters, 2025, 36(7): 110505-. doi: 10.1016/j.cclet.2024.110505
Zhirong Yang , Shan Wang , Ming Jiang , Gengchen Li , Long Li , Fangzhi Peng , Zhihui Shao . One stone three birds: Ni-catalyzed asymmetric allenylic substitution of allenic ethers, hydroalkylation of 1,3-enynes and double alkylation of enynyl ethers. Chinese Chemical Letters, 2024, 35(8): 109518-. doi: 10.1016/j.cclet.2024.109518
Rong-Nan Yi , Zi-Jian Zhao , Wei-Min He . Photoinduced gold-catalyzed cross-couplings. Chinese Chemical Letters, 2025, 36(7): 111070-. doi: 10.1016/j.cclet.2025.111070
Yanxin Jiang , Kwai Wun Cheng , Zhiping Yang , Jun (Joelle) Wang . Pd-catalyzed enantioselective and regioselective asymmetric hydrophosphorylation and hydrophosphinylation of enynes. Chinese Chemical Letters, 2025, 36(5): 110231-. doi: 10.1016/j.cclet.2024.110231
Junhua Li , Tianci Shen , Yahui Zhuang , Yu Fu , Yian Shi . Pd-Catalyzed highly regioselective migratory hydroesterification of internal olefins with formates. Chinese Chemical Letters, 2025, 36(7): 110599-. doi: 10.1016/j.cclet.2024.110599
Xiao-Bo Liu , Ren-Ming Liu , Xiao-Di Bao , Hua-Jian Xu , Qi Zhang , Yu-Feng Liang . Nickel-catalyzed reductive formylation of aryl halides via formyl radical. Chinese Chemical Letters, 2024, 35(12): 109783-. doi: 10.1016/j.cclet.2024.109783
Yongli Liu , Dan Xu , Yuanyuan Ping , Nengzhong Wang , Wangqing Kong . Enantioselective synthesis of α-aryl ketones via cross-hydroacylation of two distinct alkenes. Chinese Chemical Letters, 2026, 37(3): 111893-. doi: 10.1016/j.cclet.2025.111893
Junxin Li , Chao Chen , Yuzhen Dong , Jian Lv , Jun-Mei Peng , Yuan-Ye Jiang , Daoshan Yang . Ligand-promoted reductive coupling between aryl iodides and cyclic sulfonium salts by nickel catalysis. Chinese Chemical Letters, 2024, 35(11): 109732-. doi: 10.1016/j.cclet.2024.109732
Wujun Jian , Mong-Feng Chiou , Yajun Li , Hongli Bao , Song Yang . Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes. Chinese Chemical Letters, 2024, 35(5): 108980-. doi: 10.1016/j.cclet.2023.108980
Kongchuan Wu , Dandan Lu , Jianbin Lin , Ting-Bin Wen , Wei Hao , Kai Tan , Hui-Jun Zhang . Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene–alkene coupling reactions. Chinese Chemical Letters, 2024, 35(5): 108906-. doi: 10.1016/j.cclet.2023.108906