Recent advances of heterogeneous manganese catalysis in organic synthesis
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* Corresponding authors.
E-mail addresses: feng.chen@yzu.edu.cn (F. Chen), gaopan@yzu.edu.cn (P. Gao).
Citation:
Tianyi Zhou, Heng Yang, Guangbin Zhou, Feng Chen, Pan Gao. Recent advances of heterogeneous manganese catalysis in organic synthesis[J]. Chinese Chemical Letters,
;2026, 37(6): 112223.
doi:
10.1016/j.cclet.2025.112223
M. Kazemi, M. Ghobadi, Nanotechnol. Rev. 6 (2017) 549–571.
doi: 10.1515/ntrev-2016-0113
J.R. Carney, B.R. Dillon, S.P. Thomas, Eur. J. Org. Chem. 2016 (2016) 3912–3929.
doi: 10.1002/ejoc.201600018
J. Wang, Y. Zhang, Y. Zhou, et al., Org. Chem. Front. 11 (2024) 6850–6917.
doi: 10.1039/d4qo01499e
L.J. Li, Y. He, Y. Yang, et al., CCS Chem. 6 (2023) 537–584.
C. Wang, H. Chen, M Mi, et al., Chin. J. Org. Chem. 45 (2025) 2326–2334.
doi: 10.6023/cjoc202412002
R. Sharma, S. Pandey, M. Mohit, D.S. Rawat, Tetrahedron 171 (2025) 134416.
doi: 10.1016/j.tet.2024.134416
S. Kostera, L. Gonsalvi, ChemCatChem 16 (2024) e202301391.
doi: 10.1002/cctc.202301391
R.V. Ottenbacher, A.A. Bryliakova, V.I. Kurganskii, et al., Chem. Eur. J. 29 (2023) e202302772.
doi: 10.1002/chem.202302772
D.C. Lacy, P.C. Abhyankar, Chem. Eur. J. 29 (2023) e202300518.
doi: 10.1002/chem.202300518
K. Das, S. Waiba, A. Jana, B. Maji, Chem. Soc. Rev. 51 (2022) 4386–4464.
doi: 10.1039/d2cs00093h
G. Anusree, P.S. Devi, G. Anilkumar, Adv. Synth. Catal. 366 (2024) 3963–3999.
doi: 10.1002/adsc.202400611
N. Ahmed, J. Organometal. Chem. 1009 (2024) 123071.
doi: 10.1016/j.jorganchem.2024.123071
M.F. Ansari, A.K. Maurya, A. Kumar, S. Elangovan, Beilstein J. Org. Chem. 20 (2024) 1111–1166.
doi: 10.3762/bjoc.20.98
Y. Wang, M. Wang, Y. Li, Q. Liu, Chem 7 (2021) 1180–1223.
doi: 10.1016/j.chempr.2020.11.013
C.M. Friend, B. Xu, Acc. Chem. Res. 50 (2017) 517–521.
doi: 10.1021/acs.accounts.6b00510
F. Zaera, Chem. Rev. 122 (2022) 8594–8757.
doi: 10.1021/acs.chemrev.1c00905
A.N. Fajer, H.A. Al-Bahrani, A.A.H. Kadhum, M. Kazemi, J. Mol. Struct. 1296 (2024) 136800.
doi: 10.1016/j.molstruc.2023.136800
L. Liu, A. Corma, et al., Chem. Rev. 118 (2018) 4981–5079.
doi: 10.1021/acs.chemrev.7b00776
J. Wang, Y. Zhang, X. Guo, et al., Green Chem. 26 (2024) 2365–2383.
doi: 10.1039/d3gc04117d
M. Kazemi, R. Ali, V. Jain, et al., RSC Adv. 15 (2025) 23054–23088.
doi: 10.1039/d5ra02493e
M. Kazemi, R. Ali, V. Jain, et al., RSC Adv. 15 (2025) 23054–23088.
doi: 10.1039/D5RA02493E
B.G. Reed-Berendt, D.E. Latham, M.B. Dambatta, L.C. Morrill, ACS Cent. Sci. 7 (2021) 570–585.
doi: 10.1021/acscentsci.1c00125
K.R. Rohit, S. Radhika, S. Saranya, G. Anilkumar, Adv. Synth. Catal. 362 (2020) 1602–1650.
doi: 10.1002/adsc.201901389
S. Mullick, A. Ghosh, D. Banerjee, Chem. Commun. 60 (2024) 4002–4014.
doi: 10.1039/d4cc00003j
Y. Qiu, Y. Zhang, L. Jin, et al., Org. Chem. Front. 6 (2019) 3420–3427.
doi: 10.1039/c9qo00892f
Y. Kita, M. Kuwabara, K. Kamata, M. Hara, ACS Catal. 12 (2022) 11767–11775.
doi: 10.1021/acscatal.2c03085
M.S. Ahmad, Y. Inomata, T. Kida, Mol. Catal. 526 (2022) 112390.
G. Dey, S. Saifi, M. Sk, et al., Dalton Trans. 51 (2022) 17973–17977.
doi: 10.1039/d2dt02629e
R. Swaathy, S. Karthikeyan, ACS Omega 10 (2025) 9649–9660.
doi: 10.1021/acsomega.4c10938
P. Sudarsanam, B. Hillary, M.H. Amin, S.B.A. Hamid, S.K. Bhargava, Appl. Catal. B: Environ. 185 (2016) 213–224.
doi: 10.1016/j.apcatb.2015.12.026
F. Chen, T. Yang, S. Zhao, et al., Chin. Chem. Lett. 30 (2019) 2282–2286.
doi: 10.1016/j.cclet.2019.09.007
Q. Hao, X. Jia, J. Ma, et al., Chem. Asian J. 16 (2021) 1388–1391.
doi: 10.1002/asia.202100264
M. Subaramanian, P.M. Ramar, G. Sivakumar, et al., ChemCatChem 13 (2021) 4334–4341.
doi: 10.1002/cctc.202100635
C. Wu, J. Bu, W. Wang, et al., Ind. Eng. Chem. Res. 61 (2022) 5442–5452.
doi: 10.1021/acs.iecr.2c00311
T. Chutimasakul, W. Tirdtrakool, P. Na Nakhonpanom, et al., ChemistrySelect 7 (2022) e202203028.
doi: 10.1002/slct.202203028
A. Kumar, N.A. Espinosa-Jalapa, G. Leitus, et al., Angew. Chem. Int. Ed. 56 (2017) 14992–14996.
doi: 10.1002/anie.201709180
J. Guo, J. Tang, H. Xi, S.Y. Zhao, W. Liu, Chin. Chem. Lett. 34 (2023) 107731.
doi: 10.1016/j.cclet.2022.08.011
K. Yamaguchi, H. Kobayashi, T. Oishi, N. Mizuno, Angew. Chem. Int. Ed. 51 (2012) 544–547.
doi: 10.1002/anie.201107110
H. Wang, Q. Luo, L. Wang, et al., Chin. J. Catal. 42 (2021) 2164–2172.
doi: 10.1016/S1872-2067(21)63803-2
P. He, B. Chen, L. Huang, et al., Chem 8 (2022) 1906–1927.
doi: 10.1016/j.chempr.2022.02.021
X. Liu, B. Han, C. Wu, et al., Angew. Chem. Int. Ed. 64 (2024) e202413799.
B. Li, C. Li, L. Tian, et al., New J. Chem. 42 (2018) 15985–15989.
doi: 10.1039/c8nj02551g
J. Shen, X. Meng, Catal. Commun. 127 (2019) 58–63.
doi: 10.1016/j.catcom.2019.05.005
N. Yao, X. Bi, L. Zhang, et al., Mol. Catal. 504 (2021) 111499.
N. Liu, F. Chao, Y. Huang, et al., Tetrahedron Lett. 60 (2019) 151259.
doi: 10.1016/j.tetlet.2019.151259
F. Sun, J. Qin, X. Cao, et al., ACS Sustain. Chem. Eng. 10 (2022) 9087–9095.
doi: 10.1021/acssuschemeng.2c01703
S. Khamarui, Y. Saima, SynOpen 06 (2022) 173–178.
doi: 10.1055/a-1896-3987
Y. Ji, A.N. Blankenship, J.A. van Bokhoven, ACS Catal. 13 (2023) 3896–3901.
doi: 10.1021/acscatal.2c06292
M.E. Assal, M.R. Shaik, M. Kuniyil, et al., RSC Adv. 7 (2017) 55336–55349.
doi: 10.1039/C7RA11569E
J. Yang, K. Cao, M. Gong, B. Shan, R. Chen, J. Catal. 386 (2020) 60–69.
doi: 10.1016/j.jcat.2020.03.029
B. Liao, S. Li, J. Catal. 414 (2022) 294–301.
doi: 10.1016/j.jcat.2022.09.021
K. Kamata, N. Kinoshita, M. Koutani, et al., Catal. Sci. Technol. 12 (2022) 6219–6230.
doi: 10.1039/d2cy01476a
B. Maleki, R. Sandaroos, S. Naderi, S. Peiman, J. Organometal. Chem. 990 (2023).
J. Tang, J. Chen, Z. Zhang, et al., Chem. Sci. 14 (2023) 13402–13409.
doi: 10.1039/d3sc04418a
H. Chen, Y. Li, L. Yu, et al., Catal. Lett. 152 (2022) 3716–3724.
doi: 10.1007/s10562-022-03945-0
X. Liao, M. Guo, W. Tang, et al., Green Chem. 24 (2022) 8424–8433.
doi: 10.1039/d2gc01769e
V. Escande, C.H. Lam, C. Grison, P.T. Anastas, ACS Sustain. Chem. Eng. 5 (2017) 3214–3222.
doi: 10.1021/acssuschemeng.6b02979
V. Escande, C.H. Lam, P. Coish, P.T. Anastas, Angew. Chem. Int. Ed. 56 (2017) 9561–9565.
doi: 10.1002/anie.201705934
Q.S. Kong, X.L. Li, H.B. Shen, H.J. Xu, Y. Fu, Green Energy Environ. 7 (2022) 957–964.
doi: 10.1016/j.gee.2020.12.007
X. Yu, T. Jin, H. Wang, et al., Green Energy Environ. 8 (2023) 1683–1692.
doi: 10.1016/j.gee.2022.03.016
S. Biswas, H.S. Khanna, Q.A. Nizami, et al., Sci. Rep. 8 (2018) 13649.
doi: 10.1038/s41598-018-31729-3
B. Wang, J. Lin, Q. Sun, C. Xia, W. Sun, ACS Catal. 11 (2021) 10964–10973.
doi: 10.1021/acscatal.1c02738
E. Hayashi, T. Tamura, T. Aihara, K. Kamata, M. Hara, ACS Appl. Mater. Interfaces 14 (2022) 6528–6537.
doi: 10.1021/acsami.1c20080
S. Movahedian, A.R. Farahani, A.R. Faraji, J. Alloys Compd. 908 (2022) 164585.
doi: 10.1016/j.jallcom.2022.164585
W.F. Xu, W.J. Chen, D.C. Li, B.H. Cheng, H. Jiang, Ind. Eng. Chem. Res. 58 (2019) 3969–3977.
doi: 10.1021/acs.iecr.8b05328
L. Chen, J. Ding, J. Jia, et al., ACS Appl. Nano Mat. 2 (2019) 4417–4426.
doi: 10.1021/acsanm.9b00818
A. Khorshidi, M. Panahdar, R. Badihi, Catal. Lett. 154 (2024) 3309–3322.
doi: 10.1007/s10562-023-04557-y
B. Chen, L. Zhang, H. Luo, et al., JACS Au 3 (2023) 476–487.
doi: 10.1021/jacsau.2c00608
A.W. Stubbs, L. Braglia, E. Borfecchia, et al., ACS Catal. 8 (2017) 596–601.
S. Manimaran, K. Subramanian, R. Tschentscher, A. Pandurangan, J. Porous Mat. 29 (2021) 357–369.
M. Du, Y. Sun, J. Zhao, et al., Chin. Chem. Lett. 34 (2023) 108269.
doi: 10.1016/j.cclet.2023.108269
K. Mullick, S. Biswas, A.M. Angeles-Boza, S.L. Suib, Chem. Commun. 53 (2017) 2256–2259.
doi: 10.1039/C6CC09095H
W. Zhou, Q. Tao, F. a. Sun, et al., J. Catal. 361 (2018) 1–11.
X. Bi, T. Tang, X. Meng, et al., Catal. Sci. Technol. 10 (2020) 360–371.
doi: 10.1039/c9cy01968e
T. Tang, X. Bi, X. Meng, et al., Tetrahedron Lett. 61 (2020) 151425.
doi: 10.1016/j.tetlet.2019.151425
H.T. Tang, H.Y. Zhou, Y.M. Pan, et al., Angew. Chem. Int. Ed. 63 (2023) e202315032.
H. Wang, Y. Wang, H. Xu, et al., Ind. Eng. Chem. Res. 58 (2019) 17319–17324.
doi: 10.1021/acs.iecr.9b04128
F. Bourriquen, N. Rockstroh, S. Bartling, K. Junge, M. Beller, et al., Angew. Chem. Int. Ed. 61 (2022) e202202423.
doi: 10.1002/anie.202202423
J. Li, R.L. Smith, S. Xu, et al., Green Chem. 24 (2022) 315–324.
doi: 10.1039/D1GC03637H
L.A. Siddig, R.H. Alzard, H.L. Nguyen, et al., ACS Omega 7 (2022) 9958–9963.
doi: 10.1021/acsomega.2c00663
M.S. Ahmad, Y. Nagata, K. Masumoto, et al., Mol. Catal. 553 (2024) 113787.
Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
Chun Yin , Shuli Wang , Fulin Yang , Ligang Feng . Carbon-constrained heterogeneous Ni-Mo telluride for efficient urea oxidation. Chinese Chemical Letters, 2026, 37(6): 110999-. doi: 10.1016/j.cclet.2025.110999
Yunlong Sun , Wei Ding , Yanhao Wang , Zhening Zhang , Ruyun Wang , Yinghui Guo , Zhiyuan Gao , Haiyan Du , Dong Ma . New insight into manganese-enhanced abiotic degradation of microplastics: Processes and mechanisms. Chinese Chemical Letters, 2025, 36(3): 109941-. doi: 10.1016/j.cclet.2024.109941
Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
Heng Yang , Zhijie Zhou , Conghui Tang , Feng Chen . Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds. Chinese Chemical Letters, 2024, 35(6): 109257-. doi: 10.1016/j.cclet.2023.109257
Shuai Tang , Zian Wang , Mengyi Zhu , Xinyun Zhao , Xiaoyun Hu , Hua Zhang . Synthesis of organoboron compounds via heterogeneous C–H and C–X borylation. Chinese Chemical Letters, 2025, 36(5): 110503-. doi: 10.1016/j.cclet.2024.110503
Wen-Jing Li , Jun-Bo Wang , Yu-Heng Liu , Mo Zhang , Zhan-Hui Zhang . Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids. Chinese Chemical Letters, 2025, 36(3): 110001-. doi: 10.1016/j.cclet.2024.110001
Juntao Cai , Qian Wang , Xu Shen , Lifeng Zhu , Shiqing Jiang , Jian Yin , Chunhong Dong . Chemical strategies for the stereoselective construction of 1,2-cis-galacturonic and aminogalacturonic acid glycosides. Chinese Chemical Letters, 2026, 37(5): 112235-. doi: 10.1016/j.cclet.2025.112235
Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
Wenjuan Liu , Shanshan Zhang , Yu Wang , Bin Fang , Weirui Wang , Shujing Song , Tomohiro Hakozaki . Three-channel imaging reveals the comprehensive protein modifications and their impact on skin appearance induced by multiple stimuli. Chinese Chemical Letters, 2025, 36(6): 111182-. doi: 10.1016/j.cclet.2025.111182
Kuanhong Cao , Sainan Chu , Yuanhua Ding , Shanming Lu , Lei Yu , Juan Du . Sustainable Se/C catalysts from carbohydrates: Unlocking oxidative deoximation reaction with high turnover numbers via free radical mechanisms. Chinese Chemical Letters, 2026, 37(1): 111486-. doi: 10.1016/j.cclet.2025.111486
Hua Liu , Jian Zhao , Qi Li , Xiang-Yu Zhang , Zhi-Wei Zheng , Kun Huang , Da-Bin Qin , Bin Zhao . Indium-captured zirconium-porphyrin frameworks displaying rare multi-selectivity for catalytic transfer hydrogenation of aldehydes and ketones. Chinese Chemical Letters, 2025, 36(6): 110593-. doi: 10.1016/j.cclet.2024.110593
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Shuangyu Wu , Jian Peng , Yue Jiang , Sijie Lin . The overlooked promotional effects of alcohols to BiOBr catalysts in photocatalytic degradation of organic pollutants. Chinese Chemical Letters, 2025, 36(11): 110819-. doi: 10.1016/j.cclet.2025.110819
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