Citation: Brij Mohan, Rakesh Kumar Gupta, Matlab Khamiyev, Xiaoping Zhang, Ismayil M. Garazade, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Wei Sun. Understanding hydrogen-bonded organic frameworks in the separation of noble gases and lighter hydrocarbons[J]. Chinese Chemical Letters, ;2026, 37(5): 112142. doi: 10.1016/j.cclet.2025.112142 shu

Understanding hydrogen-bonded organic frameworks in the separation of noble gases and lighter hydrocarbons

a.
Hainan International Joint Research Center of Marine Advanced Photoelectric Functional Materials, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China
b.
Centro de Química Estrutural, Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
c.
Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China
d.
Institute of Petrochemical Processes named after Academician Yusif Mammadaliyev, Ministry of Science and Education of the Republic of Azerbaijan, Khojaly Av. 30, AZ1025, Baku, Azerbaijan

brij.mohan@tecnico.ulisboa.pt

rkg@sdu.edu.cn

sunwei@hainnu.edu.cn

Received Date: 15 May 2025
Revised Date: 24 September 2025
Accepted Date: 20 November 2025
Available Online: 21 November 2025

Figures(6)

Hydrogen-bonded frameworks (HOFs) are attracting interest for industrial and environmental applications. This review emphasizes recent developments in HOFs, concentrating on their structural characteristics, types of hydrogen bonding, and the connections that affect their mechanical properties and environmental responsiveness. It highlights hinge-like flexibility, rigidity, and framework retention, which enhance adaptability and structural integrity while trapping gases. A proposed mechanism for the selective adsorption of noble gases and light hydrocarbons emphasizes their potential in gas storage and environmental remediation. Overall, HOFs are presented as versatile materials ready to tackle emerging industrial challenges.
- Hydrogen-bonded frameworks (HOFs),
- Hinge-like flexibility,
- Separation,
- Noble gases,
- Hydrocarbons
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沈阳化工大学材料科学与工程学院沈阳 110142