Citation: Zhaojun Chen, Yongqi Wang, Yongshun Liang, Liang Shan, Ying Wang, Jiyue Hou, Ziyi Zhu, Xue Li, Yiyong Zhang. In-situ polymerization technology for all-solid state lithium batteries: Current status and future development[J]. Chinese Chemical Letters, ;2026, 37(6): 112020. doi: 10.1016/j.cclet.2025.112020 shu

In-situ polymerization technology for all-solid state lithium batteries: Current status and future development

Zhaojun Chen ^a ,
Yongqi Wang ^a ,
Yongshun Liang ^a ,
Liang Shan ^b ,
Ying Wang ^c ,
Jiyue Hou ^{a, *,} ,
Ziyi Zhu ^a ,
Xue Li ^{a, *,} ,
Yiyong Zhang ^{a, *,}

a.
National and Local Joint Engineering Research Center for Lithium-ion Batteries and Materials Preparation Technology, School of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
School of Chemical Science and Technology, Yunnan University, Kunming 650091, China
c.
College of Electrical Information Engineering, Panzhihua University, Panzhihua 617000, China

hgeneral_jy@163.com

20150044@kust.edu.cn

zhangyiyong2018@kust.edu.cn

Received Date: 6 July 2025
Revised Date: 17 October 2025
Accepted Date: 22 October 2025
Available Online: 24 October 2025

Figures(7)

The utilization of solid electrolytes as substitutes for flammable liquid electrolytes represents a crucial strategy for enhancing both the safety and energy density of lithium metal batteries. However, the poor solid-solid contact between electrodes/electrolytes and the inherent difficulties of Li dendrite growth have seriously hindered their practical applications. Among the various types of solid electrolytes, polymer electrolytes are highly regarded for their potential high ionic conductivity, good deformability, and wide electrochemical window. In-situ curing technology has been demonstrated to be an effective solution to these problems and shows great application prospects in polymer electrolyte all-solid-state lithium-metal batteries. This paper will provide a comprehensive review of the three primary types of polymerization methods: free radical polymerization, ring-opening metathesis polymerization, and ionic polymerization. The technical principles, research progress, and performance optimization of in-situ polymerized solid state electrolytes will be reviewed, and the review will look forward to the future development of in-situ curing. The emerging challenges faced by the field and the potential opportunities in practical applications will be pointed out. As research progresses and technology advances, in-situ curing technology is poised to reinvigorate the development of all-solid-state batteries, propelling them towards enhanced safety, efficiency, and reliability.
- Solid-state electrolytes,
- In-situ polymerization technology,
- Polymer electrolytes,
- Lithium metal batteries,
- Initiators,
- Interfacial stability,
- Lithium dendrite suppression
1. [1]
  Y. Bai, W. Ma, W. Dong, et al., ACS Appl. Mater. Interfaces 15 (2023) 26834–26842. doi: 10.1021/acsami.3c04234
2. [2]
  J. Chai, Z. Liu, J. Ma, et al., Adv. Sci. 4 (2017) 1600377. doi: 10.1002/advs.201600377
3. [3]
  J. Chai, Z. Liu, J. Zhang, et al., ACS Appl. Mater. Interfaces 9 (2017) 17897–17905. doi: 10.1021/acsami.7b02844
4. [4]
  Y. Cui, X. Liang, J. Chai, et al., Adv. Sci. 4 (2017) 1700174. doi: 10.1002/advs.201700174
5. [5]
  T. Dong, J. Zhang, G. Xu, et al., Energy Environ. Sci. 11 (2018) 1197–1203. doi: 10.1039/c7ee03365f
6. [6]
  A. Du, H. Zhang, Z. Zhang, et al., Adv. Mater. 31 (2019) 1805930. doi: 10.1002/adma.201805930
7. [7]
  F. Gambino, M. Gastaldi, A. Jouhara, et al., J. Power Source Adv. 30 (2024) 100160. doi: 10.1016/j.powera.2024.100160
8. [8]
  D. Goonetilleke, N. Sharma, J. Kimpton, et al., Front. Energy Res. 6 (2018) 64. doi: 10.3389/fenrg.2018.00064
9. [9]
  W. Han, J. Zheng, H. Huang, et al., J. Membr. Sci. 713 (2025) 123374. doi: 10.1016/j.memsci.2024.123374
10. [10]
  X. He, J. Lin, G. Ge, et al., J. Power Sources 555 (2023) 232346. doi: 10.1016/j.jpowsour.2022.232346
11. [11]
  J.K. Hu, H. Yuan, S.J. Yang, et al., J. Energy Chem. 71 (2022) 612–618. doi: 10.1016/j.jechem.2022.04.048
12. [12]
  J. Hu, Y. Gao, S. Yang, et al., Adv. Funct. Mater. 34 (2024) 2311633. doi: 10.1002/adfm.202311633
13. [13]
  I. Kim, S. Jang, K.H. Lee, Y. Tak, G. Lee, Energy Storage Mater. 40 (2021) 229–238. doi: 10.1016/j.ensm.2021.05.019
14. [14]
  J. Kim, W. Lee, J. Seok, et al., J. Energy Chem. 66 (2022) 226–236. doi: 10.1016/j.jechem.2021.08.017
15. [15]
  X. Li, C. Wang, W. Nan, et al., Mater. Today Chem. 40 (2024) 102219. doi: 10.1016/j.mtchem.2024.102219
16. [16]
  Z. Li, H.X. Xie, X.Y. Zhang, X. Guo, J. Mater. Chem. A 8 (2020) 3892–3900. doi: 10.1039/c9ta09969g
17. [17]
  C. Liu, F. Zhu, Z. Huang, et al., Chem. Eng. J. 434 (2022) 134644. doi: 10.1016/j.cej.2022.134644
18. [18]
  Q. Lu, C. Wang, D. Bao, et al., Energy Environ. Sci. 6 (2023) e12447.
19. [19]
  Y.Q. Mi, W. Deng, C. He, et al., Angew. Chem. Int. Ed. 62 (2023) e202218621. doi: 10.1002/anie.202218621
20. [20]
  A. Murali, R. Ramesh, M. Sakar, S. Park, S.S. Han, RSC Adv. 14 (2024) 30618–30629. doi: 10.1039/d4ra05134c
21. [21]
  L. Zhang, H. Gao, S. Xiao, et al., ACS Mater. Lett. 4 (2022) 1297–1305. doi: 10.1021/acsmaterialslett.2c00238
22. [22]
  L. Nie, S. Chen, M. Zhang, et al., Nano Res. 17 (2024) 2687–2692. doi: 10.1007/s12274-023-6096-x
23. [23]
  D. Shao, X. Wang, X. Li, et al., J. Solid State Electrochem. 23 (2019) 2785–2792. doi: 10.1007/s10008-019-04382-7
24. [24]
  S.Z. Zhang, X.H. Xia, D. Xie, et al., J. Power Sources 409 (2019) 31–37. doi: 10.3847/1538-4365/aafb32
25. [25]
  X. Yang, F. Su, M. Hou, et al., Dalton Trans. 50 (2021) 7041–7047. doi: 10.1039/d1dt00807b
26. [26]
  C. Wang, K. Fu, S.P. Kammampata, et al., Chem. Rev. 120 (2020) 4257–4300. doi: 10.1021/acs.chemrev.9b00427
27. [27]
  Z. Yao, Y. Kang, M. Hou, et al., Adv. Funct. Mater. 32 (2022) 2111919. doi: 10.1002/adfm.202111919
28. [28]
  D. Zhang, K. Ye, Y. Yao, et al., Carbon 142 (2019) 278–284. doi: 10.1016/j.carbon.2018.10.062
29. [29]
  Z. Wei, J. Huang, Z. Liao, et al., Energy Storage Mater. 72 (2024) 103714. doi: 10.1016/j.ensm.2024.103714
30. [30]
  F. Wu, J. Maier, Y. Yu, Chem. Soc. Rev. 49 (2020) 1569–1614. doi: 10.1039/c7cs00863e
31. [31]
  N. Wu, Y. Li, A. Dolocan, et al., Adv. Funct. Mater. 30 (2020) 2000831. doi: 10.1002/adfm.202000831
32. [32]
  F. Wang, C.M. Yang, Y.Q. Wang, et al., Rare Met. 43 (2024) 1461–1487. doi: 10.1007/s12598-023-02486-8
33. [33]
  F. Wang, R.W. Huang, W.C. Han, et al., Rare Met. 43 (2024) 3661–3676. doi: 10.1007/s12598-024-02704-x
34. [34]
  C. Xu, K. Zhang, D. Zhang, et al., Nano Energy 68 (2020) 104318. doi: 10.1016/j.nanoen.2019.104318
35. [35]
  P. Xu, X. Lin, Z. Sun, et al., J. Energy Chem. 72 (2022) 186–194. doi: 10.1016/j.jechem.2022.04.025
36. [36]
  L. Yang, Y. Mu, L. Zou, et al., Nano Lett. 24 (2024) 13162–13171. doi: 10.1021/acs.nanolett.4c02894
37. [37]
  J. Han, M.J. Lee, K. Lee, et al., Adv. Mater. 35 (2023) 2205194. doi: 10.1002/adma.202205194
38. [38]
  Y. He, X. Shan, Y. Li, et al., Energy Storage Mater. 68 (2024) 103281. doi: 10.1016/j.ensm.2024.103281
39. [39]
  H. Wang, Q. Wang, X. Cao, et al., Adv. Mater. 32 (2020) 2001259. doi: 10.1002/adma.202001259
40. [40]
  Q.K. Zhang, X.Q. Zhang, J. Wan, et al., Nat. Energy 8 (2023) 725–735. doi: 10.1038/s41560-023-01275-y
41. [41]
  Q. Zhou, H. Zhao, C. Fu, et al., Angew. Chem. Int. Ed. 63 (2024) e202402625. doi: 10.1002/anie.202402625
42. [42]
  Q. Liu, Y. Sun, S. Wang, et al., Mater. Today 64 (2023) 21–30. doi: 10.1016/j.mattod.2023.02.011
43. [43]
  D. Zhou, Y. He, R. Liu, et al., Adv. Energy Mater. 5 (2015) 1500353. doi: 10.1002/aenm.201500353
44. [44]
  D. Zhang, Z. Xie, K. Zhang, et al., Chem. Eng. Sci. 241 (2021) 116695. doi: 10.1016/j.ces.2021.116695
45. [45]
  K. Matyjaszewski, Adv. Mater. 30 (2018) 1706441. doi: 10.1002/adma.201706441
46. [46]
  X. Pan, M. Fantin, F. Yuan, K. Matyjaszewski, Chem. Soc. Rev. 47 (2018) 5457–5490. doi: 10.1039/c8cs00259b
47. [47]
  V. Vijayakumar, B. Anothumakkool, S. Kurungot, M. Winter, J.R. Nair, Energy Environ. Sci. 14 (2021) 2708–2788. doi: 10.1039/d0ee03527k
48. [48]
  L. Zhao, Q. Dong, Y. Wang, et al., Angew. Chem. Int. Ed. 63 (2024) e202412280. doi: 10.1002/anie.202412280
49. [49]
  M. Ma, F. Shao, P. Wen, et al., ACS Energy Lett. 6 (2021) 4255–4264. doi: 10.1021/acsenergylett.1c02036
50. [50]
  P. Purohit, A. Bhatt, R.K. Mittal, M.H. Abdellattif, T.A. Farghaly, Front. Bioeng. Biotechnol. 10 (2023) 1044927. doi: 10.3389/fbioe.2022.1044927
51. [51]
  C. Yu, J.K. Ha, M. Park, et al., Chem. Sci. 16 (2025) 11626–11636. doi: 10.1039/d5sc02594j
52. [52]
  H. Gao, Y. Zhou, K. Wang, et al., Adv. Energy Mater. 15 (2025) 2501379. doi: 10.1002/aenm.202501379
53. [53]
  R. Wang, W. Wang, Y. Zhang, et al., Angew. Chem. Int. Ed. 64 (2025) e202417605. doi: 10.1002/anie.202417605
54. [54]
  M. Ma, X. Guo, P. Wen, et al., Angew. Chem. Int. Ed. 63 (2024) e202407304. doi: 10.1002/anie.202407304
55. [55]
  L. Porcarelli, A.S. Shaplov, F. Bella, et al., ACS Energy Lett. 1 (2016) 678–682. doi: 10.1021/acsenergylett.6b00216
56. [56]
  C. Cao, Y. Li, Y. Feng, et al., J. Mater. Chem. A 5 (2017) 22519–22526. doi: 10.1039/C7TA05787C
57. [57]
  Z. Lin, X. Guo, Z. Wang, et al., Nano Energy 73 (2020) 104786. doi: 10.1016/j.nanoen.2020.104786
58. [58]
  S.J. Tan, J. Yue, Y.F. Tian, et al., Energy Storage Mater. 39 (2021) 186–193. doi: 10.1016/j.ensm.2021.04.020
59. [59]
  X. Zhang, M. Jia, Q. Zhang, et al., Chem. Eng. J. 448 (2022) 137743. doi: 10.1016/j.cej.2022.137743
60. [60]
  H. Zhang, L. Huang, H. Xu, et al., eScience 2 (2022) 201–208. doi: 10.1016/j.esci.2022.03.001
61. [61]
  Z. Sun, K. Xi, J. Chen, et al., Nat. Commun. 13 (2022) 3209. doi: 10.1007/s00170-021-08080-5
62. [62]
  S. Zhang, F. Sun, X. Du, et al., Energy Environ. Sci. 16 (2023) 2591–2602. doi: 10.1039/d3ee00558e
63. [63]
  S. Han, P. Wen, H. Wang, et al., Nat. Mater. 22 (2023) 1515–1522. doi: 10.1038/s41563-023-01693-z
64. [64]
  H. Peng, T. Long, J. Peng, et al., Adv. Energy Mater. 14 (2024) 2400428. doi: 10.1002/aenm.202400428
65. [65]
  X. Rui, R. Hua, D. Ren, et al., Adv. Mater. 36 (2024) 2402401. doi: 10.1002/adma.202402401
66. [66]
  R. Tong, Y. Huang, C. Feng, Y. Dong, C. Wang, Adv. Funct. Mater. 34 (2024) 2315777. doi: 10.1002/adfm.202315777
67. [67]
  M.H. Nguyen, D. Kim, B. Kim, S. Park, Adv. Funct. Mater. (2024) 2407179.
68. [68]
  Y. Su, X. Rong, A. Gao, et al., Nat. Commun. 13 (2022) 4181. doi: 10.1038/s41467-022-31792-5
69. [69]
  S. Yang, H. Yuan, N. Yao, et al., Adv. Mater. 36 (2024) 2405086. doi: 10.1002/adma.202405086
70. [70]
  Z. Xie, Y. Zhou, C. Ling, et al., Chin. Chem. Lett. 33 (2022) 1407–1411. doi: 10.1016/j.cclet.2021.08.031
71. [71]
  S. Zheng, L. Mo, K. Chen, et al., Adv. Funct. Mater. 32 (2022) 2201430. doi: 10.1002/adfm.202201430
72. [72]
  T. Liu, R. Parekh, P. Mocny, et al., ACS Mater. Lett. 5 (2023) 2594–2603. doi: 10.1021/acsmaterialslett.3c00485
73. [73]
  Z. Shen, J. Zhong, S. Jiang, et al., ACS Appl. Mater. Interfaces 14 (2022) 41022–41036. doi: 10.1021/acsami.2c11397
74. [74]
  S. Gao, Z. Li, Z. Zhang, et al., Energy Storage Mater. 55 (2023) 214–224. doi: 10.1016/j.ensm.2022.11.049
75. [75]
  K. Guo, J. Wang, Z. Shi, et al., Angew. Chem. Int. Ed. 62 (2023) e202213606. doi: 10.1002/anie.202213606
76. [76]
  K. Guo, S. Li, J. Wang, et al., ACS Energy Lett. 9 (2024) 843–852. doi: 10.1021/acsenergylett.3c02422
77. [77]
  J. Hu, W. Wang, B. Zhou, et al., J. Membr. Sci. 575 (2019) 200–208. doi: 10.1016/j.memsci.2019.01.025
78. [78]
  B. Zhou, T. Deng, C. Yang, et al., Adv. Funct. Mater. 33 (2023) 2212005. doi: 10.1002/adfm.202212005
79. [79]
  Y. Zhan, P. Zhai, T. Song, W. Yang, Y. Li, Chem. Eng. J. 491 (2024) 151974. doi: 10.1016/j.cej.2024.151974
80. [80]
  T. Jin, M. Liu, K. Su, et al., ACS Appl. Mater. Interfaces 13 (2021) 57489–57496. doi: 10.1021/acsami.1c19479
81. [81]
  F. Makhlooghiazad, L. Miguel Guerrero Mejía, G. Rollo-Walker, et al., J. Am. Chem. Soc. 146 (2024) 1992–2004. doi: 10.1021/jacs.3c10510
82. [82]
  B. Kim, M.J. Park, Mater. Horiz. 10 (2023) 4139–4147. doi: 10.1039/d3mh00913k
83. [83]
  C. Sun, H. Zhang, P. Mu, et al., ACS Nano 18 (2024) 2475–2484. doi: 10.1021/acsnano.3c11286
84. [84]
  S. Jiang, B. Hu, Z. Shi, et al., Adv. Funct. Mater. 30 (2020) 1908558. doi: 10.1002/adfm.201908558
85. [85]
  Y. Xie, K. Zhang, Y. Yamauchi, K. Oyaizu, Z. Jia, Mater. Horiz. 8 (2021) 803–829. doi: 10.1039/d0mh01391a
86. [86]
  Y. Xiong, Z. Wang, Y. Li, Y. Chen, L. Dong, J. Am. Chem. Soc. 146 (2024) 22777–22786. doi: 10.1021/jacs.4c07941
87. [87]
  M. Scholl, S. Ding, C.W. Lee, R.H. Grubbs, Org. Lett. 1 (1999) 953–956. doi: 10.1021/ol990909q
88. [88]
  A.A. Nagarkar, A.F.M. Kilbinger, Nat. Chem. 10 (2018) 573–573. doi: 10.1038/s41557-018-0044-5
89. [89]
  J. Xu, N. Hadjichristidis, Prog. Polym. Sci. 139 (2023) 101656. doi: 10.1016/j.progpolymsci.2023.101656
90. [90]
  P.V. Wright, Electrochim. Acta 43 (1998) 1137–1143. doi: 10.1016/S0013-4686(97)10011-1
91. [91]
  K. Mu, W. Dong, W. Xu, et al., Adv. Funct. Mater. (2024) 2405969.
92. [92]
  T. Yang, W. Zhang, Y. Liu, et al., Small 19 (2023) 2303210. doi: 10.1002/smll.202303210
93. [93]
  Y. Liu, H. Zou, Z. Huang, et al., Energy Environ. Sci. 16 (2023) 6110–6119. doi: 10.1039/d3ee02797j
94. [94]
  T. Li, K. Chen, B. Yang, et al., Chem. Sci. 15 (2024) 12108–12117. doi: 10.1039/d4sc02010c
95. [95]
  G. Li, K. Liang, Y. Li, et al., Nano Res. 17 (2024) 5216–5223. doi: 10.1007/s12274-024-6463-2
96. [96]
  Q. Hao, Y. Gao, F. Chen, et al., Chem. Eng. J. 481 (2024) 148666. doi: 10.1016/j.cej.2024.148666
97. [97]
  J. Zheng, W. Zhang, C. Huang, et al., Mater. Today Energy 26 (2022) 100984. doi: 10.1016/j.mtener.2022.100984
98. [98]
  W. Tang, T. Zhou, Y. Duan, et al., Carbon Neutral. 3 (2024) 386–395. doi: 10.1002/cnl2.130
99. [99]
  A.G. Nguyen, M.H. Lee, J. Kim, C.J. Park, Nano-Micro Lett. 16 (2024) 83. doi: 10.1007/s40820-023-01294-0
100. [100]
  K. Mu, D. Wang, W. Dong, et al., Adv. Mater. 35 (2023) 2304686. doi: 10.1002/adma.202304686
101. [101]
  S. Zou, Y. Yang, J. Wang, et al., Energy Environ. Sci. 17 (2024) 4426–4460. doi: 10.1039/d4ee00822g
102. [102]
  S. Qin, Y. Yu, J. Zhang, et al., Adv. Energy Mater. 13 (2023) 2301470. doi: 10.1002/aenm.202301470
103. [103]
  Y.Q. Mi, W. Deng, C. He, et al., Angew. Chem. 135 (2023) e202218621. doi: 10.1002/ange.202218621
104. [104]
  Y. Cui, J. Chai, H. Du, et al., ACS Appl. Mater. Interfaces 9 (2017) 8737–8741. doi: 10.1021/acsami.6b16218
105. [105]
  D. Guo, D.B. Shinde, W. Shin, et al., Adv. Mater. 34 (2022) 2201410. doi: 10.1002/adma.202201410
106. [106]
  H. Zhou, H. Liu, Y. Li, et al., J. Mater. Chem. A 7 (2019) 16984–16991. doi: 10.1039/c9ta02341k
107. [107]
  Q.J. Meisner, S. Jiang, P. Cao, et al., J. Mater. Chem. A 9 (2021) 25927–25933. doi: 10.1039/d1ta08244b
108. [108]
  F.Q. Liu, W.P. Wang, Y.X. Yin, et al., Sci. Adv. 4 (2018) eaat5383. doi: 10.1126/sciadv.aat5383
109. [109]
  S.S. Hwang, C.G. Cho, H. Kim, Electrochem. Commun. 12 (2010) 916–919. doi: 10.1016/j.elecom.2010.04.020
110. [110]
  Q. Zhao, X. Liu, S. Stalin, K. Khan, L.A. Archer, Nat. Energy 4 (2019) 365–373. doi: 10.1038/s41560-019-0349-7
111. [111]
  J.R. Nair, I. Shaji, N. Ehteshami, et al., M. Winter, Chem. Mater. 31 (2019) 3118–3133. doi: 10.1021/acs.chemmater.8b04172
112. [112]
  D. Chen, M. Zhu, P. Kang, et al., Adv. Sci. 9 (2022) 2103663. doi: 10.1002/advs.202103663
113. [113]
  J. Xiang, Y. Zhang, B. Zhang, et al., Energy Environ. Sci. 14 (2021) 3510–3521. doi: 10.1039/d1ee00049g
114. [114]
  S. Wen, C. Luo, Q. Wang, et al., Energy Storage Mater. 47 (2022) 453–461. doi: 10.1016/j.ensm.2022.02.035
115. [115]
  J. Zhu, J. Zhang, R. Zhao, et al., Energy Storage Mater. 57 (2023) 92–101. doi: 10.1016/j.ensm.2023.02.012
116. [116]
  Z. Li, J. Fu, X. Zhou, et al., Adv. Sci. 10 (2023) 2201718. doi: 10.1002/advs.202201718
117. [117]
  X. Liu, H. Jia, H. Li, Energy Storage Mater. 67 (2024) 103263. doi: 10.1016/j.ensm.2024.103263
118. [118]
  Y. Seo, Y.C. Jung, M.S. Park, D.W. Kim, J. Membr. Sci. 603 (2020) 117995. doi: 10.1016/j.memsci.2020.117995
119. [119]
  A. Mahmood, J. Energy Chem. 24 (2015) 686–692. doi: 10.1016/j.jechem.2015.10.018
120. [120]
  X. Liu, Z. Xiao, H. Peng, et al., Chem. Asian J. 17 (2022) e202200929. doi: 10.1002/asia.202200929
121. [121]
  N. Zhao, Y. Zou, X. Chen, et al., Colloid Surf. Physicochem. Eng. Asp. 666 (2023) 131317. doi: 10.1016/j.colsurfa.2023.131317
122. [122]
  Q. Zhang, K. Liu, F. Ding, X. Liu, Nano Res. 10 (2017) 4139–4174. doi: 10.1007/s12274-017-1763-4
123. [123]
  D. Zhang, L. Li, X. Wu, et al., Front. Energy Res. 9 (2021) 726738. doi: 10.3389/fenrg.2021.726738
124. [124]
  T. Uno, H. Sano, M. Matsumoto, M. Kubo, T. Itoh, J. Solid State Electrochem. 14 (2010) 2161–2167. doi: 10.1007/s10008-009-0999-7
125. [125]
  M. Jia, T. Li, D. Yang, et al., Batteries 9 (2023) 488. doi: 10.3390/batteries9100488
126. [126]
  A.E. Abdelmaoula, L. Du, L. Xu, et al., Sci. China Mater. 65 (2022) 1476–1484. doi: 10.1007/s40843-021-1940-2
127. [127]
  Z. Xiao, T. Long, L. Song, Y. Zheng, C. Wang, Ionics 28 (2022) 15–26. doi: 10.1007/s11581-021-04340-2
128. [128]
  J. Chattopadhyay, T.S. Pathak, D.M.F. Santos, Polymers 15 (2023) 3907. doi: 10.3390/polym15193907
129. [129]
  Z. Zhu, M. Xue, X. Wu, et al., Chem. Eng. J. 514 (2025) 163402. doi: 10.1016/j.cej.2025.163402
130. [130]
  G. Xiao, K. Yang, Y. Qiu, et al., Adv. Mater. 37 (2025) 2415411. doi: 10.1002/adma.202415411
131. [131]
  H. Xu, J. Mi, J. Ma, et al., Energy Environ. Sci. 18 (2025) 4231–4240. doi: 10.1039/d4ee05606j
132. [132]
  Y. Yang, J. Li, S. Guo, et al., J. Colloid. Interface Sci. 699 (2025) 138306. doi: 10.1016/j.jcis.2025.138306
133. [133]
  C. Wang, Z. Xia, G. Bai, et al., J. Energy Storage 132 (2025) 117730. doi: 10.1016/j.est.2025.117730
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142