Citation: Jinrui Qian, Yue Sun, Feixiang Long, Yiqing Liu, Guozhen Chang, Yuzhu Song, Naike Shi, Andrea Sanson, Xiuzhu Han, Chang Zhou, Jun Chen. Significantly improving the performances of thermal conductivity and thermal expansion in aluminum matrix composites through a multiphase design strategy[J]. Chinese Chemical Letters, ;2026, 37(7): 111849. doi: 10.1016/j.cclet.2025.111849 shu

Significantly improving the performances of thermal conductivity and thermal expansion in aluminum matrix composites through a multiphase design strategy

Jinrui Qian ^a ,
Yue Sun ^a ,
Feixiang Long ^a ,
Yiqing Liu ^a ,
Guozhen Chang ^a ,
Yuzhu Song ^a ,
Naike Shi ^a ,
Andrea Sanson ^c ,
Xiuzhu Han ^{a, *,} ,
Chang Zhou ^{a, b, *,} ,
Jun Chen ^a

a.
Beijing Advanced Innovation Center for Materials Genome Engineering, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China
b.
State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
c.
Department of Physics and Astronomy, University of Padova, Padova I-35131, Italy

xiuzhuhan@163.com

changzhou@ustb.edu.cn

Received Date: 11 July 2025
Revised Date: 8 September 2025
Accepted Date: 17 September 2025
Available Online: 17 September 2025

Figures(4)

Developing metal matrix composites with low thermal expansion yet high thermal conductivity (λ) has been an ongoing effort in electronic packaging materials due to the growing demand for high-power applications. However, progress has been hindered by the insufficient thermal expansion suppression of conventional low thermal expansion reinforcements or the low λ of negative thermal expansion reinforcements. In this study, this challenge is overcome via a multiphase design strategy using ZrW₂O₈ and SiC to co-reinforce the aluminum matrix composites. This approach simultaneously combines the advantages of the ZrW₂O₈ for controlling the coefficient of thermal expansion (CTE) and SiC for improving λ. A controlled CTE-λ balance (6.22–9.7 × 10^–⁶ K^-1, 63.1–131.1 W/mK) can be obtained by varying the volume ratio of ZrW₂O₈ to SiC. The CTE of this composite is significantly lower than that of the 50 vol% SiC/Al composite, while its CTE is approximately equal to that of the 45 vol% ZrW₂O₈/Al composite but with a twofold increase in λ. The good thermal performance of this composite can be attributed to the strong interfacial interactions of SiC and the tailored variation in CTE. Furthermore, simulation and experimental results revealed that the residual stress can be effectively relieved through this strategy. This work presents a straightforward structural design and an effective pathway to manufacture composites with excellent integrated properties.
- Metal matrix composites,
- Thermal expansion behavior,
- Thermal conductivity,
- Multiphase design residual stress
1. [1]
  C. Zhou, H. Zhong, H. Lu, et al., Ceram. Int. 49 (2023) 27958-27964. doi: 10.1016/j.ceramint.2023.06.033
2. [2]
  Y. Song, N. Shi, S. Deng, et al., Prog. Mater Sci. 121 (2021) 100835. doi: 10.1016/j.pmatsci.2021.100835
3. [3]
  M. Ai, Y. Song, F. Long, et al., Adv. Sci. 11 (2024) 2404838. doi: 10.1002/advs.202404838
4. [4]
  T. Huber, H. Degischer, G. Lefranc, T. Schmitt, Compos. Sci. Technol. 66 (2006) 2206-2217. doi: 10.1016/j.compscitech.2005.12.012
5. [5]
  P. Gudlur, A. Forness, J. Lentz, et al., Mat. Sci. Eng. A: Struct. 531 (2012) 18-27. doi: 10.1016/j.msea.2011.10.001
6. [6]
  S. Roy, K. Scheell, E. Bucharsky, et al., Mat. Sci. Eng. A: Struct. 743 (2019) 339-348. doi: 10.1016/j.msea.2018.11.100
7. [7]
  T. Nam, G. Requena, P. Degischer, Compos. Part A 39 (2008) 856-865. doi: 10.1016/j.compositesa.2008.01.011
8. [8]
  C. Zhou, Y. Zhou, Q. Zhang, et al., Compos. Part B 211 (2021) 108678. doi: 10.1016/j.compositesb.2021.108678
9. [9]
  J. Guo, M. Fang, Q. Liu, et al., Chin. Chem. Lett. 35 (2024) 108957. doi: 10.1016/j.cclet.2023.108957
10. [10]
  C. Zhou, Q. Zhang, S. Liu, et al., Phys. Chem. Chem. Phys. 19 (2017) 11778-11785. doi: 10.1039/C7CP00676D
11. [11]
  A. Goodwin, M. Calleja, M. Conterio, et al., Science 319 (2008) 794-797. doi: 10.1126/science.1151442
12. [12]
  C. Zhou, Q. Zhang, X. Tan, et al., Material 6 (2019) 100289. doi: 10.1016/j.mtla.2019.100289
13. [13]
  J. Miao, J. Liu, X. Wu, et al., Sci. Eng. Compos. Mater. 25 (2018) 95-100. doi: 10.1515/secm-2015-0402
14. [14]
  H. Cao, Y. Su, D. Zhang, et al., Compos. Part B 223 (2021) 109080. doi: 10.1016/j.compositesb.2021.109080
15. [15]
  H. L., C. Zhou, Y. Song, et al., Nat. Commun. 16 (2005) 211.
16. [16]
  C. Zhou, C. Liu, Y. Zhou, et al., Ceram. Int. 49 (2023) 34074-34082. doi: 10.1016/j.ceramint.2023.08.108
17. [17]
  Y. Zhou, C. Zhou, Z. Wang, et al., Ceram. Int. 48 (2022) 25826-25832. doi: 10.1016/j.ceramint.2022.05.257
18. [18]
  L. Xie, J. Lin, X. Zhong, et al., Ceram. Int. 49 (2023) 35617-35622. doi: 10.1016/j.ceramint.2023.08.240
19. [19]
  C. Zhou, Z. Tang, X. Kong, et al., Acta Mater. 275 (2024) 120076. doi: 10.1016/j.actamat.2024.120076
20. [20]
  Y. Zhou, C. Zhou, Y. Wu, et al., Ceram. Int. 49 (2023) 34472-34480. doi: 10.1016/j.ceramint.2023.08.026
21. [21]
  Y. Zhou, L. Zhang, J. Qian, et al., Material 16 (2023) 5919. doi: 10.3390/ma16175919
22. [22]
  Y. Qiao, N. Xiao, Y. Song, et al., ACS Appl. Mater. Interfaces 12 (2020) 57228-57234. doi: 10.1021/acsami.0c18416
23. [23]
  C. Kennedy, M. White, Solid State Commun. 134 (2005) 271-276. doi: 10.1016/j.ssc.2005.01.031
24. [24]
  B. Dong, C. Wei, J. Lin, et al., J. Mater. Sci. Technol. 213 (2024) 90-97. doi: 10.1109/aixset62544.2024.00018
25. [25]
  B. Dong, X. Guo, P. Tong, et al., J. Alloys Compd. 978 (2024) 173504. doi: 10.1016/j.jallcom.2024.173504
26. [26]
  B. Hang, S. Liu, X. Wang, et al., Mat. Sci. Eng. A: Struct. 804 (2021) 140517. doi: 10.1016/j.msea.2020.140517
27. [27]
  C. Liang, M. Hamidinejad, L. Ma, et al., Carbon156 (2020) 58-66. doi: 10.1016/j.carbon.2019.09.044
28. [28]
  M. Zhou, L. Ren, L. Fan, et al., J. Alloys Compd. 838 (2020) 155274. doi: 10.1016/j.jallcom.2020.155274
29. [29]
  C. Zhou, Y. Zhou, S. Liu, et al., J. Alloys Compd. 907 (2022) 164444. doi: 10.1016/j.jallcom.2022.164444
30. [30]
  C. Ding, W. Gan, X. Hu, et al., Mat. Sci. Eng. A797 (2020) 140105. doi: 10.1016/j.msea.2020.140105
31. [31]
  R. Wang, Y. Tian, X. Gao, L. Jiang, Chin. Chem. Lett. 36 (2025) 110395. doi: 10.1016/j.cclet.2024.110395
32. [32]
  L. Li, P. Ji, M. Huang, et al., Chin. Chem. Lett. 35 (2024) 109144. doi: 10.1016/j.cclet.2023.109144
33. [33]
  T. Long, P. Chen, B. Feng, et al., Chin. Chem. Lett. 35 (2024) 109267. doi: 10.1016/j.cclet.2023.109267
34. [34]
  N. Li, Y. Zhang, Y. Zhang, et al., Mater. Today Phys. 28 (2022) 100901. doi: 10.1016/j.mtphys.2022.100901
35. [35]
  T. Mary, J. Evans, T. Vogt, Science 272 (1996) 90-92. doi: 10.1126/science.272.5258.90
36. [36]
  Y. Sato, Y. Yamamura, K. Saito, Y. Ikuhara, J. Am. Chem. Soc. 134 (2012) 13942-13945. doi: 10.1021/ja305456j
37. [37]
  N. Shi, L. Fan, Y. Xu, et al., Small 20 (2024) 2312289. doi: 10.1002/smll.202312289
38. [38]
  H. Holzer, D. Dunand, J. Mater. Res. 14 (1999) 780-789. doi: 10.1557/JMR.1999.0104
39. [39]
  G. Wu, C. Zhou, Q. Zhang, et al., Scripta Mater. 96 (2015) 29-32. doi: 10.1016/j.scriptamat.2014.10.014
40. [40]
  C. Zhou, Q. Zhang, M. Zhang, G. Wu, J. Alloys Compd. 718 (2017) 356-360. doi: 10.1016/j.jallcom.2017.05.215
41. [41]
  A. Ramirez, G. Kowach, Phys. Rev. Lett. 80 (1998) 4903-4906. doi: 10.1103/PhysRevLett.80.4903
42. [42]
  J. Sethi, S. Das, K. Das, J. Alloys Compd. 774 (2019) 845-855.
43. [43]
  D. Jacobson, A. Ogilvy, Materwiss Werksttech. 34 (2003) 381-384. doi: 10.1002/mawe.200390079
44. [44]
  F. Stadler, H. Antrekowitsch, W. Fragner, et al., Mat. Sci. Eng. A 560 (2013) 481-491. doi: 10.1016/j.msea.2012.09.093
45. [45]
  X. Zhang, Y. Liu, N. Wang, et al., Microstructures 4 (2024) 2024002.
46. [46]
  Y. Fang, S. Deng, T. Li, Chin. Chem. Lett. 34 (2023) 107796. doi: 10.1016/j.cclet.2022.107796
47. [47]
  L. Wang, S. Zhan, Y. Ruan, et al., J. Rare Earths 42 (2024) 2285-2292. doi: 10.1016/j.jre.2024.03.026
48. [48]
  Y. Yang, Z. Lin, R. Li, et al., Microstructures 1 (2021) 2021002.
49. [49]
  X. Pan, Y. Cui, Z. Wang, Chin. Chem. Lett. 35 (2024) 109567. doi: 10.1016/j.cclet.2024.109567
50. [50]
  Y. Li, S. Chou, Y. Xiao, Chin. Chem. Lett. 36 (2025) 110389. doi: 10.1016/j.cclet.2024.110389
51. [51]
  Z. Karadeniz, D. Kumlutas, Compos. Struct. 78 (2007) 1-10.
52. [52]
  P. Turner, J. Res. Nat. Bur. Stand. 37 (1946) 239. doi: 10.6028/jres.037.015
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