Citation: Gaorong Wu, Tao Ma. Recent advanced in C–H borylation using BX₃ with different directing group auxiliary[J]. Chinese Chemical Letters, ;2026, 37(3): 111739. doi: 10.1016/j.cclet.2025.111739 shu

Recent advanced in C–H borylation using BX₃ with different directing group auxiliary

Gaorong Wu ^a ,
Tao Ma ^{b, *,}

a.
Jiangxi Province Key Laboratory of Pharmacology of Traditional Chinese Medicine, School of Pharmacy, Gannan Medical University, Ganzhou 341000, China
b.
School of Chinese Materia Medica, Beijing University of Chinese Medicine, Liangxiang Campus, Beijing 102488, China

201701033@bucm.edu.cn

Received Date: 6 June 2025
Revised Date: 4 August 2025
Accepted Date: 17 August 2025
Available Online: 17 August 2025

Figures(16)

Organoboron compounds have garnered significant attention in the fields of organic synthesis, materials science, medicinal chemistry and fine chemicals. In the past few decades, transition metal-catalyzed C–H borylation has been developed rapidly and efficiently. In recent years, in order to explore eco-friendly, economical and efficient method for constructing C–B bond, chemists are dedicated to developing metal-free BX₃-mediated borylation. In this review, we present a systematic and comprehensive overview of the borylation driven by BX₃ with different directing group auxiliary in the fields of organic synthesis and boron-containing organic materials since 2010, including (1) nitrogen directed C–H borylation, (2) oxygen directed C–H borylation, (3) sulfur directed C–H borylation and (4) phosphorus directed C–H borylation. The methods of borylation processes as well as the substance scopes, limits, and mechanisms of these routes are also discussed.
- Organoboron,
- C–H Borylation,
- BX₃,
- Directing group,
- Organic synthesis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Recent advanced in C–H borylation using BX3 with different directing group auxiliary

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通讯作者: 陈斌, bchen63@163.com

Recent advanced in C–H borylation using BX₃ with different directing group auxiliary