Citation: Feiyan Ma, Haomiao Dou, Danni Luo, Ying Yan, Jie Zhou, Guangda Xu, Yue Wang, Longshan Zhao. Recent advances in chiral recognition based on surface-enhanced Raman scattering spectroscopy[J]. Chinese Chemical Letters, ;2026, 37(4): 111632. doi: 10.1016/j.cclet.2025.111632 shu

Recent advances in chiral recognition based on surface-enhanced Raman scattering spectroscopy

Feiyan Ma ^{a, 1} ,
Haomiao Dou ^{a, 1} ,
Danni Luo ^a ,
Ying Yan ^a ,
Jie Zhou ^a ,
Guangda Xu ^{a, *,} ,
Yue Wang ^{b, *,} ,
Longshan Zhao ^{a, *,}

a.
School of Pharmacy, Shenyang Pharmaceutical University, Shenyang 110016, China
b.
Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China

xuguangda@syphu.edu.cn

yuewang@mail.neu.edu.cn

longshanzhao@163.com

Received Date: 18 February 2025
Revised Date: 12 July 2025
Accepted Date: 23 July 2025
Available Online: 25 July 2025

Figures(4)

Most bioactive compounds (amino acids, sugars, peptides, proteins) and drugs are chiral. Although the enantiomers have similar physical and chemical properties, they may exhibit completely different physiological effects in terms of biological activity, toxicity, and pharmacological effects. Therefore, chiral recognition is particularly important in numerous fields. Surface-enhanced Raman scattering (SERS) spectroscopy, a promising nondestructive analytical technique with wide applications in biosensing, food safety, and environmental analysis, exhibits exceptional potential for chiral recognition. However, there remains a notable scarcity of comprehensive reviews focusing on SERS-based chiral recognition. This review introduced the development of SERS and summarized the classification of chiral enantiomers recognition by SERS spectroscopy in detail in the past 10 years, mainly including EM-dominated chiral substrates, chiral ligand-modified systems, charge transfer (CT)-based "chiral-label-free" approaches, and chiral molecularly imprinted strategies. In addition, the potential challenges and prospects in SERS spectroscopy for chiral recognition are proposed, which is expected to effectively guide future research.
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