Citation: Ke-Lin Zhu, Zhi-Ao Li, Jiaqi Liang, Yong He, Han-Yuan Gong. Atropisomeric carbon-rich macrocycles: Synthesis, structural evolution, and properties[J]. Chinese Chemical Letters, ;2026, 37(2): 111629. doi: 10.1016/j.cclet.2025.111629 shu

Atropisomeric carbon-rich macrocycles: Synthesis, structural evolution, and properties

College of Chemistry, Beijing Normal University, Beijing 100875, China

heyong@bnu.edu.cn

hanyuangong@bnu.edu.cn

Received Date: 9 May 2025
Revised Date: 4 July 2025
Accepted Date: 22 July 2025
Available Online: 24 July 2025

Figures(25)

Carbon-rich cycloarene macrocycles can adopt multiple atropisomeric forms due to steric hindrance restricting σ-bond rotation. These distinct conformations exhibit variations in cavity structure, electronic properties, and functional site distribution, leading to diverse molecular recognition and self-assembly behaviors. In recent years, research on carbon-rich cycloarene macrocyclic compounds has emerged as a cutting-edge and interdisciplinary focus in the fields of carbon-rich functional molecules and macrocyclic chemistry. This review provides a comprehensive overview of the development of atropisomers in carbon-rich cycloarene macrocycles, spanning their design and synthesis, optoelectronic properties, and supramolecular chemistry.
- Atropisomer,
- Carbon-rich macrocycles,
- Supramolecular assembly,
- Host-guest chemistry,
- Stimulus responsive materials
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沈阳化工大学材料科学与工程学院沈阳 110142