Citation: Hui Xu, Hong Song, Jiangyun Wu, Minxi Sun, Chun Wu, Yinghao Zhang, Wei Qin, Qiliang Wei, Jia-Zhao Wang, Xingqiao Wu. Revisiting inactive constituents in sodium-ion batteries: Uncovering hidden drivers of performance[J]. Chinese Chemical Letters, ;2026, 37(10): 111605. doi: 10.1016/j.cclet.2025.111605 shu

Revisiting inactive constituents in sodium-ion batteries: Uncovering hidden drivers of performance

Hui Xu ^a ,
Hong Song ^a ,
Jiangyun Wu ^a ,
Minxi Sun ^a ,
Chun Wu ^{a, b, c, d, *,} ,
Yinghao Zhang ^c ,
Wei Qin ^a ,
Qiliang Wei ^{b, *,} ,
Jia-Zhao Wang ^{e, f, *,} ,
Xingqiao Wu ^{c, d, *,}

a.
College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha 410114, China
b.
Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211, China
c.
Institute for Carbon Neutralization Technology, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
d.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
e.
Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
f.
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, New South Wales 2522, Australia

wuchundd@163.com

qiliang.wei@nbut.edu.cn

jiazhao@uow.edu.au

xingqiaowu@wzu.edu.cn

Received Date: 15 May 2025
Revised Date: 15 July 2025
Accepted Date: 17 July 2025
Available Online: 17 July 2025

Figures(14)

In response to the increasing societal demand for efficient power and energy storage solutions, the development of novel battery technologies to complement existing lithium-ion batteries (LIBs) has emerged as a pivotal area of research. Sodium-ion batteries (SIBs), owing to the similarities in the physicochemical properties of sodium and lithium, have interpreted as promising candidates for next-generation secondary batteries. However, current research predominantly concentrates on the optimization of cathode and anode materials, as well as electrolytes, with insufficient attention paid to the critical role of inactive materials, such as binders, conductive agents, and separators. While electrode and electrolyte materials are undeniably crucial in determining the electrochemical behavior of batteries, the presence of these inactive components exerts a significant influence on factors including cost, performance and safety. This review aims to offer a comprehensive overview of the development, classification, and challenges associated with these key inactive components, with particular focus on cross-material synergies on battery performance. It is anticipated that this review will provide valuable insights to facilitate the enhancement of SIB performance and contribute to the optimization of battery systems as a whole.
- Inactive materials,
- Sodium-ion batteries,
- Energy storage system,
- Synergistic design,
- Electrode additives
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沈阳化工大学材料科学与工程学院沈阳 110142