Citation: Yaofei Zhang, Jiani Chen, Haotian Hu, Jianghua Huang, Jiafeng Wei, Fukun Bi, Xiaodong Zhang. Impact of residual ions on catalyst structure and catalytic performance: A review[J]. Chinese Chemical Letters, ;2026, 37(3): 111549. doi: 10.1016/j.cclet.2025.111549 shu

Impact of residual ions on catalyst structure and catalytic performance: A review

Yaofei Zhang ^a ,
Jiani Chen ^a ,
Haotian Hu ^a ,
Jianghua Huang ^a ,
Jiafeng Wei ^a ,
Fukun Bi ^a ,
Xiaodong Zhang ^{a, b, *,}

a.
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
Shanghai Non-carbon Energy Conversion and Utilization Institute, Shanghai 200240, China

fatzhxd@126.com

Received Date: 16 January 2025
Revised Date: 30 May 2025
Accepted Date: 6 July 2025
Available Online: 7 July 2025

Figures(5)

Residual ions introduced during catalyst synthesis can significantly impact both the structure and performance of the catalyst. Despite their crucial role, the effects of these residual ions are frequently overlooked in catalyst design and optimization. This review systematically surveys the characteristics and sources of typical residual ions in catalytic systems, including halogen anions, acidic anions, and alkali metal cations. It also examines their impact on both the supports and active metals of supported catalysts, as well as the alterations in surface, crystal structure, and chemical states of non-supported catalysts. The effects of residual ions on the performance of these catalysts in catalytic reactions such as oxidation and hydrogenation are discussed in detail. Additionally, the influence mechanism of residual ions on the catalysts is further explored, with a focus on their promotion and inhibition roles in catalytic processes, thus providing insights for the development of more efficient and durable catalysts. A summary finally provides an outlook on future approaches to advance catalyst preparation and mitigate the adverse effects of residual ions in catalysis.
- Residual ions,
- Catalyst structure,
- Catalytic performance,
- Catalyst preparation,
- Influence mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142