Citation: Xiaosa Zhang, Shanghao Zhou, Xiaomin Chen, Xu Xu, Xiaoyan Shi, Zhiming Zhou, Yun Wan, Xinhui Zeng, Xunzhu Zhou, Xiang Chen, Shu-Lei Chou, Lin Li. Organic liquid electrolyte for low-temperature sodium-ion batteries[J]. Chinese Chemical Letters, ;2026, 37(10): 111533. doi: 10.1016/j.cclet.2025.111533 shu

Organic liquid electrolyte for low-temperature sodium-ion batteries

Xiaosa Zhang ^{a, b, c, d} ,
Shanghao Zhou ^{b, c, d} ,
Xiaomin Chen ^{a, b, c, d} ,
Xu Xu ^{a, b, c, d} ,
Xiaoyan Shi ^{a, b, c, d} ,
Zhiming Zhou ^{a, b, c, d} ,
Yun Wan ^{a, b, c, d} ,
Xinhui Zeng ^{a, b, c, d} ,
Xunzhu Zhou ^{b, c, d, e, *,} ,
Xiang Chen ^f ,
Shu-Lei Chou ^{a, b, c, d, *,} ,
Lin Li ^{a, b, c, d, *,}

a.
Institute for Carbon Neutralization Technology, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
b.
Zhejiang Provincial Key Laboratory of Advanced Battery Materials and Technology, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
c.
Zhejiang-Australia International Joint Laboratory for Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
d.
Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
e.
Institute School of Materials Science and Engineering, Key Laboratory of Structure and Functional Regulation of Hybrid Material (Ministry of Education), Anhui University, Hefei 230601, China
f.
College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, China

xunzhuzhou@ahu.edu.cn

chou@wzu.edu.cn

linli@wzu.edu.cn

Received Date: 29 May 2025
Revised Date: 29 June 2025
Accepted Date: 2 July 2025
Available Online: 3 July 2025

Figures(13)

Low-temperature energy storage technology plays a crucial role in sustaining energy supply for interstellar exploration, polar research stations, military facilities in extremely cold regions. Sodium-ion batteries (SIBs) are regarded as potential candidates for large-scale energy storage systems under extreme low-temperature conditions due to their abundant sodium resources, low cost and superior temperature tolerance. As a critical component of SIBs, the electrolyte is closely related to the charge transfer kinetics within the battery and significantly influences its low-temperature electrochemical performance. Herein, we present a comprehensive review focusing on recent advances in organic liquid electrolytes for enhancing the low-temperature performance of SIBs. Firstly, the failure mechanisms of SIBs at low temperatures are systematically analyzed from the perspective of charge transfer kinetics. Subsequently, the electrolyte design strategies for low-temperature SIBs are introduced based on two evaluation dimensions: half cell and full cell systems. Finally, the future research directions for developing advanced electrolytes to improve the low-temperature performance of SIBs are proposed. This review provides valuable insights into electrolyte optimization strategies, which are expected to accelerate the development of high-performance SIBs for reliable energy storage in extreme cold environments.
- Sodium-ion batteries,
- Low temperature,
- Organic liquid electrolyte,
- Charge transfer kinetics,
- Electrochemical performance
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沈阳化工大学材料科学与工程学院沈阳 110142