Citation: Ruijing Fu, Junpeng Gao, Lingrui Wang, Bin Xiao, Guangxia Wang, Qingguang Zeng, Guanjun Xiao. Pressure-induced tunable photoluminescence of Mn-doped post-perovskites (TDMP)PbBr₄[J]. Chinese Chemical Letters, ;2026, 37(2): 111507. doi: 10.1016/j.cclet.2025.111507 shu

Pressure-induced tunable photoluminescence of Mn-doped post-perovskites (TDMP)PbBr₄

Ruijing Fu ^{a, d} ,
Junpeng Gao ^a ,
Lingrui Wang ^b ,
Bin Xiao ^a ,
Guangxia Wang ^{a, *,} ,
Qingguang Zeng ^{a, d, *,} ,
Guanjun Xiao ^{c, *,}

a.
School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, China
b.
Key Laboratory of Materials Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou 450052, China
c.
State Key Laboratory of High Pressure and Superhard Materials, College of Physics, Jilin University, Changchun 130012, China
d.
Institute of Carbon Peaking and Carbon Neutralization, Wuyi University, Jiangmen 529020, China

wangguangxia1107@126.com

zengqg1979@126.com

xguanjun@jlu.edu.cn

Received Date: 23 April 2025
Revised Date: 20 June 2025
Accepted Date: 25 June 2025
Available Online: 25 June 2025

Figures(5)

One-dimensional (1D) organic-inorganic halide perovskites have produced significant research interest due to their unique structure and superior tunable luminescence properties. Here, we successfully achieved a unique color-tunable phenomenon of Mn-doped 1D post-perovskite (TDMP)PbBr₄ (TDMP = trans-2,5-dimethylpiperazine) (TPBM-14) under high pressure. Which exhibited tunable photoluminescence (PL) emission from red to yellow orange. Meanwhile, the band gap continued to decrease below 20.0 GPa, accompanied by piezochromism, which was associated the shrinkage and distortion of inorganic, which enhances the crystal field splitting energy and reduces the energy gap of the ⁴T₁ to ⁶A₁ transition. The unique octahedral corner- and edge-sharing structure of (TDMP)PbBr₄, the synergistic effect of Mn doping and pressure induces local lattice distortion in TPBM-14, leading to a significant enhancement of the STE emission at 8.1 GPa. Our research explores the intrinsic connection between the band structure and optical properties of TPBM-14 under high pressure and offers valuable insights for performance optimization.
- High pressure,
- Piezochromism,
- Mn-doped perovskite,
- Emission color modulation,
- One-dimensional organic-inorganic halide perovskite
1. [1]
  X. Xu, X. Zhang, W. Deng, J. Jie, X. Zhang, Small Methods 2 (2018) 1700340. doi: 10.1002/smtd.201700340
2. [2]
  W. Zhang, K. Tao, C. Ji, et al., Inorg. Chem. 57 (2018) 4239–4243. doi: 10.1021/acs.inorgchem.8b00152
3. [3]
  Q. Zhou, W. Li, J. Xiao, A. Li, X. Han, Adv. Funct. Mater. 34 (2024) 2402902. doi: 10.1002/adfm.202402902
4. [4]
  C. Zhou, Y. Tian, M. Wang, et al., Angew. Chem. Int. Ed. 56 (2017) 9018–9022. doi: 10.1002/anie.201702825
5. [5]
  G. Huang, H. Zhou, C. Wang, et al., Inorg. Chem. Commun. 128 (2021) 108581. doi: 10.1016/j.inoche.2021.108581
6. [6]
  Y. Peng, Y. Yao, L. Li, et al., J. Mater. Chem. C 6 (2018) 6033–6037. doi: 10.1039/c8tc01150h
7. [7]
  X. Ding, R. He, T. Zhang, et al., ACS Appl. Mater. Interfaces 15 (2023) 42139–42152. doi: 10.1021/acsami.3c04255
8. [8]
  A. Jha, P. Bansal, G.K. Nim, P. Kar, Opt. Mater. 111 (2021) 110660. doi: 10.1016/j.optmat.2020.110660
9. [9]
  L. Mei, R. Xie, S. Zhu, et al., Nano Today 50 (2023) 101830. doi: 10.1016/j.nantod.2023.101830
10. [10]
  A. Chu, J. Luo, Z. Xu, et al., J. Mater. Chem. C 12 (2024) 9733–9741. doi: 10.1039/d4tc01064g
11. [11]
  H. Li, K. Han, Z. Li, et al., Adv. Sci. 11 (2024) 2307354. doi: 10.1002/advs.202307354
12. [12]
  S. Mukherjee, S. Ghosh, D. Biswas, et al., Nanoscale 15 (2023) 6947–6953. doi: 10.1039/d3nr00241a
13. [13]
  X. Wang, Q. Shen, Y. Chen, et al., Nanoscale 13 (2021) 15285–15291. doi: 10.1039/d1nr04635g
14. [14]
  B. Zhou, Z. Liu, S. Fang, et al., J. Phys. Chem. Lett. 13 (2022) 9140–9147. doi: 10.1021/acs.jpclett.2c02759
15. [15]
  S. Ge, Q. Wei, W. Jia, et al., Appl. Phys. Lett. 118 (2021) 152102. doi: 10.1063/5.0040536
16. [16]
  S. Wang, J. Leng, Q. Sun, C. Zhao, S. Jin, J. Phys. Chem. Lett. 12 (2021) 1475–1480. doi: 10.1021/acs.jpclett.1c00017
17. [17]
  A. Karmakar, M.S. Dodd, S. Agnihotri, E. Ravera, V.K. Michaelis, Chem. Mater. 30 (2018) 8280–8290. doi: 10.1021/acs.chemmater.8b03755
18. [18]
  W. Li, Y. Wang, H. Yin, et al., Inorg. Chem. 23 (2024) 10481–10489. doi: 10.1021/acs.inorgchem.4c00445
19. [19]
  B. Su, G. Zhou, J. Huang, et al., Laser Photonics Rev. 15 (2021) 2000334. doi: 10.1002/lpor.202000334
20. [20]
  J. Gao, Y. Guo, X. Zhang, et al., Adv. Sci. 12 (2025) 2413402. doi: 10.1002/advs.202413402
21. [21]
  S. Ji, X. Yuan, S. Cao, et al., J. Phys. Chem. Lett. 11 (2020) 2142–2149. doi: 10.1021/acs.jpclett.0c00372
22. [22]
  Z. Ma, Q. Li, J. Luo, et al., J. Am. Chem. Soc. 143 (2021) 15176–15184. doi: 10.1021/jacs.1c06207
23. [23]
  Y. Wang, X. Yang, C. Liu, et al., Angew. Chem. Int. Ed. 61 (2022) e202210836. doi: 10.1002/anie.202210836
24. [24]
  T. Zhang, X. Yong, J. Yu, et al., Adv. Mater. 35 (2023) 2211729. doi: 10.1002/adma.202211729
25. [25]
  Z. Ma, G. Xiao, L. Ding, J. Semicond. 42 (2021) 100203–100204. doi: 10.1088/1674-4926/42/10/100203
26. [26]
  A. Noculak, S.C. Boehme, M. Aebli, et al., Helv. Chim. Acta 104 (2021) e2000222. doi: 10.1002/hlca.202000222
27. [27]
  A. Weingarten, Nat. Rev. Chem. 3 (2019) 513-513. doi: 10.1038/s41570-019-0131-1
28. [28]
  Y. Chen, R. Fu, L. Wang, et al., J. Mater. Chem. A 7 (2019) 6357–6362. doi: 10.1039/c8ta11992a
29. [29]
  Z. Ma, F. Li, G. Qi, et al., Nanoscale 11 (2019) 820–825. doi: 10.1039/c8nr05684f
30. [30]
  G. Xiao, Y. Wang, D. Han, et al., J. Am. Chem. Soc. 140 (2018) 13970–13975. doi: 10.1021/jacs.8b09416
31. [31]
  R. Fu, W. Zhao, L. Wang, et al., Angew. Chem. Int. Ed. 60 (2021) 10082–10088. doi: 10.1002/anie.202015395
32. [32]
  N. Li, Q. Zhang, Y. Wang, W. Yang, Appl. Phys. Lett. 117 (2020) 080502. doi: 10.1063/5.0014947
33. [33]
  G. Xiao, T. Geng, B. Zou, ACS Mater. Lett. 2 (2020) 1233–1239. doi: 10.1021/acsmaterialslett.0c00329
34. [34]
  Q. Li, B. Xu, X. Xu, Y. Wang, Z. Quan, Aggregate 6 (2025) e70004. doi: 10.1002/agt2.70004
35. [35]
  N.V. Morozova, I.V. Zhevstovskikh, I.V. Korobeinikov, et al., J. Alloy. Compd. 988 (2024) 174305. doi: 10.1016/j.jallcom.2024.174305
36. [36]
  D. Zhao, M. Cong, Z. Liu, et al., Cell Rep. Phys. Sci. 4 (2023) 101445. doi: 10.1016/j.xcrp.2023.101445
37. [37]
  Z. Ma, Z. Liu, S. Lu, et al., Nat. Commun. 9 (2018) 4506. doi: 10.1038/s41467-018-06840-8
38. [38]
  Y. Shi, Z. Ma, D. Zhao, et al., J. Am. Chem. Soc. 141 (2019) 6504–6508. doi: 10.1021/jacs.9b02568
39. [39]
  Y. Fang, L. Zhang, L. Wu, et al., Angew. Chem. Int. Ed. 58 (2019) 15249–15253. doi: 10.1002/anie.201906311
40. [40]
  W. Zhao, G. Xiao, B. Zou, Aggregate 5 (2024) e461. doi: 10.1002/agt2.461
41. [41]
  Y. Wang, S. Guo, H. Luo, et al., J. Am. Chem. Soc. 142 (2020) 16001–16006. doi: 10.1021/jacs.0c07166
42. [42]
  X. Yu, Y. Fang, X. Sun, et al., Angew. Chem. Int. Ed. 63 (2024) e202412756. doi: 10.1002/anie.202412756
43. [43]
  Y. Shi, W. Zhao, Z. Ma, G. Xiao, B. Zou, Chem. Sci. 12 (2021) 14711–14717. doi: 10.1039/d1sc04987a
44. [44]
  M. Cong, Q. Li, X. Wang, et al., ACS Mater. Lett. 7 (2025) 996–1002. doi: 10.1021/acsmaterialslett.4c02556
45. [45]
  Y. Cao, G. Qi, L. Sui, et al., ACS Mater. Lett. 2 (2020) 381–388. doi: 10.1021/acsmaterialslett.0c00033
46. [46]
  Y. Shi, Z. Jin, P. Lv, et al., J. Mater. Chem. C 11 (2023) 1726–1732. doi: 10.1039/d2tc05158c
47. [47]
  L. Zhang, Z. Liu, X. Sun, et al., Adv. Optical Mater. 10 (2022) 2101892. doi: 10.1002/adom.202101892
48. [48]
  R. Fu, J. Gao, L. Wang, et al., Inorg. Chem. 63 (2024) 18276–18284. doi: 10.1021/acs.inorgchem.4c03145
49. [49]
  R. Gautier, F. Massuyeau, G. Galnon, M. Paris, Adv. Mater. 31 (2019) 1807383. doi: 10.1002/adma.201807383
50. [50]
  R. Gautier, M. Paris, F. Massuyeau, J. Am. Chem. Soc. 141 (2019) 12619–12623. doi: 10.1021/jacs.9b04262
51. [51]
  T. Huang, H. Peng, Q. Wei, et al., Nano Energy 93 (2022) 106863. doi: 10.1016/j.nanoen.2021.106863
52. [52]
  G. Zhou, X. Jiang, M. Molokeev, et al., Chem. Mater. 31 (2019) 5788–5795. doi: 10.1021/acs.chemmater.9b01864
53. [53]
  Z. Wang, Y. Xiao, B. Liu, et al., Adv. Opt. Mater. 12 (2024) 2301796. doi: 10.1002/adom.202301796
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2. [2]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
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4. [4]
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沈阳化工大学材料科学与工程学院沈阳 110142

Pressure-induced tunable photoluminescence of Mn-doped post-perovskites (TDMP)PbBr4

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通讯作者: 陈斌, bchen63@163.com

Pressure-induced tunable photoluminescence of Mn-doped post-perovskites (TDMP)PbBr₄