Citation: Xiaobo Li, Qunyan Wu, Congzhi Wang, Jianhui Lan, Meng Zhang, Weiqun Shi. Kinetically controlled Np(Ⅵ)/Pu(Ⅳ) selective reduction by n-butyraldehyde[J]. Chinese Chemical Letters, ;2026, 37(2): 111503. doi: 10.1016/j.cclet.2025.111503 shu

Kinetically controlled Np(Ⅵ)/Pu(Ⅳ) selective reduction by n-butyraldehyde

Xiaobo Li ^a ,
Qunyan Wu ^{a, *,} ,
Congzhi Wang ^a ,
Jianhui Lan ^a ,
Meng Zhang ^b ,
Weiqun Shi ^{a, c, *,}

a.
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
b.
Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin 150001, China
c.
Institute of Nuclear Fuel Cycle and Materials, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

wuqy@ihep.ac.cn

shiwq@sjtu.edu.cn

Received Date: 13 January 2025
Revised Date: 9 June 2025
Accepted Date: 24 June 2025
Available Online: 1 July 2025

Figures(7)

The demand for ²³⁸Pu (nuclear battery heat source) drives the separation of its precursor, ²³⁷Np, from spent nuclear fuel (SNF). However, the co-existence of multi-valence states (Ⅳ/Ⅴ/Ⅵ) of Np and similar redox behavior with Pu(Ⅳ) hinder the effective separation of Np. N-Butyraldehyde (n-C₃H₇CHO) selectively reduces Np(Ⅵ) to Np(Ⅴ) without reducing Pu(Ⅳ). Herein, we examined the reduction mechanisms of Np(Ⅵ) and Pu(Ⅳ) by n-C₃H₇CHO using relativistic density functional theory. Based on the results of the potential energy profiles, the reductions of both Np(Ⅵ) and Pu(Ⅳ) by n-C₃H₇CHO are thermodynamically feasible, whereas only the former is kinetically achievable. It uncovers that n-C₃H₇CHO can only reduce Np(Ⅵ) to Np(Ⅴ) owing to kinetically controlled selective reduction. The analyses of spin density and bond distance indicate that the reduction nature for the first Np(Ⅵ)/Pu(Ⅳ) belongs to hydrogen atom transfer, whereas that for the second one involves outer-sphere electron transfer. Localized molecular orbitals (LMOs) analysis discloses the bonding evolution during the reduction process of Np(Ⅵ)/Pu(Ⅳ). This study elucidates the reason behind the kinetically controlled selective reduction of Np(Ⅵ)/Pu(Ⅳ) by n-C₃H₇CHO at the molecular level and offers in-depth perspectives on the isolation of specific metal ions from the view of kinetic control.
- Neptunium,
- Plutonium,
- Reduction,
- Density functional theory,
- Kinetic control
1. [1]
  Y. Liu, X.P. Shao, W.T. Bu, et al., Chin. Chem. Lett. 33 (2022) 3384–3394. doi: 10.1016/j.cclet.2022.03.016
2. [2]
  T.Y. Xiu, S.M. Zhang, P. Ren, et al., Chin. Chem. Lett. 34 (2023) 108440. doi: 10.1016/j.cclet.2023.108440
3. [3]
  W.X. Xiao, D.Q. Pan, Z.W. Niu, et al., Chin. Chem. Lett. 33 (2022) 3413–3421. doi: 10.1016/j.cclet.2022.03.017
4. [4]
  L.K. Liu, S.B. Xie, H.B. Lv, et al., Chin. Chem. Lett. 33 (2022) 3439–3443. doi: 10.1016/j.cclet.2022.04.001
5. [5]
  O. Artun, Appl. Radiat. Isotopes 166 (2020) 109337. doi: 10.1016/j.apradiso.2020.109337
6. [6]
  X. Zhang, L. Zhang, T. Bo, et al., Chin. Chem. Lett. 33 (2022) 3527–3530. doi: 10.1016/j.cclet.2022.03.026
7. [7]
  X.H. Kong, X.L. Liao, Z.K. Huang, et al., Chin. Chem. Lett. 35 (2024) 109642. doi: 10.1016/j.cclet.2024.109642
8. [8]
  R.E. Isaacson, B.F. Judson, Ind. Eng. Chem. Process Des. Dev. 3 (1964) 296–301. doi: 10.1021/i260012a003
9. [9]
  M. Benedict, T.H. Pigford, H.W. Levi, Nuclear Chemical Engineering, 2nd ed., McGraw-Hill Education, New York, 1981.
10. [10]
  K.W. Kim, K.C. Song, E.H. Lee, et al., J. Radioanal. Nucl. Chem. 246 (2000) 215–219. doi: 10.1023/A:1006731920212
11. [11]
  X. Dong, Z.P. Wang, Q. Yan, et al., Chin. Chem. Lett. 33 (2022) 3531–3533. doi: 10.1016/j.cclet.2022.02.057
12. [12]
  S.L. Yarbro, S.B. Schreiber, E.M. Ortiz, et al., J. Radioanal. Nucl. Chem. 235 (1998) 21–25. doi: 10.1007/BF02385931
13. [13]
  V.S. Koltunov, S.M. Baranov, Radiochemistry 42 (2000) 236–241.
14. [14]
  A.Y. Zhang, J.X. Hu, X.Y. Zhang, et al., J. Radioanal. Nucl. Chem. 253 (2002) 107–113. doi: 10.1023/A:1015872703102
15. [15]
  Y.X. Chen, H.B. Tang, J.P. Liu, et al., J. Radioanal. Nucl. Chem. 289 (2011) 41–47. doi: 10.1007/s10967-011-1030-1
16. [16]
  V.I. Marchenko, K.N. Dvoeglazov, O.A. Savilova, et al., Radiochemistry 54 (2012) 459–464. doi: 10.1134/S1066362212050074
17. [17]
  T.H. Yan, W.F. Zhen, G.A. Ye, et al., J. Radioanal. Nucl. Chem. 279 (2009) 293–299. doi: 10.1007/s11029-009-9081-x
18. [18]
  T.H. Yan, W.F. Zheng, C. Zuo, et al., Radiochim. Acta 98 (2010) 35–38.
19. [19]
  P. Sivakumar, S. Meenakshi, R.V.S. Rao, J. Radioanal. Nucl. Chem. 292 (2012) 603–608. doi: 10.1007/s10967-011-1454-7
20. [20]
  V.S. Koltunov, R.J. Taylor, S.M. Baranov, et al., Radiochim. Acta 88 (2000) 65–70. doi: 10.1524/ract.2000.88.2.065
21. [21]
  V.S. Koltunov, S.M. Baranov, V.G. Pastushchak, Radiochemistry 43 (2001) 346–349. doi: 10.1023/A:1012845516509
22. [22]
  V.S. Koltunov, E.A. Mezhov, S.M. Baranov, Radiochemistry 43 (2001) 342–345. doi: 10.1023/A:1012893432439
23. [23]
  V.S. Koltunov, R.J. Taylor, S.M. Baranov, et al., J. Nucl. Sci. Technol. 39 (2002) 878–881. doi: 10.1080/00223131.2002.10875609
24. [24]
  V.S. Koltunov, S.M. Baranov, Inorg. Chim. Acta 140 (1987) 31–34. doi: 10.1016/S0020-1693(00)81042-7
25. [25]
  X.Y. Zhang, Z.L. Huang, S.T. Xiao, et al., Atomic Energy Science Technology 33 (1999) 8–11.
26. [26]
  V. Koltunov, J. Nucl. Sci. Technol. 39 (2002) 347–350. doi: 10.1080/00223131.2002.10875480
27. [27]
  V.S. Koltunov, K.M. Frolov, Y.V. Isaev, Radiochemistry 44 (2002) 121–126. doi: 10.1023/A:1019606909734
28. [28]
  W.Q. Shi, H.B. Tang, Y.X. Ye, et al., J. Nucl. Radiochem. 24 (2002) 134–137.
29. [29]
  Y. Ban, T. Asakura, Y. Morita, J. Radioanal. Nucl. Chem. 279 (2009) 423–429. doi: 10.1007/s10967-007-7262-4
30. [30]
  H. Yang, H. Zhang, L. Li, et al., Nuclear Techniques 39 (2016) 37–44.
31. [31]
  Z.Y. Liu, H. Zhang, R.T. Wang, et al., Nuclear Techniques 40 (2017) 28–34. doi: 10.3390/met7010028
32. [32]
  G. Uchiyama, S. Fujine, S. Hotoku, et al., Nucl. Technol. 102 (1993) 341–352. doi: 10.13182/NT93-A17033
33. [33]
  G. Uchiyama, S. Hotoku, S. Fujine, et al., Nucl. Technol. 122 (1998) 222–227. doi: 10.13182/NT98-A2864
34. [34]
  G. Uchiyama, H. Mineo, S. Hotoku, et al., Prog. Nucl. Energy 37 (2000) 151–156. doi: 10.1016/S0149-1970(00)00040-8
35. [35]
  V.I. Marchenko, V.S. Koltunov, O.A. Savilova, et al., Radiochemistry 43 (2001) 276–283. doi: 10.1023/A:1012812609241
36. [36]
  Y. Ban, T. Asakura, Y. Morita, Radiochim. Acta 92 (2004) 883–887. doi: 10.1524/ract.92.12.883.55113
37. [37]
  Z.P. Cheng, Q.Y. Wu, Y.H. Liu, et al., RSC Adv. 6 (2016) 109045–109053. doi: 10.1039/C6RA13339H
38. [38]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., J. Phys. Chem. A 124 (2020) 3720–3729. doi: 10.1021/acs.jpca.0c01504
39. [39]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., J. Phys. Chem. A 125 (2021) 6180–6188. doi: 10.1021/acs.jpca.1c04198
40. [40]
  Z.P. Cheng, X.B. Li, Q.Y. Wu, et al., Radiochim. Acta 110 (2022) 471–480. doi: 10.1515/ract-2021-1120
41. [41]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., Phys. Chem. Chem. Phys. 24 (2022) 17782–17791. doi: 10.1039/d2cp01730j
42. [42]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., J. Phys. Chem. A 127 (2023) 4259–4268. doi: 10.1021/acs.jpca.3c00062
43. [43]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., Chin. Chem. Lett. 35 (2024) 109359. doi: 10.1016/j.cclet.2023.109359
44. [44]
  X. Huang, X.B. Li, Q.Y. Wu, et al., Phys. Chem. Chem. Phys. 26 (2024) 27395–27405. doi: 10.1039/d4cp03097d
45. [45]
  X.B. Li, Q.Y. Wu, C.Z. Wang, et al., J. Phys. Chem. A 127 (2023) 7479–7486. doi: 10.1021/acs.jpca.3c03830
46. [46]
  C.T. Lee, W.T. Yang, R.G. Parr, Phys. Rev. B 37 (1988) 785–789. doi: 10.1103/PhysRevB.37.785
47. [47]
  A.D. Becke, J. Chem. Phys. 98 (1993) 5648–5652. doi: 10.1063/1.464913
48. [48]
  Y.T. Bi, Z. Bao, L. Li, et al., ChemistrySelect 3 (2018) 4804–4810. doi: 10.1002/slct.201800328
49. [49]
  J.P. Wang, W.Y. Xie, W.R. Jiang, et al., Adv. Theory Simul. 2 (2019) 1900138. doi: 10.1002/adts.201900138
50. [50]
  Y.X. Wang, S.X. Hu, L.W. Cheng, et al., CCS Chem. 2 (2020) 425–431. doi: 10.31635/ccschem.020.202000152
51. [51]
  P. Zhang, Y.X. Wang, P. Zhang, et al., Inorg. Chem. 59 (2020) 11953–11961. doi: 10.1021/acs.inorgchem.0c00535
52. [52]
  X. -K. Zhao, C. -S. Cao, J. -C. Liu, et al., Chem. Sci. 13 (2022) 8518–8525. doi: 10.1039/d2sc02017c
53. [53]
  X.P. Lei, Q.Y. Wu, C.Z. Wang, et al., Inorg. Chem. 62 (2023) 2705–2714. doi: 10.1021/acs.inorgchem.2c03823
54. [54]
  L.L. Su, Q.Y. Wu, C.Z. Wang, et al., Chin. Chem. Lett. 35 (2024) 109402. doi: 10.1016/j.cclet.2023.109402
55. [55]
  M. Cossi, N. Rega, G. Scalmani, et al., J. Comput. Chem. 24 (2003) 669–681. doi: 10.1002/jcc.10189
56. [56]
  V. Barone, M. Cossi, J. Phys. Chem. A 102 (1998) 1995–2001. doi: 10.1021/jp9716997
57. [57]
  M.J. Frisch, G.W. Trucks, H.B. Schlegel, et al., Gaussian 16 Software Program, Gaussian Inc., Wallingford, CT, 2016.
58. [58]
  W. Küchle, M. Dolg, H. Stoll, et al., J. Chem. Phys. 100 (1994) 7535–7542. doi: 10.1063/1.466847
59. [59]
  X.Y. Cao, M. Dolg, H. Stoll, J. Chem. Phys. 118 (2003) 487–496. doi: 10.1063/1.1521431
60. [60]
  X.Y. Cao, M. Dolg, J. Mol. Struc. (THEOCHEM) 673 (2004) 203–209. doi: 10.1016/j.theochem.2003.12.015
61. [61]
  E. Fromager, V. Vallet, B. Schimmelpfennig, et al., J. Phys. Chem. A 109 (2005) 4957–4960. doi: 10.1021/jp051056o
62. [62]
  J.K. Gibson, W.A. de Jong, P.D. Dau, et al., J. Phys. Chem. A 121 (2017) 9156–9162. doi: 10.1021/acs.jpca.7b09721
63. [63]
  J. Autschbach, J. Chem. Theory Comput. 13 (2017) 710–718. doi: 10.1021/acs.jctc.6b01014
64. [64]
  E. Van Lenthe, E.J. Baerends, J. Comput. Chem. 24 (2003) 1142–1156. doi: 10.1002/jcc.10255
65. [65]
  C. Fonseca Guerra, J.G. Snijders, G. te Velde, et al., Theor. Chem. Acc. 99 (1998) 391–403.
66. [66]
  G. te Velde, F.M. Bickelhaupt, E.J. Baerends, et al., J. Comput. Chem. 22 (2001) 931–967. doi: 10.1002/jcc.1056
67. [67]
  E.J. Baerends, T. Ziegler, A.J. Atkins, et al., ADF2022, Theoretical Chemistry, Vrije Universiteit, Amsterdam, The Netherlands, 2022 URL http://www.scm.com.
68. [68]
  A. Klamt, G. Schüürmann, J. Chem. Soc., Perkin Trans. 2 (1993) 799–805.
69. [69]
  A. Klamt, J. Phys. Chem. 99 (1995) 2224–2235. doi: 10.1021/j100007a062
70. [70]
  A. Klamt, V. Jonas, J. Chem. Phys. 105 (1996) 9972–9981. doi: 10.1063/1.472829
71. [71]
  J. Pipek, P.G. Mezey, J. Chem. Phys. 90 (1989) 4916–4926. doi: 10.1063/1.456588
72. [72]
  T. Lu, F.W. Chen, J. Comput. Chem. 33 (2012) 580–592. doi: 10.1002/jcc.22885
73. [73]
  T. Lu, J. Chem. Phys. 161 (2024) 082503. doi: 10.1063/5.0216272
74. [74]
  T. Lu, Q.X. Chen, J. Comput. Chem. 43 (2022) 539–555. doi: 10.1002/jcc.26812
75. [75]
  D. Kirk Veirs, C.A. Smith, J.M. Berg, et al., J. Alloys Compd. 213-214 (1994) 328–332. doi: 10.1016/0925-8388(94)90924-5
76. [76]
  P.G. Allen, D.K. Veirs, S.D. Conradson, et al., Inorg. Chem. 35 (1996) 2841–2845. doi: 10.1021/ic9511231
77. [77]
  S.D. Conradson, K.D. Abney, B.D. Begg, et al., Inorg. Chem. 43 (2004) 116–131. doi: 10.1021/ic0346477
78. [78]
  A.M. Lines, S.R. Adami, S.I. Sinkov, et al., Anal. Chem. 89 (2017) 9354–9359. doi: 10.1021/acs.analchem.7b02161
79. [79]
  C. Madic, G.M. Begun, D.E. Hobart, et al., Inorg. Chem. 23 (1984) 1914–1921. doi: 10.1021/ic00181a025
80. [80]
  P.J. Hay, R.L. Martin, G. Schreckenbach, J. Phys. Chem. A. 104 (2000) 6259–6270. doi: 10.1021/jp000519h
81. [81]
  P. Lindqvist-Reis, C. Apostolidis, O. Walter, et al., Dalton Trans. 42 (2013) 15275–15279. doi: 10.1039/c3dt51650d
82. [82]
  L. Zhang, S.Y. Liu, Z.G. Zhao, et al., Chem. Sci. 9 (2018) 6085–6090. doi: 10.1039/c8sc01882k
83. [83]
  L.Y. Wang, Y.B. Zhang, J. Yao, et al., Catal. Lett. 152 (2022) 1131–1139. doi: 10.1007/s10562-021-03706-5
84. [84]
  J.R. Bryant, J.M. Mayer, J. Am. Chem. Soc. 125 (2003) 10351–10361. doi: 10.1021/ja035276w
85. [85]
  J.M. Mayer, Acc. Chem. Res. 44 (2011) 36–46. doi: 10.1021/ar100093z
86. [86]
  K.R. Gorantla, B.S. Mallik, J. Phys. Chem. A 126 (2022) 3301–3310. doi: 10.1021/acs.jpca.2c01043
87. [87]
  J.G. Muller, R.P. Hickerson, R.J. Perez, et al., J. Am. Chem. Soc. 119 (1997) 1501–1506. doi: 10.1021/ja963701y
88. [88]
  R.S. Miller, J.M. Sealy, M. Shabangi, et al., J. Am. Chem. Soc. 122 (2000) 7718–7722. doi: 10.1021/ja001260j
89. [89]
  Y.M. Lee, S. Kim, K. Ohkubo, et al., J. Am. Chem. Soc. 141 (2019) 2614–2622. doi: 10.1021/jacs.8b12935
90. [90]
  Y. Wakatsuki, N. Koga, H. Werner, et al., J. Am. Chem. Soc. 119 (1997) 360–366. doi: 10.1021/ja962732q
91. [91]
  R.Z. Sun, M.Y. Yu, G.Q. Luo, et al., Chem. Eng. J. 407 (2021) 127113. doi: 10.1016/j.cej.2020.127113
92. [92]
  J.L. Qu, J.W. Xiao, H.T. Chen, et al., Chin. J. Catal. 42 (2021) 288–296. doi: 10.1016/S1872-2067(20)63643-9
93. [93]
  F.Z. Zhang, Q.P. Kong, H.H. Chen, et al., Chem. Eng. J. 434 (2022) 134674. doi: 10.1016/j.cej.2022.134674
94. [94]
  G.L. Yu, Y.Q. Liu, X.Q. Zou, et al., J. Mater. Chem. A 6 (2018) 11797–11803. doi: 10.1039/c8ta03509a
95. [95]
  T.T. Nguyen, M.J. Koh, X. Shen, et al., Science 352 (2016) 569–575. doi: 10.1126/science.aaf4622
96. [96]
  X. Shen, T.T. Nguyen, M.J. Koh, et al., Nature 541 (2017) 380–385. doi: 10.1038/nature20800
97. [97]
  H. Kokusen, K. Suzaki, K. Ohashi, et al., Anal. Sci. 4 (1988) 617–622. doi: 10.2116/analsci.4.617
98. [98]
  K.E. Mayhew, T.M. McCoy, D.L. Jones, et al., Solvent Extr. Ion Exch. 29 (2011) 755–781. doi: 10.1080/07366299.2011.595628
99. [99]
  Y.Y. Liang, L. Mei, Q.Y. Jin, et al., Chin. Chem. Lett. 33 (2022) 3539–3542. doi: 10.1016/j.cclet.2022.03.092
1. [1]
  Xiaobo Li , Qunyan Wu , Congzhi Wang , Jianhui Lan , Meng Zhang , Weiqun Shi . Theoretical perspectives on the reduction of Pu(Ⅳ) and Np(Ⅵ) by methylhydrazine in HNO₃ solution: Implications for Np/Pu separation. Chinese Chemical Letters, 2024, 35(7): 109359-. doi: 10.1016/j.cclet.2023.109359
2. [2]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
3. [3]
  Qiaorui Wang , Dingyun Liang , Zhongwen Zhang , Yalan Yang , Yunran Zhang , Yirong Wang , Lei Liu , Wenfeng Jiang , Muneerah Alomar , Li-Long Zhang . Single-atom catalysts for electrocatalytic nitrogen reduction to ammonia: A review. Chinese Journal of Structural Chemistry, 2025, 44(6): 100599-100599. doi: 10.1016/j.cjsc.2025.100599
4. [4]
  Wei Chen , Pieter Cnudde . A minireview to ketene chemistry in zeolite catalysis. Chinese Journal of Structural Chemistry, 2024, 43(11): 100412-100412. doi: 10.1016/j.cjsc.2024.100412
5. [5]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
6. [6]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
7. [7]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
8. [8]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
9. [9]
  Lingling Su , Qunyan Wu , Congzhi Wang , Jianhui Lan , Weiqun Shi . Theoretical design of polyazole based ligands for the separation of Am(Ⅲ)/Eu(Ⅲ). Chinese Chemical Letters, 2024, 35(8): 109402-. doi: 10.1016/j.cclet.2023.109402
10. [10]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
13. [13]
  Weiping Xiao , Yuhang Chen , Qin Zhao , Danil Bukhvalov , Caiqin Wang , Xiaofei Yang . Constructing the synergistic active sites of nickel bicarbonate supported Pt hierarchical nanostructure for efficient hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(12): 110176-. doi: 10.1016/j.cclet.2024.110176
14. [14]
  Ze Zhang , Lei Yang , Jin-Ru Liu , Hao Hu , Jian-Li Mi , Chao Su , Bei-Bei Xiao , Zhi-Min Ao . Improved oxygen electrocatalysis at FeN₄ and CoN₄ sites via construction of axial coordination. Chinese Chemical Letters, 2025, 36(2): 110013-. doi: 10.1016/j.cclet.2024.110013
15. [15]
  Chaozheng He , Menghui Xi , Chenxu Zhao , Ran Wang , Ling Fu , Jinrong Huo . Highly N₂ dissociation catalyst: Ir(100) and Ir(110) surfaces. Chinese Chemical Letters, 2025, 36(3): 109671-. doi: 10.1016/j.cclet.2024.109671
16. [16]
  Mianfeng Li , Haozhi Wang , Zijun Yang , Zexiang Yin , Yuan Liu , Yingmei Bian , Yang Wang , Xuerong Zheng , Yida Deng . Synergistic enhancement of alkaline hydrogen evolution reaction by role of Ni-Fe LDH introducing frustrated Lewis pairs via vacancy-engineered. Chinese Chemical Letters, 2025, 36(3): 110199-. doi: 10.1016/j.cclet.2024.110199
17. [17]
  Teng Wang , Jiachun Cao , Juan Li , Didi Li , Zhimin Ao . A novel photocatalytic mechanism of volatile organic compounds degradation on BaTiO₃ under visible light: Photo-electrons transfer from photocatalyst to pollutant. Chinese Chemical Letters, 2025, 36(3): 110078-. doi: 10.1016/j.cclet.2024.110078
18. [18]
  Yubang Liu , Jiaxin Lin , Huayu Liang , Yinwu Li , Zhuofeng Ke . Computational insights into three-centre four-electron bridging hydride bond in boryl type PBP-M dihydride complexes^{✰ ✩}. Chinese Chemical Letters, 2025, 36(5): 110291-. doi: 10.1016/j.cclet.2024.110291
19. [19]
  Jin Li , Xin Chen , Aling Chen , Zhi-Qiang Wang , Dengsong Zhang . Theoretical insight into the active sites for chlorobenzene oxidation: From phosphate to M₃ clusters. Chinese Chemical Letters, 2025, 36(8): 110527-. doi: 10.1016/j.cclet.2024.110527
20. [20]
  Yanhui Lu , Chengang Pei , Wenqiang Li , Qing Liu , Huan Pang , Xu Yu . Tailoring active sites of cerium and nitrogen Co-doped rhenium disulfide for enhanced hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(12): 111646-. doi: 10.1016/j.cclet.2025.111646

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(10)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142