Citation: Xia Mi, Chaoyang Wang, Jingyu Zhang, Remi Chauvin, Xiuling Cui. Recent progress in the visible-light-promoted synthesis of phenanthridines[J]. Chinese Chemical Letters, ;2025, 36(11): 111485. doi: 10.1016/j.cclet.2025.111485 shu

Recent progress in the visible-light-promoted synthesis of phenanthridines

Xia Mi ^{a, *,} ,
Chaoyang Wang ^a ,
Jingyu Zhang ^a ,
Remi Chauvin ^c ,
Xiuling Cui ^{b, *,}

a.
College of Pharmacy, Henan University of Chinese Medicine, Zhengzhou 450046, China
b.
Pingyuan Laboratory, and College of Chemistry, Zhengzhou University, Zhengzhou 450052, China
c.
University of Toulouse, Toulouse 3-Paul Sabatier, Toulouse 31077, France

mixia@hactcm.edu.cn

cuixl@zzu.edu.cn

Received Date: 25 January 2025
Revised Date: 9 June 2025
Accepted Date: 17 June 2025
Available Online: 18 June 2025

Figures(54)

Phenanthridine is a key structural motif in numerous natural products and biologically active compounds, making it an attractive target for pharmaceuticals and advanced materials. Recently, visible-light-induced cyclization through radical process has emerged as a powerful and sustainable strategy for building such a core under mild and environmentally friendly conditions, paving the way for new applications in synthetic and medicinal chemistry. This review highlights recent progress in the photochemical synthesis of phenanthridines, mainly focusing on various radical acceptors, including 2-isocyanobiaryls, cyanides, vinyl azides and vinyl benzotriazoles.
- Phenanthridine,
- Photochemistry,
- Radical cascade,
- Isocyanobiaryls,
- Cyanides,
- Vinyl azides
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沈阳化工大学材料科学与工程学院沈阳 110142