Citation: Wanting Sun, Lan Deng, Mengyun Zhao, Tianfu Liu, Hongjin Lv. Controllable syntheses of {SbW₉O₃₃}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction[J]. Chinese Chemical Letters, ;2026, 37(9): 111416. doi: 10.1016/j.cclet.2025.111416 shu

Controllable syntheses of {SbW₉O₃₃}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

landeng@bit.edu.cn

liutf@bit.edu.cn

hlv@bit.edu.cn

Received Date: 17 April 2025
Revised Date: 28 May 2025
Accepted Date: 6 June 2025
Available Online: 6 June 2025

Figures(6)

In this work, we report the controllable synthesis and characterization of four atomically precise silver clusters, Ag₁₈(SbW₉O₃₃)₂(DPPP)₈ (1, DPPP = 1,3-bis(diphenyphosphino)propane), Ag₁₈(SbW₉O₃₃)₂(DPPB)₈ (2, DPPB = 1,4-bis(diphenylphosphino)butane), Ag₁₈(SbW₉O₃₃)₂(DPPPe)₈ (3, DPPPe = 1,5-bis(diphenylphosphino)pentane), and Ag₁₈(SbW₉O₃₃)₂(TPP)₁₄ (4, TPP = triphenylphosphine) by using a facile one-pot solvothermal approach. The resulting four Ag clusters exhibit similar lacunary [SbW₉O₃₃]^9‒ ({SbW₉O₃₃})-sandwiched structures, which can be adjusted by the external different phosphine ligands. In addition, all four clusters display variable physicochemical and catalytic performance, correlating well to their distinct molecular structures.
- Polyoxometalates,
- Silver nanoclusters,
- Photoluminescence,
- Photothermal conversion,
- 4-Nitrophenol reduction
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沈阳化工大学材料科学与工程学院沈阳 110142

Controllable syntheses of {SbW9O33}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction

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通讯作者: 陈斌, bchen63@163.com

Controllable syntheses of {SbW₉O₃₃}-sandwiched silver clusters induced by external phosphine ligands towards 4-nitrophenol reduction