Citation: Jialin Zheng, Fang Xu, Ao Wang, Zhenjiang Li, Mengqin Song, Chunyan Xu, Cheng Yun, Beinuo Zhang, Dai-Huo Liu. Cation/anion synergy induced (100) plane dense deposition for dendrite-free aqueous zinc-ion batteries[J]. Chinese Chemical Letters, ;2026, 37(1): 111415. doi: 10.1016/j.cclet.2025.111415 shu

Cation/anion synergy induced (100) plane dense deposition for dendrite-free aqueous zinc-ion batteries

Key Laboratory of Green Chemical Media and Reactions, Ministry of Education Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

xufang@htu.edu.cn

liudaihuo@htu.edu.cn

Received Date: 20 March 2025
Revised Date: 28 May 2025
Accepted Date: 6 June 2025
Available Online: 6 June 2025

Figures(6)

Aqueous zinc-ion batteries (AZIBs) have advantages including low economic cost and high safety. Nevertheless, the serious hydrogen evolution reactions (HER) and rampant growth of Zn dendrite hinder their further development. Herein, potassium acetate (KAc) additive with cation/anion synergy effect is added into the ZnSO₄ electrolyte to effectively promote the oriented uniform Zn deposition and suppress side reactions. According to density functional theory calculation and experimental results, CH₃COO⁻ (Ac⁻) anions are capable of forming stronger hydrogen bonds with H₂O molecules, leading to an expanded electrochemical stability window, reduced the reactivity of H₂O, and hence suppressing HER. Meanwhile, Ac⁻ anions can also preferentially adsorb onto the Zn anode, promoting dense deposition towards the (100) crystal plane. Besides, dissociated K⁺ ions serve as electrostatic shielding cations, which significantly promote uniform Zn deposition and prevent dendrite formation. Thus, the ZnZn symmetric cell demonstrates an impressive cycle lifespan of 3000 h at 1.0 mA/cm². Furthermore, the ZnMnO₂ full battery exhibits superior stability with a capacity retention of 86.95% at 2.0 A/g after 4000 cycles. Therefore, the cation/anion synergy effect in KAc additive offers a viable solution to address HER and hinder dendrite growth at the interface of Zn anodes.
- Hydrogen bond network,
- Cation/anion synergy,
- (100) plan dense deposition,
- Electrolyte additive,
- Aqueous zinc-ion battery
1. [1]
  Q. Guo, G. Teri, W. Mo, et al., Energy Environ. Sci. 17 (2024) 2888–2896. doi: 10.1039/D4EE00986J
2. [2]
  L. Hong, J. Guan, Y. Tan, et al., Energy Environ. Sci. 17 (2024) 3157–3167. doi: 10.1039/D4EE00199K
3. [3]
  A. Wang, D. Liu, L. Yang, et al., Carbon Energy 6 (2024) e512. doi: 10.1002/cey2.512
4. [4]
  S. Deng, B. Xu, J. Zhao, et al., Angew. Chem. Int. Ed. 63 (2024) e202401996. doi: 10.1002/anie.202401996
5. [5]
  S. Deng, Y. Sun, Z. Yang, et al., Adv. Funct. Mater. 34 (2024) 2408546. doi: 10.1002/adfm.202408546
6. [6]
  J. Cao, Y. Sun, D. Zhang, et al., Adv. Energy Mater. 14 (2023) 2302770.
7. [7]
  L. Ma, M.A. Schroeder, O. Borodin, et al., Nat. Energy 5 (2020) 743–749. doi: 10.1038/s41560-020-0674-x
8. [8]
  N. Guo, Z. Peng, W. Huo, et al., Small 19 (2023) 2303963. doi: 10.1002/smll.202303963
9. [9]
  D. Liu, A. Wang, Y. Liu, et al., Adv. Mater. 37 (2025) 2501624. doi: 10.1002/adma.202501624
10. [10]
  T. Wang, P. Wang, L. Pan, et al., Adv. Energy Mater. 13 (2022) 2203523.
11. [11]
  H. Chen, H. Meng, T. Zhang, et al., Angew. Chem. Int. Ed. 63 (2024) e202402327. doi: 10.1002/anie.202402327
12. [12]
  X. Yu, Z. Li, X. Wu, et al., Joule 7 (2023) 1145–1175. doi: 10.1016/j.joule.2023.05.004
13. [13]
  X. Ma, H. Yu, C. Yan, et al., J. Colloid Interface Sci. 664 (2024) 539–548. doi: 10.1016/j.jcis.2024.03.085
14. [14]
  W. Ma, S. Wang, X. Wu, et al., Energy Environ. Sci. 17 (2024) 4819–4846. doi: 10.1039/D4EE00313F
15. [15]
  Z. Liu, R. Wang, Q. Ma, et al., Adv. Funct. Mater. 34 (2023) 2214538.
16. [16]
  X. Liang, X. Chen, Z. Zhai, et al., Chem. Eng. J. 493 (2024) 152622. doi: 10.1016/j.cej.2024.152622
17. [17]
  F. Liu, C. Shi, X. Guo, et al., Adv. Sci. 9 (2022) 2200307. doi: 10.1002/advs.202200307
18. [18]
  A. Raza, K. Deen, E. Asselin, et al., Renew. Sustain. Energy Rev. 161 (2022) 112323. doi: 10.1016/j.rser.2022.112323
19. [19]
  D. Chao, S. Qiao, Joule 4 (2020) 1846–1851. doi: 10.1016/j.joule.2020.07.023
20. [20]
  W. Xu, X. Ma, P. Lyu, et al., React. Chem. Eng. 10 (2025) 214–223. doi: 10.1039/D4RE00366G
21. [21]
  D. Sheng, X. Liu, Z. Yang, et al., Adv. Funct. Mater. 34 (2024) 2402014. doi: 10.1002/adfm.202402014
22. [22]
  F. Bu, Y. Gao, W. Zhao, et al., Angew. Chem. Int. Ed. 63 (2024) e202318496. doi: 10.1002/anie.202318496
23. [23]
  Z. Feng, Y. Feng, F. Fan, et al., SusMat 4 (2024) e184. doi: 10.1002/sus2.184
24. [24]
  H. Fu, S. Huang, T. Wang, et al., Adv. Mater. 37 (2024) 2411686.
25. [25]
  H. Tang, N. Hu, L. Ma, et al., Adv. Funct. Mater. 34 (2024) 2402484. doi: 10.1002/adfm.202402484
26. [26]
  Z. Peng, X. Shen, B. Li, et al., Prog. Mater Sci. 152 (2025) 101453. doi: 10.1016/j.pmatsci.2025.101453
27. [27]
  X. Feng, P. Li, J. Yin, et al., ACS Energy Lett. 8 (2023) 1192–1200. doi: 10.1021/acsenergylett.2c02455
28. [28]
  Y. Xu, J. Zhu, J. Feng, et al., Energy Storage Mater 38 (2021) 299–308. doi: 10.1016/j.ensm.2021.03.019
29. [29]
  M. Liu, Y. Wang, Y. Li, et al., Adv. Mater. 36 (2024) 2406145. doi: 10.1002/adma.202406145
30. [30]
  Z. Hu, F. Zhang, Y. Zhao, et al., Adv. Mater. 34 (2022) 2203104. doi: 10.1002/adma.202203104
31. [31]
  G. Ma, L. Miao, Y. Dong, et al., Energy Storage Mater. 47 (2022) 203–210. doi: 10.1016/j.ensm.2022.02.019
32. [32]
  Y. Wang, Z. Wang, W. Pang, et al., Nat. Commun. 14 (2023) 2720. doi: 10.1038/s41467-023-38384-x
33. [33]
  X. Gu, Y. Du, X. Ren, et al., Adv. Funct. Mater. 34 (2024) 2316541. doi: 10.1002/adfm.202316541
34. [34]
  M. Shi, C. Lei, H. Wang, et al., Angew. Chem. Int. Ed. 63 (2024) e202407261. doi: 10.1002/anie.202407261
35. [35]
  X. Li, J. Miao, F. Hu, et al., J. Mater. Chem. A 12 (2024) 968–978. doi: 10.1039/D3TA05814J
36. [36]
  M. Zhang, H. Hua, P. Dai, et al., Adv. Mater. 35 (2023) 2208630.
37. [37]
  D. Xu, X. Ren, H. Li, et al., Angew. Chem. Int. Ed. 63 (2024) e202402833. doi: 10.1002/anie.202402833
38. [38]
  C. Lv, X. Zhou, L. Zhong, et al., Adv. Mater. 34 (2021) 2101474.
39. [39]
  W. Zhang, Y. Liu, Z. Guo, Sci. Adv. 5 (2019) eaav7412. doi: 10.1126/sciadv.aav7412
40. [40]
  P. Pau, J. Berg, W. McMillan, J. Phys. Chem. 94 (1990) 2671–2679. doi: 10.1021/j100369a080
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2. [2]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
3. [3]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
4. [4]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
5. [5]
  Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma . Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries. Chinese Chemical Letters, 2024, 35(12): 110014-. doi: 10.1016/j.cclet.2024.110014
6. [6]
  Aonan Wang , Jingwen Dai , Yiming Guo , Fanghua Ning , Xiaoyu Liu , Sidra Subhan , Jiaqian Qin , Shigang Lu , Jin Yi . Imidazolium bromide based dual-functional redox mediator for the construction of dendrite-free Li-CO₂ batteries. Chinese Chemical Letters, 2025, 36(7): 110186-. doi: 10.1016/j.cclet.2024.110186
7. [7]
  Mengxiao Yang , Haicheng Huang , Shiyi Shen , Xinxin Liu , Mengyu Liu , Jiahua Guo , Fenghui Yang , Baoli Zha , Jiansheng Wu , Sheng Li , Fengwei Huo . Flexible aqueous zinc-ion battery with low-temperature resistant leather gel electrolyte. Chinese Chemical Letters, 2025, 36(6): 109988-. doi: 10.1016/j.cclet.2024.109988
8. [8]
  Canglong Li , Tao Liao , Dongping Chen , Tiancheng You , Xiaozhi Jiang , Minghan Xu , Huaming Yu , Gang Zhou , Guanghui Li , Yuejiao Chen . Fabrication of carbon-coated V₂O_5-x nanoparticles by plasma-enhanced chemical vapor deposition for high-performance aqueous zinc-ion battery composite cathodes. Chinese Chemical Letters, 2025, 36(12): 110557-. doi: 10.1016/j.cclet.2024.110557
9. [9]
  Wenjie Ma , Yakun Tang , Yue Zhang , Lang Liu , Bin Tang , Dianzeng Jia , Yuliang Cao . Cation-disordered Li₂FeTiO₄ nanoparticles with multiple cation and anion redox for symmetric lithium-ion batteries. Chinese Chemical Letters, 2025, 36(9): 110346-. doi: 10.1016/j.cclet.2024.110346
10. [10]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
11. [11]
  Xiaoxi Zhao , Qingyun Dou , Pei Tang , Bingjun Yang , Qunji Xue , Xingbin Yan . In-situ construction of solid electrolyte interphase for stable zinc anode via synergy of electrochemical reduction and chemical precipitation. Chinese Chemical Letters, 2025, 36(11): 110422-. doi: 10.1016/j.cclet.2024.110422
12. [12]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
13. [13]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
14. [14]
  Tong Peng , Yupeng Xing , Lan Mu , Chenggang Wang , Ning Zhao , Wenbo Liao , Jianlei Li , Gang Zhao . Recent research on aqueous zinc-ion batteries and progress in optimizing full-cell performance. Chinese Chemical Letters, 2025, 36(6): 110039-. doi: 10.1016/j.cclet.2024.110039
15. [15]
  Long Huang , Jian Pu , Yunyu Zhao , Xiangxiang Fang , Yingjian Yu , Yuan Li , Jinyan Ma , Yuejin Zhu , Fang Hu , Chuang Yue . Phosphorus-doped carbon as an effective protective layer for advanced aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110989-. doi: 10.1016/j.cclet.2025.110989
16. [16]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
17. [17]
  Le Li , Shaofeng Jia , Shi Yue , Yuanyuan Yang , Chao Tan , Conghui Wang , Hengwei Qiu , Yongqiang Ji , Minghui Cao , Zige Tai , Dan Zhang . Vanadium doping inhibit the Jahn−Teller effect of Mn³⁺ for high-performance aqueous zinc ion battery. Chinese Chemical Letters, 2025, 36(10): 111009-. doi: 10.1016/j.cclet.2025.111009
18. [18]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
19. [19]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-0. doi: 10.3866/PKU.WHXB202308048
20. [20]
  Xiaojun Wang , Yizhou Zhang , Linwei Guo , Jianwei Li , Peng Wang , Lei Yang , Zhiming Liu . V₂CT_X MXene-derived ammonium vanadate with robust carbon skeleton for superior rate aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(8): 111231-. doi: 10.1016/j.cclet.2025.111231

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