Citation: Song-Lin Tian, Li-Na Song, Li-Min Chang, Wan-Qiang Liu, De-Hui Guan, Ji-Jing Xu. A magnetic/thermal coupling assisted lithium-oxygen battery based on magnetic heating effect of single atom-Co/MoS₂ cathode[J]. Chinese Chemical Letters, ;2026, 37(8): 111349. doi: 10.1016/j.cclet.2025.111349 shu

A magnetic/thermal coupling assisted lithium-oxygen battery based on magnetic heating effect of single atom-Co/MoS₂ cathode

Song-Lin Tian ^{a, b} ,
Li-Na Song ^{c, d} ,
Li-Min Chang ^b ,
Wan-Qiang Liu ^{a, *,} ,
De-Hui Guan ^{c, d, *,} ,
Ji-Jing Xu ^{c, d, *,}

a.
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130012, China
b.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials of the Ministry of Education, Jilin Normal University, Changchun 130103, China
c.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
d.
International Center of Future Science, Jilin University, Changchun 130012, China

wqliu1979@126.com

guandehui@jlu.edu.cn

jijingxu@jlu.edu.cn

Received Date: 15 April 2025
Revised Date: 14 May 2025
Accepted Date: 19 May 2025
Available Online: 19 May 2025

Figures(5)

Lithium−oxygen (Li−O₂) batteries exhibit a superior energy density compared with any other battery currently available on the market. However, the practical application has been impeded by the insulated, insoluble discharge product (Li₂O₂). The limitations caused by Li₂O₂ are hardly to be addressed through the conventional catalyst design, which relies on the electronic structure and interfacial charge transfer characteristics. Herein, a magnetic/thermal coupling assisted Li−O₂ batteries based on the thermoelectric material of MoS₂ and magnetism single atom cobalt (SA−Co/MoS₂) was constructed for the first time, by combing the magnetic heating and the thermoelectric catalytic effect. The spin polarization of the single atom Co may be promoted and a magnetic heating effect is generated by an external magnetic field, speeding up the oxygen evolution process (OER) and oxygen reduction reaction (ORR), as well as promoting the parallel spin arrangement of oxygen atoms. Because of its special SA−Co/MoS₂ cathode, the Li−O₂ battery with magnetic/thermal coupling assistance offers an ultra-low charging platform of 3.33 V and an ultra-high discharge platform of 2.90 V. The proposed novel method of sustaining the magnetic and thermal fields provides a crucial guidance for adjusting the excessive overpotential in metal−air battery systems.
- Li−O₂ batteries,
- Energy storage,
- Field assisted,
- Cathode,
- Overpotential
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A magnetic/thermal coupling assisted lithium-oxygen battery based on magnetic heating effect of single atom-Co/MoS2 cathode

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通讯作者: 陈斌, bchen63@163.com

A magnetic/thermal coupling assisted lithium-oxygen battery based on magnetic heating effect of single atom-Co/MoS₂ cathode