Citation: Yueheng Yu, Wanjie Gao, Yi Peng, Yuhan Lu, Jiarui He, Yuping Wu. Advanced electrolytes toward high-performance sodium secondary batteries[J]. Chinese Chemical Letters, ;2026, 37(8): 111309. doi: 10.1016/j.cclet.2025.111309 shu

Advanced electrolytes toward high-performance sodium secondary batteries

Confucius Energy Storage Lab, School of Energy and Environment & Z Energy Storage Center, Southeast University, Nanjing 211189, China

hejiarui123@sina.com

wuyp@seu.edu.cn

Received Date: 21 February 2025
Revised Date: 28 April 2025
Accepted Date: 13 May 2025
Available Online: 17 May 2025

Figures(12)

Sodium-based batteries (SBBs) are considered as promising next-generation energy storage devices owing to the low cost and natural abundance of raw materials. As the blood of SSBs, electrolytes are required to exhibit specific properties, including broad electrochemical stability windows, high thermal stability, prior ionic conductivity, and so on. Therefore, a diverse array of materials and compositions were developed to form novel electrolytes, thereby satisfying the practical requirements of SSBs. In this review, we comprehensively summarize the latest advances and the corresponding electrochemical properties of different electrolytes for SBBs. First, this review describes the desirable characteristics of electrolytes in detail. Subsequently, the latest progress in the design and regulation of electrolytes is systematically analyzed from four key aspects: organic liquid electrolytes, aqueous electrolytes, solid-state electrolytes, and quasi-solid-state electrolytes. Finally, this review delivers an exhaustive illustration on the challenges and research prospects concerning the further development of electrolytes in SBBs.
- Electrolytes,
- Sodium-based batteries,
- Electrochemical behaviors,
- Interface properties,
- Design strategies
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沈阳化工大学材料科学与工程学院沈阳 110142