Citation: Rong Zhang, Yong Chen, Zhiyi Yu, Yu Liu. Laponite cascade assembly activated reversible multicolor luminescence supramolecular hydrogel with near-infrared emission[J]. Chinese Chemical Letters, ;2026, 37(1): 111147. doi: 10.1016/j.cclet.2025.111147 shu

Laponite cascade assembly activated reversible multicolor luminescence supramolecular hydrogel with near-infrared emission

College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

yuliu@nankai.edu.cn

Received Date: 23 September 2024
Revised Date: 12 March 2025
Accepted Date: 26 March 2025
Available Online: 27 March 2025

Figures(6)

Photo-responsive supramolecular assembly especially supramolecular hydrogels with tunable luminescence show a promising application potential in writable information recording and display materials. Herein, we report photo-responsive reversible multicolor supramolecular hydrogel with near-infrared emission, which is constructed by cucurbit[7]uril (CB[7]), cyanostilbene derivative (DAC) and Laponite XLG (LP) via supramolecular cascade assembly. Compared with the free guest molecule DAC, the confinement of macrocycle CB[7] achieve effective near-infrared fluorescence in the aqueous phase from scratch, and the subsequent cascade assembly with LP further restrict the molecular rotation of the DAC, which not only result in a substantial enhancement of the fluorescence intensity, but is also endowed with light-controlled fluorescence on/off both in the solution and hydrogel states. Further, 8–hydroxy-1,3,6-pyrenetrisulfonic acid trisodium salt (HPTS) is introduced in the cascade assembly to fabricated photo-controllable reversible multicolor luminescence supramolecular hydrogel between red and green induced by Förster resonance energy transfer, which is successfully employed in reversible multiple information encryption.
- Supramolecular cascade system,
- Multicolor luminescence,
- Photo-responsiveness,
- Cucurbituril,
- Dynamic anti-counterfeiting
1. [1]
  C. Kaspar, B.J. Ravoo, W.G. van der Wiel, S.V. Wegner, W.H.P. Pernice, Nature 594 (2021) 345–355. doi: 10.1038/s41586-021-03453-y
2. [2]
  W.T. Xu, X. Li, P.C. Wu, et al., Angew. Chem. Int. Ed. 63 (2024) e202319502. doi: 10.1002/anie.202319502
3. [3]
  Q.K. Qi, S.Q. Huang, X.G. Liu, I. Aprahamian, J. Am. Chem. Soc. 146 (2024) 6471–6475. doi: 10.1021/jacs.4c00592
4. [4]
  W.W. Xu, Y. Chen, X.F. Xu, Y. Liu, Small 20 (2024) 2311087. doi: 10.1002/smll.202311087
5. [5]
  Y. Chen, L.B. Li, L.S. Gong, T.Y. Zhou, J.B. Liu, Adv. Funct. Mater. 29 (2019) 1806945. doi: 10.1002/adfm.201806945
6. [6]
  W. Szymanski, J.M. Beierle, H.A.V. Kistemaker, W.A. Velema, B.L. Feringa, Chem. Rev. 113 (2013) 6114–6178. doi: 10.1021/cr300179f
7. [7]
  M.L. Lian, J. Zhao, D. Zhang, et al., Angew. Chem. Int. Ed. 63 (2024) e202401228. doi: 10.1002/anie.202401228
8. [8]
  Y.L. Zhu, Y.G. Tang, P. Miao, Langmuir 40 (2023) 1130–1136. doi: 10.1007/s11605-023-05610-2
9. [9]
  Z. Liu, H. Chen, M. Tian, et al., Aggregate 5 (2024) e627. doi: 10.1002/agt2.627
10. [10]
  X.L. Zhou, X. Zhao, X. Bai, Q.W. Cheng, Y. Liu, Adv. Funct. Mater. 34 (2024) 2400898. doi: 10.1002/adfm.202400898
11. [11]
  J.F. Liu, D.K. Ma, C.Z. Qi, D.P. Yang, S.M. Huang, ACS Appl. Mater. Inter. 16 (2024) 2740–2750. doi: 10.1021/acsami.3c15120
12. [12]
  Y. Zhang, Y. Chen, J.Q. Li, S.E. Liu, Y. Liu, Adv. Sci. 11 (2024) 2307777. doi: 10.1002/advs.202307777
13. [13]
  Y. Yin, Q.C. Guan, Z. Chen, et al., Sci. Adv. 10 (2024) eadk5444. doi: 10.1126/sciadv.adk5444
14. [14]
  R. Lan, J. Bao, Z. Li, et al., Angew. Chem. Int. Ed. 61 (2022) e202213915. doi: 10.1002/anie.202213915
15. [15]
  R. Zhang, Y. Chen, L. Chen, Y. Zhang, Y. Liu, Adv. Opt. Mater. 11 (2023) 2300101. doi: 10.1002/adom.202300101
16. [16]
  H.J. Wang, H.Y. Zhang, W.W. Xing, et al., Chin. Chem. Lett. 33 (2022) 4033–4036. doi: 10.1016/j.cclet.2021.12.051
17. [17]
  L. Fei, W.D. Yu, Z.H. Wu, et al., Angew. Chem. Int. Ed. 61 (2022) e202212483. doi: 10.1002/anie.202212483
18. [18]
  Y. Ma, J.D. Shen, J.F. Zhao, et al., Angew. Chem. Int. Ed. 61 (2022) e202202655. doi: 10.1002/anie.202202655
19. [19]
  D. Bléger, S. Hecht, Angew. Chem. Int. Ed. 54 (2015) 11338–11349. doi: 10.1002/anie.201500628
20. [20]
  S.Y. Lin, K.G. Gutierrez-Cuevas, X.F. Zhang, J.B. Guo, Q. Li, Adv. Funct. Mater. 31 (2021) 2007957. doi: 10.1002/adfm.202007957
21. [21]
  Y.Z. Liu, H.L. Wang, P.R. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 5766–5770. doi: 10.1002/anie.202015597
22. [22]
  L.N. Lameijer, S. Budzak, N.A. Simeth, et al., Angew. Chem. Int. Ed. 59 (2020) 21663–21670. doi: 10.1002/anie.202008700
23. [23]
  H.M.D. Bandara, S.C. Burdette, Chem. Soc. Rev. 41 (2012) 1809–1825. doi: 10.1039/C1CS15179G
24. [24]
  P. Lentes, E. Stadler, F. Röhricht, et al., J. Am. Chem. Soc. 141 (2019) 13592–13600. doi: 10.1021/jacs.9b06104
25. [25]
  M. Irie, T. Fulcaminato, K. Matsuda, S. Kobatake, Chem. Rev. 114 (2014) 12174–12277. doi: 10.1021/cr500249p
26. [26]
  T. Fukaminato, T. Hirose, T. Doi, et al., J. Am. Chem. Soc. 136 (2014) 17145–17154. doi: 10.1021/ja5090749
27. [27]
  R. Kashihara, M. Morimoto, S. Ito, H. Miyasaka, M. Irie, J. Am. Chem. Soc. 139 (2017) 16498–16501. doi: 10.1021/jacs.7b10697
28. [28]
  H.C. Xi, Z.P. Zhang, W.W. Zhang, et al., J. Am. Chem. Soc. 141 (2019) 18467–18474. doi: 10.1021/jacs.9b07357
29. [29]
  C.H. Wang, Y.M. Zhang, H.R. Li, et al., Chin. Chem. Lett. 33 (2022) 2447–2450. doi: 10.1016/j.cclet.2021.09.106
30. [30]
  L. Kortekaas, W.R. Browne, Chem. Soc. Rev. 48 (2019) 3406–3424. doi: 10.1039/c9cs00203k
31. [31]
  R. Klajn, Chem. Soc. Rev. 43 (2014) 148–184. doi: 10.1039/C3CS60181A
32. [32]
  J.H. Huang, Y. Jiang, Q.Y. Chen, H. Xie, S.B. Zhou, Nat. Commun. 14 (2023) 7131. doi: 10.1038/s41467-023-42795-1
33. [33]
  C.Y. Huang, A. Bonasera, L. Hristov, et al., J. Am. Chem. Soc. 139 (2017) 15205–15211. doi: 10.1021/jacs.7b08726
34. [34]
  K. Klaue, W.J. Han, P. Liesfled, et al., J. Am. Chem. Soc. 142 (2020) 11857–11864. doi: 10.1021/jacs.0c04219
35. [35]
  L. Fang, Z.W. Lin, Y. Zhang, et al., Angew. Chem. Int. Ed. 63 (2024) e202402349. doi: 10.1002/anie.202402349
36. [36]
  Y.L. Huang, H.K. Bisoyi, S. Huang, et al., Angew. Chem. Int. Ed. 60 (2021) 11247–11251. doi: 10.1002/anie.202101881
37. [37]
  R. Zhang, Y. Chen, Y. Liu, Angew. Chem. Int. Ed. 62 (2023) e202315749. doi: 10.1002/anie.202315749
38. [38]
  W.C. Zhong, L. Shang, Chem. Sci. 15 (2024) 6218–6228. doi: 10.1039/d4sc00114a
39. [39]
  K. Mutoh, N. Miyashita, K. Arai, J. Abe, J. Am. Chem. Soc. 141 (2019) 5650–5654. doi: 10.1021/jacs.9b01870
40. [40]
  J.Y. Zhang, C.J. Song, S.N. Zhang, et al., Adv. Funct. Mater. 34 (2024) 2400030. doi: 10.1002/adfm.202400030
41. [41]
  H. Wu, Y. Chen, Y. Liu, Adv. Mater. 29 (2017) 1605271. doi: 10.1002/adma.201605271
42. [42]
  W.L. Zhou, Y.G. Wu, S.W. Wang, et al., Biosens. Bioelectron. 258 (2024) 116343. doi: 10.1016/j.bios.2024.116343
43. [43]
  S.E. Liu, Y. Zhang, J.Q. Li, et al., ACS Appl. Mater. Inter. 16 (2024) 5149–5157. doi: 10.1021/acsami.3c17214
44. [44]
  Z. Li, X.F. Ji, H.L. Xie, B.Z. Tang, Adv. Mater. 33 (2021) 2100021. doi: 10.1002/adma.202100021
45. [45]
  H. Liu, S.X. Wei, H.Y. Qiu, et al., Adv. Funct. Mater. 32 (2022) 2108830. doi: 10.1002/adfm.202108830
46. [46]
  Y. Sun, X.X. Le, H. Shang, et al., Adv. Mater. 36 (2024) 2401589. doi: 10.1002/adma.202401589
47. [47]
  B.Y. Wu, M.Q. Si, L.Q. Hua, et al., Adv. Mater. 36 (2024) 2401659. doi: 10.1002/adma.202401659
48. [48]
  G.M.Y. Su, N. Wang, Y.K. Liu, et al., Adv Mater 36 (2024) 2400085. doi: 10.1002/adma.202400085
49. [49]
  H.L. Yang, S.N. Li, J.X. Zheng, et al., Adv. Mater. 35 (2023) 2301300. doi: 10.1002/adma.202301300
50. [50]
  P.Y. Xing, H.Z. Chen, L.Y. Bai, Y.L. Zhao, Chem. Commun. 51 (2015) 9309–9312. doi: 10.1039/C5CC02816G
51. [51]
  L.L. Zhu, X. Li, Q. Zhang, X. Ma, et al., J. Am. Chem. Soc. 135 (2013) 5175–5182. doi: 10.1021/ja400456h
52. [52]
  Q.H. Cheng, Z.Z. Cao, A.Y. Hao, Y.L. Zhao, P. Y. Xing, ACS Appl. Mater. Inter. 12 (2020) 15491–15499. doi: 10.1021/acsami.0c04418
53. [53]
  G.X. Liu, Y.M. Zhang, X.F. Xu, L. Zhang, Y. Liu, Adv. Optical Mater. 5 (2017) 1700149. doi: 10.1002/adom.201700149
1. [1]
  Guoxing Liu , Yixin Li , Changming Tian , Yongmei Xiao , Lijie Liu , Zhanqi Cao , Song Jiang , Xin Zheng , Caoyuan Niu , Yun-Lai Ren , Liangru Yang , Xianfu Zheng , Yong Chen . Highly reversible photomodulated hydrosoluble stiff-stilbene supramolecular luminophor induced by cucurbituril. Chinese Chemical Letters, 2024, 35(8): 109403-. doi: 10.1016/j.cclet.2023.109403
2. [2]
  Qian Ren , Xue Dai , Ran Cen , Yang Luo , Mingyang Li , Ziyun Zhang , Qinghong Bai , Zhu Tao , Xin Xiao . A cucurbit[8]uril-based supramolecular phosphorescent assembly: Cell imaging and sensing of amino acids in aqueous solution. Chinese Chemical Letters, 2024, 35(12): 110022-. doi: 10.1016/j.cclet.2024.110022
3. [3]
  Jianqiu Li , Yi Zhang , Songen Liu , Jie Niu , Rong Zhang , Yong Chen , Yu Liu . Cucurbit[8]uril-based non-covalent heterodimer realized NIR cell imaging through topological transformation from nanowire to nanorod. Chinese Chemical Letters, 2024, 35(10): 109645-. doi: 10.1016/j.cclet.2024.109645
4. [4]
  Haiyang Gu , Xiang Xu . Multicolor hybrid metal halides and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(9): 100352-100352. doi: 10.1016/j.cjsc.2024.100352
5. [5]
  Wen-Wen Xu , Yue-Xiu Qin , Xiao-Yong Yu , Lin-Nan Jiang , Heng-Yi Zhang , Yong Chen , Yu Liu . Multipath cascade light harvesting for multicolor luminescence based on macrocyclic sulfonatocalix[4]arene. Chinese Chemical Letters, 2025, 36(11): 111068-. doi: 10.1016/j.cclet.2025.111068
6. [6]
  Siyu Zong , Xiaowei Yu , Yining Yang , Xin Yang , Jiyang Li . Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite. Chinese Chemical Letters, 2025, 36(6): 110343-. doi: 10.1016/j.cclet.2024.110343
7. [7]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
8. [8]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
9. [9]
  Yinghao Zhang , Ke Shao , Yihang Zhu , Haokun Zhang , Yinuo Zhuo , Huihui Bao , Yeye Ai , Yongguang Li . Unanticipated optical properties of π-conjugated cyclometalated Pt(Ⅱ) complexes for advanced information storage and anti-counterfeiting materials. Chinese Chemical Letters, 2025, 36(9): 110735-. doi: 10.1016/j.cclet.2024.110735
10. [10]
  Hong Wang , Yong Tian , Tiancheng Wu , Shun He , Jiaxi Cui , Jian Chen , Xudong Chen . Photoswitchable dual-color fluorescent polymeric nanoparticles for self-erased time-resolved information encryption and anti-counterfeiting. Chinese Chemical Letters, 2025, 36(7): 110509-. doi: 10.1016/j.cclet.2024.110509
11. [11]
  Linnan Jiang , Zhenkai Qian , Yong Chen , Xiaoyong Yu , Yugui Qiu , Wen-Wen Xu , Yonghui Sun , Xiufang Xu , Lihua Wang , Yu Liu . Double response reversible phosphorescence based on cyclodextrin supramolecular flexible elastic achieved multicolor delayed fluorescence. Chinese Chemical Letters, 2025, 36(8): 110676-. doi: 10.1016/j.cclet.2024.110676
12. [12]
  Xingyue Yuan , Li Wu , Qiuyu Peng , Yanyan Tang , Mingxu Wang , Yuhang Wei , Zhu Tao , Xin Xiao . Developing color-tunable long afterglow anti-counterfeiting materials using cucurbit[6]uril and classical aggregation-caused quenching compounds through multiple non-covalent interactions. Chinese Chemical Letters, 2025, 36(9): 110821-. doi: 10.1016/j.cclet.2025.110821
13. [13]
  Zhen Dai , Linzhi Tan , Yeyu Su , Kerui Zhao , Yushun Tian , Yu Liu , Tao Liu . Site-specific incorporation of reduction-controlled guest amino acids into proteins for cucurbituril recognition. Chinese Chemical Letters, 2024, 35(5): 109121-. doi: 10.1016/j.cclet.2023.109121
14. [14]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
15. [15]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
16. [16]
  Junying Zhang , Ruochen Li , Haihua Wang , Wenbing Kang , Xing-Dong Xu . Photo-induced tunable luminescence from an aggregated amphiphilic ethylene-pyrene derivative in aqueous media. Chinese Chemical Letters, 2024, 35(6): 109216-. doi: 10.1016/j.cclet.2023.109216
17. [17]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
18. [18]
  Chenchen Xie , Jun Liao , Yi Li , Yunan Zhang , Zhicheng Xiao , Yun Wang , Ting Chen , Liyan Xiong , Tao Pang , Xiangao Jiang , Feng Zhang , Chuan Zhang , Tingfang Wang . Synergistic anti-inflammatory effect of cascade nanozymes for neural recovery in ischemic stroke. Chinese Chemical Letters, 2026, 37(1): 110956-. doi: 10.1016/j.cclet.2025.110956
19. [19]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
20. [20]
  Huijuan Zhang , Chenglin Liang , Xinyi Ding , Meng Zhang , Siyu Lu , Lin Hou . Manganese-based nano-delivery system for sensitized anti-tumor immunotherapy via combined autophagy inhibition. Chinese Chemical Letters, 2025, 36(7): 110525-. doi: 10.1016/j.cclet.2024.110525

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(4)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142