Citation: Qiyue Luo, Chen Liu, Siwu Li, Chaochao Wei, Zhongkai Wu, Lin Li, Ziling Jiang, Liping Li, Guangshe Li, Shijie Cheng, Chuang Yu. Charge carrier distribution enabling superior electrochemical performance for all-solid-state lithium batteries over wide temperature range[J]. Chinese Chemical Letters, ;2026, 37(7): 111113. doi: 10.1016/j.cclet.2025.111113 shu

Charge carrier distribution enabling superior electrochemical performance for all-solid-state lithium batteries over wide temperature range

Qiyue Luo ^{a, b} ,
Chen Liu ^a ,
Siwu Li ^{c, *,} ,
Chaochao Wei ^{a, b} ,
Zhongkai Wu ^{a, b} ,
Lin Li ^{a, b} ,
Ziling Jiang ^{a, b} ,
Liping Li ^{d, *,} ,
Guangshe Li ^d ,
Shijie Cheng ^a ,
Chuang Yu ^{a, *,}

a.
State Key Laboratory of Advanced Electromagnetic Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
c.
Key Laboratory of Artificial Olfaction of Shaanxi Higher Education Institutes, the Academy of Advanced Interdisciplinary Research, Xidian University, Xi’an 710126, China
d.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

lisiwu@xidian.edu.cn

lipingli@jlu.edu.cn

cyu2020@hust.edu.cn

Received Date: 11 July 2024
Revised Date: 13 March 2025
Accepted Date: 18 March 2025
Available Online: 18 March 2025

Figures(4)

Argyrodite-based all-solid-state batteries exhibit significant potential as energy storage devices across a wide temperature zone. The Li-ion and electronic conductivities in the cathode mixture is crucial factor in determining the corresponding electrochemical performances. Here, an effective charge carrier distribution is tailored by introducing Li₃InCl₆ electrolyte with wider voltage stability surrounding the bare LiNi_0.7Co_0.2Mn_0.1O₂ to promote ionic conductivity and mixing carbon additives to enhance electronic conductivity. The Li₃InCl₆@LiNi_0.7Co_0.2Mn_0.1O₂/Li_5.5PS_4.5Cl_1.5/Li-In battery exhibits superior electrochemical performance at various C-rates over a wide operating temperature range due to the enhanced charge carrier conducting rates. It delivers high charge/discharge capacities, superior rate capability and exceptional cycling performance. Specifically, the battery delivers initial discharge capacities of 202 mAh/g at 0.2 C and retains a discharge capacity of 162 mAh/g at 2 C with a capacity retention of 91.8% over 500 cycles when cycled at room temperature. Moreover, due to the Li₃InCl₆ coating layer and the carbon additive in the cathode, it exhibits higher discharge capacities and superior cycling performances when operated at -20 and 60 ℃. This work presents a guideline for fabricating high-performance all-climate solid-state lithium batteries via tailoring the charger carriers conducting pathway in the electrode structure.
- Li_5.5PS_4.5Cl_1.5 electrolyte,
- Charge carriers,
- Li₃InCl₆ coating,
- Electronic conductivity,
- Electrochemical performances
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