Citation: Linyu Zhu, Xu Tian, Guang Shi, Wenchi Zhang, Peisong Tang, Mohamed Bououdina, Sajjad Ali, Pengfei Xia. Assembling 3D cross-linked network by carbon nitride nanowires for visible-light photocatalytic H₂ evolution from dyestuffs wastewater[J]. Chinese Chemical Letters, ;2025, 36(12): 111088. doi: 10.1016/j.cclet.2025.111088 shu

Assembling 3D cross-linked network by carbon nitride nanowires for visible-light photocatalytic H₂ evolution from dyestuffs wastewater

Linyu Zhu ^a ,
Xu Tian ^a ,
Guang Shi ^a ,
Wenchi Zhang ^a ,
Peisong Tang ^a ,
Mohamed Bououdina ^c ,
Sajjad Ali ^{c, *,} ,
Pengfei Xia ^{b, *,}

a.
Department of Materials and Chemistry, Huzhou University, Huzhou 313000, China
b.
School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, China
c.
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh 11586, Saudi Arabia

sajjad@psu.edu.sa

forsky@csj.uestc.edu.cn

Received Date: 14 August 2024
Revised Date: 5 February 2025
Accepted Date: 13 March 2025
Available Online: 14 March 2025

Figures(5)

Photocatalytic H₂ evolution from wastewater exhibits fascinating prospects in environment and energy fields. Here, we propose a novel 3D cross-linked g-C₃N₄ network (SCN) assembling with 1D nanowires. This network structure endows SCN with abundant carbon defects, creating a defect energy level and shallow charge trapping centres, which significantly prolongs the photocarrier lifetime, suppresses their recombination and facilitates the mass transfer process during the dye photodegradation. Consequently, in photocatalytic H₂ evolution coupled with Rhodamine B (RhB) photodegradation under visible light, the H₂ production rate of SCN is 283 µmol h⁻¹ g⁻¹, accompanying by 97% RhB photodegradation efficiency, much higher than UCN’s 31 µmol h⁻¹ g⁻¹ and 64%. In particular, AQY of SCN for H₂ evolution from RhB solution reaches 23.7% at 380 nm. Furthermore, the calculated transition states demonstrate that the N1 site connected to the defect in SCN has a minimum Gibbs free energy ∆G (H*), indicating that H⁺ undergoes an H⁺ → H* → H₂ evolution process.
- Photocatalysis,
- Carbon nitride,
- 3D cross-linked network,
- H₂ evolution from wastewater,
- Reaction mechanism
1. [1]
  J. Dong, J. Zhao, X. Yan, et al., Appl. Catal. B: Environ. Energy351 (2024) 123993. doi: 10.1016/j.apcatb.2024.123993
2. [2]
  C. Feng, T. Bo, P. Maity, et al., Adv. Funct. Mater. 34 (2024) 2309761. doi: 10.1002/adfm.202309761
3. [3]
  Y. Gao, X. Zhai, Y. Zhang, et al., Nano Mater. Sci. 5 (2023) 177–188. doi: 10.1016/j.nanoms.2022.01.004
4. [4]
  J. Luo, S. Zhang, M. Sun, L. Yang, J.C. Crittenden, ACS. Nano13 (2019) 9811–9840. doi: 10.1021/acsnano.9b03649
5. [5]
  M. Xiao, Z. Wang, M. Lyu, et al., Adv. Mater. 31 (2019) 1801369. doi: 10.1002/adma.201801369
6. [6]
  S. Meng, C. Chen, X. Gu, et al., Appl. Catal. B: Environ. 285 (2021) 119789. doi: 10.1016/j.apcatb.2020.119789
7. [7]
  P.F. Xia, S.W. Cao, B.C. Zhu, et al., Angew. Chem. Int. Ed. 59 (2020) 5218–5225. doi: 10.1002/anie.201916012
8. [8]
  A. Genoux, M. Pauly, C.L. Rooney, et al., J. Am. Chem. Soc. 145 (2023) 20739–20744. doi: 10.1021/jacs.3c05417
9. [9]
  P.F. Xia, M. Antonietti, B.C. Zhu, et al., Adv. Funct. Mater. 29 (2019) 1900093. doi: 10.1002/adfm.201900093
10. [10]
  G.H. Dong, D.L. Jacobs, L. Zang, C.Y. Wang, Appl. Catal. B: Environ. 218 (2017) 515–524. doi: 10.1016/j.apcatb.2017.07.010
11. [11]
  M. Jourshabani, M.R. Asrami, B.K. Lee, Appl. Catal. B: Environ. 302 (2022) 120839. doi: 10.1016/j.apcatb.2021.120839
12. [12]
  X. Li, J. Yu, M. Jaroniec, Chem. Soc. Rev. 45 (2016) 2603–2636. doi: 10.1039/C5CS00838G
13. [13]
  P.Y. Kuang, M. Sayed, J.J. Fan, B. Cheng, J.G. Yu, Adv. Energy Mater. 10 (2020) 1903802. doi: 10.1002/aenm.201903802
14. [14]
  S. An, G. Zhang, K. Li, et al., Adv. Mater. 33 (2021) 2104361. doi: 10.1002/adma.202104361
15. [15]
  J. Fu, J. Yu, C. Jiang, B. Cheng, Adv. Energy Mater. 8 (2017) 1701503.
16. [16]
  X.H. Wu, H.Q. Ma, W. Zhong, J.J. Fan, H.G. Yu, Appl. Catal. B: Environ. 271 (2020) 118899. doi: 10.1016/j.apcatb.2020.118899
17. [17]
  L. Lin, Z. Yu, X. Wang, Angew. Chem. Int. Edit. 58 (2019) 6164–6175. doi: 10.1002/anie.201809897
18. [18]
  Y.P. Zhu, Y.J. Lei, F.W. Ming, et al., Nano Energy65 (2019) 104030. doi: 10.1016/j.nanoen.2019.104030
19. [19]
  Y.C. Hu, Y. Shim, J. Oh, et al., Chem. Mater. 29 (2017) 5080–5089. doi: 10.1021/acs.chemmater.7b00069
20. [20]
  Z. Yang, M. Yuan, Z. Cheng, et al., Angew. Chem. Int. Ed. 63 (2024) e202401758. doi: 10.1002/anie.202401758
21. [21]
  G. Zhao, Y.L. Cheng, Y.Z. Wu, X.J. Xu, X.P. Hao, Small. 14 (2018) 1704138. doi: 10.1002/smll.201704138
22. [22]
  T.T. Bartels, The Sadtler Handbook of Infrared Spectra, Sadtler, Philadelphia, 1978.
23. [23]
  P. Xia, B. Zhu, J. Yu, S. Cao, M. Jaroniec, J. Mater. Chem. A5 (2017) 3230–3238. doi: 10.1039/C6TA08310B
24. [24]
  Y.B. Jiang, Z.Z. Sun, C. Tang, et al., Appl. Catal. B: Environ. 240 (2019) 30–38. doi: 10.1145/3373509.3373568
25. [25]
  M.H. Vu, M. Sakar, C.C. Nguyen, T.O. Do, A.C.S. Sustain. Chem. Eng. 6 (2018) 4194–4203. doi: 10.1021/acssuschemeng.7b04598
26. [26]
  M. Groenewolt, M. Antonietti, Adv. Mater. 17 (2005) 1789–1792. doi: 10.1002/adma.200401756
27. [27]
  X. Yu, S.F. Ng, L.K. Putri, et al., Small. 17 (2021) 2006851. doi: 10.1002/smll.202006851
28. [28]
  X. Chen, R. Shi, Q. Chen, et al., Nano Energy59 (2019) 644–650. doi: 10.1016/j.nanoen.2019.03.010
29. [29]
  S. Mondal, L. Sahoo, Y. Vaishnav, et al., J. Mater. Chem. A8 (2020) 20581–20592. doi: 10.1039/d0ta08001b
30. [30]
  L. Liang, L. Shi, F. Wang, et al., Appl. Catal. A599 (2020) 117618. doi: 10.1016/j.apcata.2020.117618
31. [31]
  Q. Han, B. Wang, Y. Zhao, C.G. Hu, L.T. Qu, Angew. Chem. Int. Ed. 54 (2015) 11433–11437. doi: 10.1002/anie.201504985
32. [32]
  Y. Liang, X. Wu, X. Liu, C. Li, S. Liu, Appl. Catal. B: Environ. 304 (2022) 120978. doi: 10.1016/j.apcatb.2021.120978
33. [33]
  S. Gao, X. Wang, C. Song, et al., Appl. Catal. B: Environ. 295 (2021) 120272. doi: 10.1016/j.apcatb.2021.120272
34. [34]
  B. Yang, J. Han, Q. Zhang, et al., Carbon. N. Y. 202 (2023) 348–357. doi: 10.1016/j.carbon.2022.10.074
35. [35]
  Y. Li, M. Zhou, B. Cheng, Y. Shao, J. Mater. Sci. Technol. 56 (2020) 1–17. doi: 10.1016/j.jmst.2020.04.028
36. [36]
  Y. Mun, M.J. Kim, S.A. Park, et al., Appl. Catal. B: Environ. 222 (2018) 191–199. doi: 10.1016/j.apcatb.2017.10.015
37. [37]
  D. Gu, C.J. Jia, C. Weidenthaler, et al., J. Am. Chem. Soc. 137 (2015) 11407–11418. doi: 10.1021/jacs.5b06336
38. [38]
  M.A. Isaacs, N. Robinson, B. Barbero, et al., J. Mater. Chem. A7 (2019) 11814–11825. doi: 10.1039/c9ta01867k
39. [39]
  Y. Wei, N. Yang, K. Huang, et al., Adv. Mater. 32 (2020) 2002556. doi: 10.1002/adma.202002556
40. [40]
  Y. Chen, M. Cheng, C. Lai, et al., Small. 19 (2023) 2205902. doi: 10.1002/smll.202205902
41. [41]
  P. Shoghi, M. Hamzehloo, J. Colloid Interf. Sci. 616 (2022) 453–464. doi: 10.1016/j.jcis.2022.02.028
42. [42]
  T.K.A. Nguyen, T. Trần-Phú, X.M.C. Ta, et al., Small Methods8 (2024) 2300427. doi: 10.1002/smtd.202300427
43. [43]
  L. Zhu, H. Li, Q. Xu, D. Xiong, P. Xia, J. Colloid Interf. Sci. 564 (2020) 303–312. doi: 10.1016/j.jcis.2019.12.088
44. [44]
  C. Han, P. Su, B. Tan, et al., J. Colloid Interf. Sci. 581 (2021) 159–166. doi: 10.1016/j.jcis.2020.07.119
45. [45]
  Q. Xu, B. Zhu, B. Cheng, et al., Appl. Catal. B: Environ. 255 (2019) 117770. doi: 10.1016/j.apcatb.2019.117770
46. [46]
  S. Zhou, L. Jiang, H. Wang, et al., Adv. Funct. Mater. 33 (2023) 2307702. doi: 10.1002/adfm.202307702
47. [47]
  T. Tang, Z. Wang, J. Guan, Chin. J. Catal. 43 (2022) 636–678. doi: 10.1016/S1872-2067(21)63945-1
48. [48]
  I.T. McCrum, M.T. Koper, Nat. Energy5 (2020) 891–899. doi: 10.1038/s41560-020-00710-8
49. [49]
  W. Zhong, B. Xiao, Z. Lin, et al., Adv. Mater. 33 (2021) 2007894. doi: 10.1002/adma.202007894
1. [1]
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2. [2]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
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4. [4]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
5. [5]
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6. [6]
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7. [7]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
8. [8]
  Yanghanbin Zhang , Dongxiao Wen , Wei Sun , Jiahe Peng , Dezhong Yu , Xin Li , Yang Qu , Jizhou Jiang . State-of-the-art evolution of g-C3N4-based photocatalytic applications: A critical review. Chinese Journal of Structural Chemistry, 2024, 43(12): 100469-100469. doi: 10.1016/j.cjsc.2024.100469
9. [9]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
10. [10]
  Jiaming Li , Na Xu , Yafei Zhang , Hongjun Dong , Chunmei Li . Research progress of heterogeneous photocatalyst for H₂O₂ production: A mini review. Chinese Chemical Letters, 2025, 36(11): 110470-. doi: 10.1016/j.cclet.2024.110470
11. [11]
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12. [12]
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13. [13]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
14. [14]
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沈阳化工大学材料科学与工程学院沈阳 110142

Assembling 3D cross-linked network by carbon nitride nanowires for visible-light photocatalytic H2 evolution from dyestuffs wastewater

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通讯作者: 陈斌, bchen63@163.com

Assembling 3D cross-linked network by carbon nitride nanowires for visible-light photocatalytic H₂ evolution from dyestuffs wastewater