Citation: Zhen Kong, Chaoyang Sun, Mingyuan Pang, Wei Liu, Haohao Zhang, Min Yang, Jiajia Ye, Juan An, Yijie Wang, Yen Leng Pak, Xing Gao, Jibin Song. Phosphorus modification-induced dense crystalline-amorphous heterostructured P-Sn₆O₄(OH)₄@RGO for high-rate and ultra-stable lithium storage[J]. Chinese Chemical Letters, ;2026, 37(1): 111082. doi: 10.1016/j.cclet.2025.111082 shu

Phosphorus modification-induced dense crystalline-amorphous heterostructured P-Sn₆O₄(OH)₄@RGO for high-rate and ultra-stable lithium storage

Zhen Kong ^a ,
Chaoyang Sun ^a ,
Mingyuan Pang ^a ,
Wei Liu ^a ,
Haohao Zhang ^{a, *,} ,
Min Yang ^a ,
Jiajia Ye ^a ,
Juan An ^{a, *,} ,
Yijie Wang ^b ,
Yen Leng Pak ^a ,
Xing Gao ^a ,
Jibin Song ^{c, d, *,}

a.
College of Biological and Chemical Engineering, Qilu Institute of Technology, Ji'nan 250200, China
b.
College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China
c.
State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
d.
Handan Kaipu Xin Technology Co., Ltd., Handan 075570, China

haonier2@163.com

angelanjuan@163.com

chem64@163.com

Received Date: 8 January 2025
Revised Date: 5 March 2025
Accepted Date: 12 March 2025
Available Online: 17 March 2025

Figures(7)

The large volume expansion and rapid capacity attenuation of tin-based electrodes are the main factors limiting their commercial application. The reasonable design of electrode material structure is particularly important for improving its electrochemical performance. Herein, phosphorus-modified graphene encapsulated Sn₆O₄(OH)₄ nanoparticles composite (P-Sn₆O₄(OH)₄@RGO) with crystalline-amorphous heterostructure has been successfully designed and prepared. The design of crystalline-amorphous structure has largely enhanced the active sites, and the construction of a graphene encapsulation structure has greatly alleviated volume expansion. Notably, P-Sn₆O₄(OH)₄@RGO obtained an excellent high-rate long-term cycling performance for lithium-ion batteries anode, reaching a high specific capacity of 970 mAh/g at 1.0 A/g after 1450 cycles. This work demonstrates that restructuring the electrode material's structure and phase through phosphorus modification can effectively improve the electrochemical performance of tin-based electrode materials.
- Phosphorus modification,
- P-Sn₆O₄(OH)₄@RGO,
- Crystalline-amorphous heterostructure,
- Graphene encapsulation structure,
- Lithium-ion batteries
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Phosphorus modification-induced dense crystalline-amorphous heterostructured P-Sn6O4(OH)4@RGO for high-rate and ultra-stable lithium storage

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通讯作者: 陈斌, bchen63@163.com

Phosphorus modification-induced dense crystalline-amorphous heterostructured P-Sn₆O₄(OH)₄@RGO for high-rate and ultra-stable lithium storage