Citation: Ning Liu, Man Tian, Ye Zhang, Jinming Yang, Zhihao Wang, Wangxi Dai, Guixiang Quan, Jianqiu Lei, Xiaodong Zhang, Liang Tang. Three-dimensional MIL-88A(Fe)-derived α-Fe₂O₃ and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin[J]. Chinese Chemical Letters, ;2025, 36(12): 111063. doi: 10.1016/j.cclet.2025.111063 shu

Three-dimensional MIL-88A(Fe)-derived α-Fe₂O₃ and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin

Ning Liu ^a ,
Man Tian ^a ,
Ye Zhang ^a ,
Jinming Yang ^a ,
Zhihao Wang ^a ,
Wangxi Dai ^a ,
Guixiang Quan ^d ,
Jianqiu Lei ^c ,
Xiaodong Zhang ^{a, *,} ,
Liang Tang ^{b, *,}

a.
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
Key Laboratory of Organic Compound Pollution Control Engineering (MOE), School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
c.
Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
d.
School of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

fatzhxd@126.com

tang1liang@shu.edu.cn

Received Date: 20 November 2024
Revised Date: 2 February 2025
Accepted Date: 10 March 2025
Available Online: 10 March 2025

Figures(5)

The photo-assisted Fenton-like method is an effective and sustainable way to remove organic pollutants from water. Herein, a series of three-dimensional composites containing MIL-88A(Fe)-derived α-Fe₂O₃ and graphene aerogel (GA-Fe-X) were designed and used as catalysts to degrade ciprofloxacin (CIP) by peroxymonosulfate (PMS) activated photo-Fenton-like technology. The as-prepared GA-Fe-1 displayed remarkable enhancement with a CIP degradation rate constant (0.017 min⁻¹) higher than that of graphene aerogel (0.0031 min⁻¹) and MIL-88A(Fe) (0.0039 min⁻¹). Experimental results demonstrated that the combination of MIL-88A(Fe)-derived α-Fe₂O₃ and graphene aerogel forming GA-Fe-X enhanced the separation efficiency of electron-hole pairs, activating PMS to produce SO₄^•−, ^•OH and ¹O₂ for enhanced CIP degradation through radical and non-radical pathways. The factors affecting CIP degradation during the photo-Fenton-like process were thoroughly investigated. The possible CIP degradation pathways and ecotoxicity of the intermediates were also analyzed. This work enhances our understanding of the photo-Fenton-like effect in three-dimensional graphene aerogel composites.
- Photo-Fenton-like,
- Peroxymonosulfate activation,
- Graphene aerogel,
- MIL-88A(Fe)-derived α-Fe₂O₃,
- Ciprofloxacin
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Three-dimensional MIL-88A(Fe)-derived α-Fe2O3 and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin

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通讯作者: 陈斌, bchen63@163.com

Three-dimensional MIL-88A(Fe)-derived α-Fe₂O₃ and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin