Citation: Xue-Na Tang, Qingshun Fan, Guang-Ning Liu, Cuncheng Li, Zhihua Sun. Exceptional one-dimensional hybrid lead halide for high-performance X-ray detection through hydrogen bond enhanced charge transport[J]. Chinese Chemical Letters, ;2026, 37(6): 111036. doi: 10.1016/j.cclet.2025.111036 shu

Exceptional one-dimensional hybrid lead halide for high-performance X-ray detection through hydrogen bond enhanced charge transport

Xue-Na Tang ^{a, 1} ,
Qingshun Fan ^{b, 1} ,
Guang-Ning Liu ^{a, *,} ,
Cuncheng Li ^a ,
Zhihua Sun ^{b, *,}

a.
Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Ji'nan 250022, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

chm_liugn@ujn.edu.cn

sunzhihua@fjirsm.ac.cn

Received Date: 15 January 2025
Revised Date: 23 February 2025
Accepted Date: 5 March 2025
Available Online: 5 March 2025

Figures(5)

The immense potential of one-dimensional (1D) hybrid lead halide perovskites (HLHPs) in single crystal X-ray detection is hindered by their relatively low charge transport abilities and needle-like morphology. Alloying mixed cations in 1D HLHP is expected to realize superior charge mobility and large single crystals. Herein, we report a 1D HLHP of (ATZ)(EA)₄Pb₃I₁₁ (1) with thiazol-2-aminium (ATZ)⁺ and ethanaminium (EA)⁺ as the mixed cations, demonstrating an exceptional 1D HLHP for high-performance X-ray detector. The H···I hydrogen bonds with a fraction of 69.7% are stronger than those in 1D HLHPs containing solely (ATZ)⁺ or (EA)⁺ cations. The single crystal of 1 posesses remarkable semiconducting properties, including a high resistivity (1.94 × 10¹¹ Ω cm) and a large mobility-lifetime product (2.22 × 10⁻⁴ cm²/V), which contribute to the outstanding X-ray detection, manifested by a high sensitivity of 1356 µC Gy_air⁻¹ cm⁻² and an ultra-low dark current drift of 5.01 × 10⁻⁸ nA cm⁻¹ s⁻¹ V⁻¹.
- Lead halide,
- Inorganic–organic hybrid,
- Hydrogen bonds,
- Mixed cation,
- X-ray detection
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