Citation: Haiying Zhou, Jian Wen, Guanghui Wu, Pinghua Chen, Qi Ke, Yonghui Deng, Xibao Li, Xinming Zhou, Shaoning Yu, Hualin Jiang. Rational construction of hollow NiCoCd-S nanoprisms for high-performance supercapacitor[J]. Chinese Chemical Letters, ;2026, 37(5): 110954. doi: 10.1016/j.cclet.2025.110954 shu

Rational construction of hollow NiCoCd-S nanoprisms for high-performance supercapacitor

Haiying Zhou ^{a, c, d} ,
Jian Wen ^b ,
Guanghui Wu ^{a, c, d} ,
Pinghua Chen ^{a, c, d, *,} ,
Qi Ke ^{a, c, d} ,
Yonghui Deng ^{a, e} ,
Xibao Li ^a ,
Xinming Zhou ^{a, c, d} ,
Shaoning Yu ^{a, c, d} ,
Hualin Jiang ^{a, c, d, *,}

a.
Nanchang Hangkong University, Nanchang 330063, China
b.
Jiangxi Institute of Fashion Technology, Nanchang 330201, China
c.
Key Laboratory of Jiangxi Province for Persistent Pollutants Prevention Control and Resource Reuse, Nanchang 330063, China
d.
National-local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization, Nanchang 330063, China
e.
Department of Chemistry, Fudan University, Shanghai 200433, China

cph1979@126.com

hua20022000@126.com

Received Date: 22 November 2024
Revised Date: 19 January 2025
Accepted Date: 12 February 2025
Available Online: 13 February 2025

Figures(6)

High-performance electrode materials are of paramount significance for practical applications in energy storage devices, and the design of hollow-structured active electrode materials is a simple effective strategy. Herin, a three-dimensional nickel cobalt cadmium ternary sulfide hollow nanoprism material (NiCoCd-S) was successfully synthesized by combination of refluxing, hydrothermal and calcination methods. The co-existence and synergism of Ni, Co and Cd endow the material surface with abundant catalytic active sites, facilitating the progress of the reaction, enabling it to exhibit better performance than single-metal or bimetallic compounds. The unique hollow structure facilitates increased contact between the electrolyte and more electroactive sites, while the shorter diffusion pathways enable rapid ion/electron transfer rates within the material, synergistically generating enhanced supercapacitive activity. The synthesized NiCoCd-S shows a high specific capacitance (C_g) of 1643.7 F/g@1 A/g, along with a prolonged cycling life (81.6% capacitance retention after 10,000 cycles). When assembling the NiCoCd-S//AC asymmetric supercapacitor, it demonstrates an impressive energy/power density of 105.9 Wh/kg and 919.2 W/kg, respectively. After 10,000 charging-discharging cycles, the initial capacitance can still be maintained at 88.5%. The present work offers a strategy for the rational design of hollow nanostructured polymetallic sulfides with high electrochemical performance and stability.
- Ni-Co-Cd trimetallic sulfide,
- Hollow,
- Nanomaterial,
- Supercapacitor,
- Electrocatalysis
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