Citation: Xifeng Lu, Pei Su. Design and application of metal-organic frameworks derivatives as 3-electron ORR electrocatalysts for ^•OH generation in wastewater treatment: A review[J]. Chinese Chemical Letters, ;2025, 36(11): 110909. doi: 10.1016/j.cclet.2025.110909 shu

Design and application of metal-organic frameworks derivatives as 3-electron ORR electrocatalysts for ^•OH generation in wastewater treatment: A review

Xifeng Lu ,
Pei Su ^*,

Hebei Key Laboratory of Applied Chemistry and Hebei Key Laboratory of Heavy Metal Deep−Remediation in Water and Resource Reuse, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China

sup@ysu.edu.cn

Received Date: 16 October 2024
Revised Date: 20 November 2024
Accepted Date: 3 February 2025
Available Online: 4 February 2025

Figures(6)

Derivatives of metal−organic frameworks (MOFs) are a promising bifunctional electrocatalysts in electrochemical advanced oxidation processes (EAOPs). These metal/carbon materials overcome the limitations of individual components by creating synergistic effects. EAOPs is primarily constrained by the generation and activation of H₂O₂. This article examines the regulatory strategies employed in MOFs derivatives to enhance the production of H₂O₂ via 2e⁻ pathways and its activation to ^•OH, focusing on preparation techniques, structures, and compositions. The design of these derivatives involves methods such as metal dispersion on the surface of nanocarbons, embedding in carbon shells, and atomic dispersion of metals anchored in porous carbon. MOFs derivatives promote ^•OH production and enhance wastewater purification through mechanisms such as boosting the Fe(Ⅱ)/Fe(Ⅲ) cycle, facilitating direct 3e⁻ reactions of O₂, and interacting of O₂^•−. Moreover, the performance and durability of MOFs derivatives in wastewater treatment, particularly in influencing ^•OH generation within EAOPs, were investigated. This review addresses current challenges and future prospects, offering valuable insights for the development of MOFs derivatives as 3e⁻ ORR electrocatalysts and the advancement of sustainable water treatment technologies.
- Metal−organic frameworks,
- Derivatives,
- 3-Electron ORR,
- Hydroxyl radicals,
- Water purification
1. [1]
  C.L.S. Vilela, J.P. Bassin, R.S. Peixoto, Environ. Pollut. 235 (2018) 546–559. doi: 10.1016/j.envpol.2017.12.098
2. [2]
  F. Huang, Z. An, M.J. Moran, et al., J. Hazard. Mater. 399 (2020) 122813. doi: 10.1016/j.jhazmat.2020.122813
3. [3]
  T. Wang, J. He, J. Lu, et al., Chin. Chem. Lett. 33 (2022) 3585–3593. doi: 10.1016/j.cclet.2021.09.029
4. [4]
  Y. Zhang, X. Zhang, S. Wang, Sci. Total Environ. 883 (2023) 163702. doi: 10.1016/j.scitotenv.2023.163702
5. [5]
  X. Du, S. Wang, F. Ye, et al., Environ. Res. 206 (2022) 112414. doi: 10.1016/j.envres.2021.112414
6. [6]
  W. Xiong, G. Zeng, Z. Yang, et al., Sci. Total Environ. 627 (2018) 235–244. doi: 10.1016/j.scitotenv.2018.01.249
7. [7]
  C. Zhang, C. Lai, G. Zeng, et al., Water Res. 95 (2016) 103–112. doi: 10.1016/j.watres.2016.03.014
8. [8]
  J. Li, Y. Li, Z. Xiong, et al., Chin. Chem. Lett. 30 (2019) 2139–2146. doi: 10.1016/j.cclet.2019.04.057
9. [9]
  Z. Wang, M. Liu, F. Xiao, et al., Chin. Chem. Lett. 33 (2022) 653–662. doi: 10.3390/machines10080653
10. [10]
  P. Su, M. Zhou, G. Ren, et al., J. Mater. Chem. A 7 (2019) 24408–24419. doi: 10.1039/c9ta07491k
11. [11]
  H. Zhao, L. Qian, X. Guan, et al., Environ. Sci. Technol. 50 (2016) 5225–5233. doi: 10.1021/acs.est.6b00265
12. [12]
  M.H. Zhang, H. Dong, L. Zhao, et al., Sci. Total Environ. 670 (2019) 110–121. doi: 10.1016/j.scitotenv.2019.03.180
13. [13]
  Z. Yang, J. Qian, A. Yu, et al., Proc. Natl. Acad. Sci. U. S. A. 116 (2019) 6659–6664. doi: 10.1073/pnas.1819382116
14. [14]
  J. Xu, X. Zheng, Z. Feng, Nat. Sustain. 4 (2021) 233–241. doi: 10.54691/bcpbm.v13i.88
15. [15]
  M. Xing, W. Xu, C. Dong, et al., Chem 4 (2018) 1359–1372. doi: 10.1016/j.chempr.2018.03.002
16. [16]
  X. Du, W. Fu, P. Su, et al., Chem. Eng. J. 398 (2020) 125681. doi: 10.1016/j.cej.2020.125681
17. [17]
  J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38 (2009) 1477–1504. doi: 10.1039/b802426j
18. [18]
  X. Li, W. Guo, Z. Liu, et al., Appl. Surf. Sci. 369 (2016) 130–136. doi: 10.1016/j.apsusc.2016.02.037
19. [19]
  M. Zhao, Y. Huang, Y. Peng, et al., Chem. Soc. Rev. 47 (2018) 6267–6295. doi: 10.1039/c8cs00268a
20. [20]
  X. Zhang, X. Lv, X. Shi, et al., J Colloid Interf. Sci. 539 (2019) 152–160. doi: 10.1016/j.jcis.2018.12.056
21. [21]
  Y. Wei, X. Zhang, Z. Wang, et al., Chin. Chem. Lett. 32 (2021) 119–124. doi: 10.1016/j.cclet.2020.10.046
22. [22]
  Y. Liu, H. Cheng, M. Cheng, et al., Chem. Eng. J. 417 (2021) 127914. doi: 10.1016/j.cej.2020.127914
23. [23]
  Y. He, Z. Wang, H. Wang, et al., Coordin. Chem. Rev. 429 (2021) 213618. doi: 10.1016/j.ccr.2020.213618
24. [24]
  H. Fu, C.-C. Wang, W. Liu, Chin. Chem. Lett. 33 (2022) 1647–1649. doi: 10.1016/j.cclet.2021.08.065
25. [25]
  J. Wang, H. Li, P. Xia, et al., Chem. Eng. J. 483 (2024) 149230. doi: 10.1016/j.cej.2024.149230
26. [26]
  Z. Ye, G.E.M. Schukraft, A. L'Hermitte, et al., Water Res. 184 (2020) 115986. doi: 10.1016/j.watres.2020.115986
27. [27]
  F. Wang, Y. Gao, S.-S. Liu, et al., Chem. Eng. J. 463 (2023) 142466. doi: 10.1016/j.cej.2023.142466
28. [28]
  F.X. Wang, Z.C. Zhang, C.C. Wang, et al., Chem. Eng. J. 459 (2023) 141538. doi: 10.1016/j.cej.2023.141538
29. [29]
  S. Lu, L. Liu, H. Demissie, et al., Environ. Int. 146 (2021) 106273. doi: 10.1016/j.envint.2020.106273
30. [30]
  W. Xue, Q. Zhou, X. Cui, et al., Nano Energy 86 (2021) 106073. doi: 10.1016/j.nanoen.2021.106073
31. [31]
  K. Dhanabalan, M. Perumalsamy, G. Sriram, et al., Energies 16 (2023) 4950. doi: 10.3390/en16134950
32. [32]
  X.C. Zhang, C.Q. Zhang, C.Z. Yu, et al., Mater. Chem. Fron. 8 (2024) 1084–1100. doi: 10.1039/d3qm00972f
33. [33]
  L. Qu, Y. Liu, J.B. Baek, et al., ACS Nano 4 (2010) 1321–1326. doi: 10.1021/nn901850u
34. [34]
  C. Zhu, H. Li, S. Fu, Chem. Soc. Rev. 45 (2016) 517–531. doi: 10.1039/C5CS00670H
35. [35]
  C.-H. Hsu, S.G. Cloutier, S. Palefsky, Nano Lett. 10 (2010) 3272–3276. doi: 10.1021/nl100616x
36. [36]
  Y. Liu, X. Quan, X. Fan, et al., Angew. Chem. Int. Ed. 54 (2015) 6837–6841. doi: 10.1002/anie.201502396
37. [37]
  G. Zhong, H. Wang, H. Yu, et al., Electrochem. Commun. 40 (2014) 5–8. doi: 10.1016/j.elecom.2013.12.017
38. [38]
  X. Yan, Y. Yao, Y. Chen, Nanoscale Res. Lett. 13 (2018) 218. doi: 10.1186/s11671-018-2635-x
39. [39]
  W. Zhang, X. Yao, S. Zhou, et al., Small 14 (2018) 1800423. doi: 10.1002/smll.201800423
40. [40]
  Y. Zheng, S.Z. Qiao, Natl. Sci. Rev. 5 (2018) 626–627. doi: 10.1093/nsr/nwy010
41. [41]
  G. Song, H. Wu, J. Jing, et al., Environ. Sci. Technol. 57 (2023) 14482–14492. doi: 10.1021/acs.est.3c06021
42. [42]
  N. Wang, X. Zhao, R. Zhang, et al., ACS Catal. 12 (2022) 4156–4164. doi: 10.1021/acscatal.1c05633
43. [43]
  X. Shen, F. Xiao, H. Zhao, et al., Environ. Sci. Technol. 54 (2020) 4564–4572. doi: 10.1021/acs.est.9b05896
44. [44]
  Y. Sun, L. Silvioli, N.R. Sahraie, et al., J. Am. Chem. Soc. 141 (2019) 12372–12381. doi: 10.1021/jacs.9b05576
45. [45]
  W. Liu, C. Zhang, J. Zhang, et al., Appl. Catal. B: Environ. 310 (2022) 121312. doi: 10.1016/j.apcatb.2022.121312
46. [46]
  X. Lu, P. Su, G. Song, et al., Chem. Eng. J. 488 (2024) 150967. doi: 10.1016/j.cej.2024.150967
47. [47]
  W. Liu, J. Feng, R. Yin, et al., Chem. Eng. J. 430 (2022) 132990. doi: 10.1016/j.cej.2021.132990
48. [48]
  K. Liu, M. Yu, H. Wang, et al., Environ. Sci. Technol. 53 (2019) 6474–6482. doi: 10.1021/acs.est.9b01143
49. [49]
  P. Cao, X. Quan, K. Zhao, et al., Environ. Sci. Technol. 54 (2020) 12662–12672. doi: 10.1021/acs.est.0c03614
50. [50]
  S. Qiu, Y. Wang, J. Wan, et al., Chemosphere 273 (2021) 130269. doi: 10.1016/j.chemosphere.2021.130269
51. [51]
  X. Zhou, D. Xu, Y. Chen, et al., Chem. Eng. J. 384 (2020) 123324. doi: 10.1016/j.cej.2019.123324
52. [52]
  C. Sun, J. Wang, C. Gu, et al., Chem. Eng. J. 452 (2023) 139592. doi: 10.1016/j.cej.2022.139592
53. [53]
  Y. Du, Z. Li, R. Feng, et al., J. Environ. Chem. Eng. 12 (2024) 112324. doi: 10.1016/j.jece.2024.112324
54. [54]
  P. Su, X. Du, Y. Zheng, et al., Chem. Eng. J. 433 (2022) 133597. doi: 10.1016/j.cej.2021.133597
55. [55]
  S. Cheng, Y. Liu, H. Zheng, et al., Sep. Purif. Technol. 325 (2023) 124545. doi: 10.1016/j.seppur.2023.124545
56. [56]
  X. Zhang, X. Zhang, G. Song, et al., J. Environ. Chem. Eng. 12 (2024) 112587. doi: 10.1016/j.jece.2024.112587
57. [57]
  C. Xue, H. Wang, H. Liu, et al., J. Clean. Prod. 448 (2024) 141550. doi: 10.1016/j.jclepro.2024.141550
58. [58]
  P. Su, W. Fu, Z. Hu, et al., Appl. Catal. B: Environ. 313 (2022) 121457. doi: 10.1016/j.apcatb.2022.121457
59. [59]
  S. Cheng, C. Shen, H. Zheng, et al., Appl. Catal. B: Environ. 269 (2020) 118785. doi: 10.1016/j.apcatb.2020.118785
60. [60]
  L. Wang, C. Tang, P. Huang, et al., J. Alloy. Compd. 945 (2023) 169263. doi: 10.1016/j.jallcom.2023.169263
61. [61]
  X. Ma, Z. Xu, L. Zhang, et al., Chem. Eng. J. 475 (2023) 146049. doi: 10.1016/j.cej.2023.146049
62. [62]
  L. He, F. Weniger, H. Neumann, et al., Angew. Chem. Int. Ed. 55 (2016) 12582–12594. doi: 10.1002/anie.201603198
63. [63]
  P. Cao, K. Zhao, X. Quan, et al., Sep. Purifi. Technol. 238 (2020) 116424. doi: 10.1016/j.seppur.2019.116424
64. [64]
  H. Wang, C. Tang, L. Wang, et al., Appl. Catal. B: Environ. 333 (2023) 122755. doi: 10.1016/j.apcatb.2023.122755
65. [65]
  J. Xiao, J. Chen, Z. Ou, et al., Chinese J. Catal. 42 (2021) 953–962. doi: 10.1016/S1872-2067(20)63719-6
66. [66]
  W. Wang, Q. Jia, S. Mukerjee, et al., ACS Catal. 9 (2019) 10126–10141. doi: 10.1021/acscatal.9b02583
67. [67]
  J. Weiss, H. Zhang, P. Zelenay, et al., J. Electroanal. Chem. 875 (2020) 114696. doi: 10.1016/j.jelechem.2020.114696
68. [68]
  S. Huang, Y. Wang, S. Qiu, et al., Appl. Surf. Sci. 586 (2022) 152804. doi: 10.1016/j.apsusc.2022.152804
69. [69]
  A. Fu, Z. Liu, Z. Sun, Chemosphere 297 (2022) 134257. doi: 10.1016/j.chemosphere.2022.134257
70. [70]
  Z. Ye, J.A. Padilla, E. Xuriguera, et al., Appl. Catal. B: Environ. 266 (2020) 118604. doi: 10.1016/j.apcatb.2020.118604
71. [71]
  K. Liu, J.C.C. Yu, H. Dong, et al., Environ. Sci. Technol. 52 (2018) 12667–12674. doi: 10.1021/acs.est.8b03916
72. [72]
  M.I. Gonzalez, A.B. Turkiewicz, L.E. Darago, et al., Nature 577 (2020) 64–68. doi: 10.1038/s41586-019-1776-0
73. [73]
  L. Zhou, X. Wang, H.J. Shin, et al., J. Am. Chem. Soc. 142 (2020) 5583–5593. doi: 10.1021/jacs.9b11303
74. [74]
  P. Cao, X. Quan, K. Zhao, et al., J. Hazard. Mater. 382 (2020) 121102. doi: 10.1016/j.jhazmat.2019.121102
75. [75]
  J. Meng, C. Niu, L. Xu, et al., J. Am. Chem. Soc. 139 (2017) 8212–8221. doi: 10.1021/jacs.7b01942
76. [76]
  J. Yu, G. Li, H. Liu, et al., Int. J. Hydrogen Energy 43 (2018) 12110–12118. doi: 10.1016/j.ijhydene.2018.04.210
77. [77]
  F. Xiao, Z. Wang, J. Fan, et al., Angew. Chem. Int. Ed. 60 (2021) 10375–10383. doi: 10.1002/anie.202101804
78. [78]
  Y. Wang, G. Zhao, S. Chai, et al., ACS Appl. Mater. Interfaces 5 (2013) 842–852. doi: 10.1021/am302437a
79. [79]
  Y. Chen, S. Ji, C. Chen, et al., Joule 2 (2018) 1242–1264. doi: 10.1016/j.joule.2018.06.019
80. [80]
  R. Ren, X. Shang, Z. Song, et al., Chem. Eng. J. 474 (2023) 145545. doi: 10.1016/j.cej.2023.145545
81. [81]
  K. Jiang, S. Back, A.J. Akey, et al., Nat. Commun. 10 (2019) 3997. doi: 10.1038/s41467-019-11992-2
82. [82]
  C.H. Choi, M. Kim, H.C. Kwon, et al., Nat. Commun. 7 (2016) 10922. doi: 10.1038/ncomms10922
83. [83]
  E. Jung, H. Shin, B.-H. Lee, et al., Nat. Mater. 19 (2020) 436–442. doi: 10.1038/s41563-019-0571-5
84. [84]
  C. Wan, X. Duan, Y. Huang, Adv. Energy Mater. 10 (2020) 1903815. doi: 10.1002/aenm.201903815
85. [85]
  C. Tang, Y. Jiao, B. Shi, et al., Angew. Chem. Int. Ed. 59 (2020) 9171–9176. doi: 10.1002/anie.202003842
86. [86]
  T. Sun, S. Mitchell, J. Li, et al., Adv. Mater. 33 (2021) 2003075. doi: 10.1002/adma.202003075
87. [87]
  F.M. Ali, A. Gouda, P.N. Duchesne, et al., Chem Catal. 4 (2024) 100983.
88. [88]
  D. Zhang, Q. Yin, L. Li, et al., Inorg. Chem. Commun. 108 (2019) 107503. doi: 10.1016/j.inoche.2019.107503
89. [89]
  J. Low, B. Dai, T. Tong, et al., Adv. Mater. 31 (2019) 1802981. doi: 10.1002/adma.201802981
90. [90]
  J. Wei, D. Xia, Y. Wei, ACS Catal. 12 (2022) 7811–7820. doi: 10.1021/acscatal.2c00771
91. [91]
  C. Tang, L. Chen, H. Li, et al., J. Am. Chem. Soc. 143 (2021) 7819–7827. doi: 10.1021/jacs.1c03135
92. [92]
  C. Wang, J. Kim, J. Tang, et al., Chem 6 (2020) 19–40. doi: 10.1016/j.chempr.2019.09.005
93. [93]
  C. Li, Q. Li, Y.V. Kaneti, et al., Chem. Soc. Rev. 49 (2020) 4681–4736. doi: 10.1039/d0cs00021c
94. [94]
  M. Hao, M. Qiu, H. Yang, et al., Sci. Total Environ. 760 (2021) 143333. doi: 10.1016/j.scitotenv.2020.143333
95. [95]
  J. Li, Z. Ai, L. Zhang, J. Hazard, Mater. 164 (2009) 18–25.
96. [96]
  C. Zhang, M. Zhou, G. Ren, et al., Water Res. 70 (2015) 414–424. doi: 10.1016/j.watres.2014.12.022
97. [97]
  K. Gong, F. Du, Z. Xia, et al., Science 323 (2009) 760–764. doi: 10.1126/science.1168049
98. [98]
  J.Y. Lu, Y.R. Yuan, X. Hu, et al., Ind. Eng. Chem. Res. 59 (2020) 1800–1808. doi: 10.1021/acs.iecr.9b04428
99. [99]
  A. Byeon, J. Cho, J.M. Kim, et al., Nanoscale Horiz. 5 (2020) 832–838. doi: 10.1039/c9nh00783k
100. [100]
  H.C. Huang, I. Shown, S.T. Chang, et al., Adv. Funct. Mater. 22 (2012) 3500–3508. doi: 10.1002/adfm.201200264
101. [101]
  X. Du, W. Fu, P. Su, et al., ACS EST Engg. 1 (2021) 1311–1322. doi: 10.1021/acsestengg.1c00131
102. [102]
  M. Yu, H. Dong, Y. Zheng, et al., Sci. Total Environ. 818 (2022) 151747. doi: 10.1016/j.scitotenv.2021.151747
103. [103]
  Y. Zhu, R. Zhu, Y. Xi, et al., Appl. Catal. B: Environ. 255 (2019) 117739. doi: 10.1016/j.apcatb.2019.05.041
104. [104]
  S. Xu, H. Zhu, W. Cao, et al., Appl. Catal. B: Environ. 234 (2018) 223–233. doi: 10.1016/j.apcatb.2018.04.029
105. [105]
  X. Li, L. Qin, Y. Zhang, et al., ACS Appl. Mater. Interfaces 11 (2019) 3925–3936. doi: 10.1021/acsami.8b18704
106. [106]
  J. Xie, W. Fu, H. Wu, et al., Chem. Eng. J. 477 (2023) 147004. doi: 10.1016/j.cej.2023.147004
107. [107]
  E. Liu, T. Hu, N.A. Al-Dhabi, et al., Environ. Res. 247 (2024) 118357. doi: 10.1016/j.envres.2024.118357
108. [108]
  W. Yang, M. Zhou, L. Mai, et al., Sci. Total Environ. 791 (2021) 148107. doi: 10.1016/j.scitotenv.2021.148107
109. [109]
  W. Yang, M. Zhou, L. Liang, Chem. Eng. J. 338 (2018) 700–708. doi: 10.1016/j.cej.2018.01.013
110. [110]
  J.M. Burns, W.J. Cooper, J.L. Ferry, Aquat. Sci. 74 (2012) 683–734. doi: 10.1007/s00027-012-0251-x
111. [111]
  X. Mi, J. Han, Y. Sun, et al., J. Hazard. Mater. 367 (2019) 365–374. doi: 10.1016/j.jhazmat.2018.12.074
112. [112]
  P. Su, W. Fu, X. Du, et al., Chem. Eng. J. 452 (2023) 139693. doi: 10.1016/j.cej.2022.139693
113. [113]
  Z. Ye, R. Oriol, C. Yang, et al., Chem. Eng. J. 433 (2022) 133547. doi: 10.1016/j.cej.2021.133547
114. [114]
  Z. Ye, J.A. Padilla, E. Xuriguera, et al., Environ. Sci. Technol. 54 (2020) 4664–4674. doi: 10.1021/acs.est.9b07604
115. [115]
  P. Xia, C. Wang, Q. He, et al., Chem. Eng. J. 452 (2023) 139446. doi: 10.1016/j.cej.2022.139446
116. [116]
  H. Olvera-Vargas, C. Trellu, P.V. Nidheesh, E. Mousset, et al., Water Res. 266 (2024) 122430. doi: 10.1016/j.watres.2024.122430
117. [117]
  S. Cheng, H. Zheng, C. Shen, et al., Adv. Funct. Mater. 31 (2021) 2106311. doi: 10.1002/adfm.202106311
118. [118]
  X. Li, C. Xiao, X. Ruan, et al., Chem. Eng. J. 427 (2022) 130927. doi: 10.1016/j.cej.2021.130927
119. [119]
  S. Zhong, Z.S. Zhu, P. Zhou, et al., ACS Appl. Nano Mater. 5 (2022) 12095–12106. doi: 10.1021/acsanm.2c01413
120. [120]
  X. Sun, H. Qi, Z. Sun, Chemosphere 286 (2022) 131972. doi: 10.1016/j.chemosphere.2021.131972
121. [121]
  B.C. Huang, J. Jiang, W.K. Wang, et al., ACS Sustainable Chem. Eng. 6 (2018) 5540–5546. doi: 10.1021/acssuschemeng.8b00416
122. [122]
  Q. Tian, F. Xiao, H. Zhao, et al., Appl. Catal. B: Environ. 272 (2020) 119039. doi: 10.1016/j.apcatb.2020.119039
123. [123]
  Q. Wang, M. Liu, H. Zhao, et al., Chem. Eng. J. 378 (2019) 122071. doi: 10.1016/j.cej.2019.122071
124. [124]
  S. Mao, X. Sun, H. Qi, et al., Sci. Total Environ. 793 (2021) 148492. doi: 10.1016/j.scitotenv.2021.148492
1. [1]
  Shouchao Zhong , Yue Wang , Mingshu Xie , Yiqian Wu , Jiuqiang Li , Jing Peng , Liyong Yuan , Maolin Zhai , Weiqun Shi . Radiation reduction modification of sp² carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal. Chinese Chemical Letters, 2025, 36(5): 110312-. doi: 10.1016/j.cclet.2024.110312
2. [2]
  Runsheng Xu , Haotian Wu , Daoyuan Zu , Kui Yang , Xiangtong Kong , Jinxing Ma . Porous cathode enables continuous flow anodic oxidation for water purification: Performance and mechanisms. Chinese Chemical Letters, 2025, 36(8): 110517-. doi: 10.1016/j.cclet.2024.110517
3. [3]
  Ruiting Ni , Kwame Nana Opoku , Xingrong Li , Yarao Gao , Yanyun Wang , Fu Yang . Recent advance in utilization of advanced composite photothermal materials for water disinfection: Synthesis, mechanism, and application. Chinese Chemical Letters, 2025, 36(9): 110813-. doi: 10.1016/j.cclet.2024.110813
4. [4]
  Haoyu Luo , Jinsong Chen , Mengfei Luo , Hui Ma , Shengyan Pu . Heterogeneous Fenton catalytic degradation of nitrobenzene by controlled-release nano calcium peroxide. Chinese Chemical Letters, 2025, 36(6): 110367-. doi: 10.1016/j.cclet.2024.110367
5. [5]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
6. [6]
  Jiaxuan YANG , Chenfa DENG , Jingyang LIU , Chenzexi XU , Hongxin CHEN , Yahui ZHU , Ying LI , Shuhua WANG , Rongping ZHOU , Chao CHEN . Advances in selective hydrogenation of α, β-unsaturated aldehydes/ketones catalyzed by metal-organic frameworks and their derivatives: A review. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 1973-2010. doi: 10.11862/CJIC.20250175
7. [7]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
8. [8]
  Minglei Sun , Zhong-Yong Yuan . Valorization strategies for electrodegradation of nitrogenous wastes in sewage. Acta Physico-Chimica Sinica, 2025, 41(9): 100108-0. doi: 10.1016/j.actphy.2025.100108
9. [9]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
10. [10]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
11. [11]
  Jiahao Li , Guinan Chen , Chunhong Chen , Yuanyuan Lou , Zhihao Xing , Tao Zhang , Chengtao Gong , Yongwu Peng . Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification. Chinese Chemical Letters, 2025, 36(1): 109760-. doi: 10.1016/j.cclet.2024.109760
12. [12]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
13. [13]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
14. [14]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
15. [15]
  Rongxin Zhu , Shengsheng Yu , Xuanzong Yang , Ruyu Zhu , Hui Liu , Kaikai Niu , Lingbao Xing . Construction of pyrene-based hydrogen-bonded organic frameworks as photocatalysts for photooxidation of styrene in water. Chinese Chemical Letters, 2024, 35(10): 109539-. doi: 10.1016/j.cclet.2024.109539
16. [16]
  Xiaoru LIU , Jinlian SHI , Yajia ZHENG , Shuangcun MO , Zhongxuan XU . Two Ni-based frameworks with helices and dinuclear units constructed from semi-rigid carboxylic acid and imidazole derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 797-808. doi: 10.11862/CJIC.20240328
17. [17]
  Yu Hong , Yuqian Jiang , Chenhuan Yuan , Decai Wang , Yimeng Sun , Jian Jiang . Unraveling temperature-dependent supramolecular polymorphism of naphthalimide-substituted benzene-1,3,5-tricarboxamide derivatives. Chinese Chemical Letters, 2024, 35(12): 109909-. doi: 10.1016/j.cclet.2024.109909
18. [18]
  Sheng Tang , Mingyue Liao , Weihai Sun , Jihuai Wu , Jiamin Lu , Yiming Xie . Optimizing CsPbBr₃ perovskite solar cell interface and performance through tetraphenylethene derivatives. Chinese Chemical Letters, 2025, 36(6): 110838-. doi: 10.1016/j.cclet.2025.110838
19. [19]
  Ke Wu , Xiuqin Ruan , Shuolei Jia , Enyuan Wang , Qingfa Zhou . DABCO-catalyzed [3+4] annulations of Schiff bases with α-substituted allenes: Construction of functionalized benzazepine derivatives. Chinese Chemical Letters, 2025, 36(7): 110646-. doi: 10.1016/j.cclet.2024.110646
20. [20]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(24)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Design and application of metal-organic frameworks derivatives as 3-electron ORR electrocatalysts for •OH generation in wastewater treatment: A review

Metrics

通讯作者: 陈斌, bchen63@163.com

Design and application of metal-organic frameworks derivatives as 3-electron ORR electrocatalysts for ^•OH generation in wastewater treatment: A review