Citation: Zhi-Long Li, Hao-Fei Ni, Bo Zhuang, Kun Ding, Da-Wei Fu, Qiang Guo, Meng-Meng Lun. Halogen substitution strategy for regulating the photoluminescence and dielectric response of ferroelastics[J]. Chinese Chemical Letters, ;2026, 37(4): 110755. doi: 10.1016/j.cclet.2024.110755 shu

Halogen substitution strategy for regulating the photoluminescence and dielectric response of ferroelastics

Zhi-Long Li ^{a, 1} ,
Hao-Fei Ni ^{b, 1} ,
Bo Zhuang ^{a, 1} ,
Kun Ding ^{a, *,} ,
Da-Wei Fu ^{b, *,} ,
Qiang Guo ^{b, *,} ,
Meng-Meng Lun ^{a, c, *,}

a.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China
b.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321019, China
c.
School of Electronics and Information, Zhengzhou University of Light Industry, Zhengzhou 450000, China

Received Date: 13 November 2024
Revised Date: 6 December 2024
Accepted Date: 11 December 2024
Available Online: 14 December 2024

Figures(6)

Ferroelastics have attracted considerable interest because of their promising uses in areas such as energy conversion, sensing technologies, and beyond. However, exploring ferroelastics with high-temperature dielectric switching and photoluminescence remains a challenge. Here, we have synthesized two ferroelastics (DMTP)PbBr₃ (DMTP = N,N-dimethyl-1,2,3,6-tetrahydropyridine) and (DMTP)PbI₃ under the guidance of halogen substitution strategy. (DMTP)PbI₃ experiences the dielectric switching at 371 K, and upon halogen substitution, the strengthened intermolecular interactions lead to (DMTP)PbBr₃ undergoing a similar switching at around 390 K. Additionally, two compounds both emit orange light under ultraviolet illumination. (DMTP)PbI₃ has the photoluminescence quantum yield of 2.68%, while (DMTP)PbBr₃, due to the increased distortion of the inorganic part after halogen substitution, achieves the higher quantum yield of 12%. This work offers meaningful perspectives on exploring the search for ferroelectrics with photoluminescence and high-temperature dielectric switching, and also demonstrates the rationality of the halogen substitution strategy.
- Ferroleastics,
- Halogen substitution,
- Photoluminescence,
- Dielectric response,
- Organic-inorganic hybrid materials
1. [1]
  F.F. Di, H. Peng, H. Zhang, et al., Mater. Chem. Front. 5 (2021) 2842–2848. doi: 10.1039/d1qm00007a
2. [2]
  D.W. Fu, J.X. Gao, P.Z. Huang, et al., Angew. Chem. Int. Ed. 60 (2021) 8198–8202. doi: 10.1002/anie.202015219
3. [3]
  P.Z. Huang, H.F. Ni, C.Y. Su, et al., CCS Chem. 5 (2023) 1942–1951. doi: 10.31635/ccschem.022.202202332
4. [4]
  Q.Q. Jia, H.F. Lu, J.Q. Luo, et al., Small 20 (2023) 2306989.
5. [5]
  H.F. Ni, J.H. Lin, C.F. Wang, et al., Inorg. Chem. Front. 10 (2023) 7231–7237. doi: 10.1039/d3qi01650a
6. [6]
  S.E. Park, H.T. Jeong, Y.C. Cho, et al., Phase Transit. 70 (2006) 231–242.
7. [7]
  J.L. Schlenker, G.V. Gibbs, M.B. Boisen, Acta. Crystal. A 34 (1978) 52–54. doi: 10.1107/S0567739478000108
8. [8]
  C.Y. Su, M.M. Lun, Y.D. Chen, et al., CCS Chem. 4 (2022) 2009–2019. doi: 10.31635/ccschem.021.202101073
9. [9]
  H. Yan, H. Yang, J. Luo, et al., Chin. Chem. Lett. 32 (2021) 3825–3832. doi: 10.1016/j.cclet.2021.05.017
10. [10]
  W.L. Yang, X. Yan, M. Wang, et al., Inorg. Chem. Front. 11 (2024) 6874–6879. doi: 10.1039/d4qi01780c
11. [11]
  J.T. Mo, Z. Wang, Chin. Chem. Lett. 35 (2024) 109360. doi: 10.1016/j.cclet.2023.109360
12. [12]
  J.C. Qi, Y. Qin, H. Peng, et al., Sci. China. Chem. 67 (2024) 4167–4174. doi: 10.1007/s11426-024-2175-2
13. [13]
  H. Peng, L. Qin, Y.H. Liu, et al., Chin. Chem. Lett. 34 (2023) 107980. doi: 10.1016/j.cclet.2022.107980
14. [14]
  S.Y. Zhang, Z.C. Zhang, T. Zhang, et al., Dalton Trans. 52 (2023) 10415–10422. doi: 10.1039/d3dt01574b
15. [15]
  Q.Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539. doi: 10.1016/j.cclet.2022.05.053
16. [16]
  Z.X. Zhang, C.Y. Su, J. Li, et al., Chem. Mater. 33 (2021) 5790–5799. doi: 10.1021/acs.chemmater.1c01699
17. [17]
  L.L. Chu, T. Zhang, Y.F. Gao, et al., Chem. Mater. 32 (2020) 6968–6974. doi: 10.1021/acs.chemmater.0c02223
18. [18]
  D.W. Fu, J.X. Gao, W.H. He, et al., Angew. Chem. Int. Ed. 59 (2020) 17477–17481. doi: 10.1002/anie.202007660
19. [19]
  J.X. Gao, W.Y. Zhang, Z.G. Wu, et al., J. Am. Chem. Soc. 142 (2020) 4756–4761. doi: 10.1021/jacs.9b13291
20. [20]
  X.J. Song, T. Zhang, Z.X. Gu, et al., J. Am. Chem. Soc. 143 (2021) 5091–5098. doi: 10.1021/jacs.1c00613
21. [21]
  C.Y. Su, Z.X. Zhang, J. Yao, et al., Chin. Chem. Lett. 34 (2023) 107442. doi: 10.1016/j.cclet.2022.04.040
22. [22]
  Y. Wang, T. Zhang, M.M. Lun, et al., Inorg. Chem. Front. 8 (2021) 4230–4238. doi: 10.1039/d1qi00736j
23. [23]
  Y.F. Xie, Y. Ai, Y.L. Zeng, et al., J. Am. Chem. Soc. 142 (2020) 12486–12492. doi: 10.1021/jacs.0c05372
24. [24]
  Y.Y. Zhang, J.Q. Luo, Y. Han, et al., Chin. Chem. Lett. 36 (2024) 109530.
25. [25]
  T. Zhang, J.Y. Li, G.W. Du, et al., Inorg. Chem. Front. 9 (2022) 4341–4349. doi: 10.1039/d2qi00964a
26. [26]
  Y. Zhang, X.J. Song, Z.X. Zhang, et al., Matter 2 (2020) 697–710. doi: 10.1016/j.matt.2019.12.008
27. [27]
  H.Y. Liu, H.Y. Zhang, X.G. Chen, et al., J. Am. Chem. Soc. 142 (2020) 15205–15218. doi: 10.1021/jacs.0c07055
28. [28]
  J.Q. Luo, M.M. Lun, Q.Q. Jia, et al., Chin. J. Chem. 42 (2024) 1706–1712. doi: 10.1002/cjoc.202400076
29. [29]
  B.W. Deng, Z.P. Rao, M.J. Shen, et al., J. Mater. Chem. C 12 (2024) 6098–6105. doi: 10.1039/d4tc00428k
30. [30]
  J.H. Lin, J.R. Lou, L.K. Ye, et al., Inorg. Chem. 62 (2023) 2870–2876. doi: 10.1021/acs.inorgchem.2c04295
31. [31]
  X.T. Sun, H.F. Ni, Y. Zhang, et al., Chin. J. Struc. Chem. 43 (2024) 100212.
32. [32]
  Y.Y. Chen, C.H. Gao, T. Yang, et al., Chin. J. Struc. Chem. 41 (2022) 2204001–2204011.
33. [33]
  K. Ding, H.S. Ye, C.Y. Su, et al., Nat. Commun. 14 (2023) 2863. doi: 10.1038/s41467-023-38590-7
34. [34]
  J.Y. Li, T. Zhang, M.M. Lun, et al., Small 19 (2023) 2301364. doi: 10.1002/smll.202301364
35. [35]
  M.M. Lun, H.F. Ni, Z.X. Zhang, et al., Angew. Chem. Int. Ed. 63 (2024) e202313590. doi: 10.1002/anie.202313590
36. [36]
  M.M. Lun, C.Y. Su, J. Li, et al., Small 19 (2023) 2303127. doi: 10.1002/smll.202303127
37. [37]
  M.M. Lun, J.Q. Luo, Z.X. Zhang, et al., Chem. Eng. J. 475 (2023) 145969. doi: 10.1016/j.cej.2023.145969
38. [38]
  M.M. Lun, C.Y. Su, Q.Q. Jia, et al., Inorg. Chem. Front. 10 (2023) 5026–5034. doi: 10.1039/d3qi01037f
39. [39]
  J.Q. Luo, Q.Q. Jia, G. Teri, et al., ACS Mater. Lett. 6 (2023) 452–460.
40. [40]
  H.F. Ni, L.K. Ye, P.C. Zhuge, et al., Chem. Sci. 14 (2023) 1781–1786. doi: 10.1039/d2sc05857j
41. [41]
  J.Q. Wang, G. Teri, H.F. Ni, et al., Inorg. Chem. Front. 10 (2023) 3860–3866. doi: 10.1039/d3qi00594a
42. [42]
  Z.J. Wang, H.F. Ni, T. Zhang, et al., Chem. Sci. 14 (2023) 9041–9047. doi: 10.1039/d3sc02652c
43. [43]
  Q.Q. Jia, J.Q. Luo, Z.Y. Xue, et al., Chin. Chem. Lett. 36 (2025) 110471. doi: 10.1016/j.cclet.2024.110471
44. [44]
  Q.Q. Jia, G. Teri, J.Q. Luo, et al., J. Am. Chem. Soc. 30 (2024) 21120–21128. doi: 10.1021/jacs.4c06929
45. [45]
  J.Y. Liu, M.M. Lun, Z.J. Wang, et al., Chem. Sci. 15 (2024) 16612–16617. doi: 10.1039/d4sc03571b
46. [46]
  J.Y. Liu, M. Zhu, F.W. Zhang, et al., Inorg. Chem. Front. 11 (2024) 6418–6424. doi: 10.1039/d4qi01774a
47. [47]
  J.Q. Luo, H.F. Lu, Y.J. Nie, et al., Nat. Commun. 15 (2024) 8636. doi: 10.1038/s41467-024-53031-9
48. [48]
  C.F. Wang, Y. Yang, Y. Hu, et al., Angew. Chem. Int. Ed. 63 (2024) e202413726. doi: 10.1002/anie.202413726
49. [49]
  Z.J. Wang, M.J. Shen, Z.P. Rao, et al., Inorg. Chem. Front. 11 (2024) 2290–2299. doi: 10.1039/d4qi00303a
50. [50]
  Z.X. Zhang, H. Wang, H.F. Ni, et al., Angew. Chem. Int. Ed. 63 (2024) e202319650. doi: 10.1002/anie.202319650
51. [51]
  Z.X. Zhang, H.F. Ni, J.S. Tang, et al., J. Am. Chem. Soc. 146 (2024) 27443–27450. doi: 10.1021/jacs.4c07268
52. [52]
  J. Li, T. Zhang, M.M. Lun, et al., Chem. Commun. 59 (2023) 4644. doi: 10.1039/d3cc00776f
1. [1]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2023.100212
2. [2]
  Tiantian Gong , Yanan Chen , Shuo Wang , Miao Wang , Junwei Zhao . Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties. Chinese Journal of Structural Chemistry, 2024, 43(9): 100370-100370. doi: 10.1016/j.cjsc.2024.100370
3. [3]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
4. [4]
  Yan Wang , Si-Meng Zhai , Peng Luo , Xi-Yan Dong , Jia-Yin Wang , Zhen Han , Shuang-Quan Zang . Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals. Chinese Chemical Letters, 2024, 35(11): 109493-. doi: 10.1016/j.cclet.2024.109493
5. [5]
  Xiaoqin Du , Peiyao Pan , Haoqi Li , Di Zhang , Wentao Huang , Xi Kang , Manzhou Zhu . Assessing the photoluminescence of metal nanoclusters: The individual versus the collective. Chinese Chemical Letters, 2026, 37(2): 111155-. doi: 10.1016/j.cclet.2025.111155
6. [6]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
7. [7]
  Bohan Zhang , Bingzhe Wang , Guichuan Xing , Zikang Tang , Songnan Qu . Regulation of the multi-emission centers in carbon dots via a bottom-up synthesis approach. Chinese Chemical Letters, 2024, 35(9): 109358-. doi: 10.1016/j.cclet.2023.109358
8. [8]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
9. [9]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
10. [10]
  Huanyu Liu , Gang Yu , Ruoyao Guo , Hao Qi , Jiayin Zheng , Tong Jin , Zifeng Zhao , Zuqiang Bian , Zhiwei Liu . Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes. Chinese Chemical Letters, 2025, 36(2): 110296-. doi: 10.1016/j.cclet.2024.110296
11. [11]
  Xinjuan He , Zishuo Wang , Boyang Wang , Yongqiang Zhang , Xiaokai Xu , Huijuan Cai , Siyu Lu . Recent advances in carbon dots imaging at the subcellular level: Synthesis strategies, properties, and organelle imaging. Chinese Chemical Letters, 2026, 37(2): 111957-. doi: 10.1016/j.cclet.2025.111957
12. [12]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
13. [13]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
14. [14]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
15. [15]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
16. [16]
  Guojun Zhou , Qiqiong Ren , Yanting Wang , Nan Zhang , Yilin Mao , Pei Wang , Xian-Ming Zhang . Excitation-dependent tunable photoluminescence in CsCdCl3 all-inorganic perovskite for anti-counterfeiting. Chinese Journal of Structural Chemistry, 2026, 45(2): 100774-100774. doi: 10.1016/j.cjsc.2025.100774
17. [17]
  Huan Hu , Ying Zhang , Shi-Shuang Huang , Zhi-Gang Li , Yungui Liu , Rui Feng , Wei Li . Temperature- and pressure-responsive photoluminescence in a 1D hybrid lead halide. Chinese Journal of Structural Chemistry, 2024, 43(10): 100395-100395. doi: 10.1016/j.cjsc.2024.100395
18. [18]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
19. [19]
  Mengdan Tian , Chuanzheng Zhu , Kun Luo . Hybrid organic-inorganic modification on tunnel-structured α-MnO₂ for high-performance aqueous zinc-ion battery. Chinese Chemical Letters, 2026, 37(3): 110702-. doi: 10.1016/j.cclet.2024.110702
20. [20]
  Zhiwei Sun , Bingbing Wu , Xiaoli Wang , Qingran Ding , Yanqiu Zhang , Xinjie Zhou , Sinan Tan , Ming Zhong , Sangen Zhao , Junhua Luo . Enhancing birefringence and second-harmonic generation response via aliovalent metal substitution. Chinese Journal of Structural Chemistry, 2026, 45(2): 100790-100790. doi: 10.1016/j.cjsc.2025.100790

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(90)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142