Citation: Zhen-Wei Zhang, Da-Shuai Zhang, Wei Wang, Xiao-Ting Liu, Hui Hu, Yong-Zheng Zhang, Longlong Geng, Bin Li, Yuchen Deng, Rongmin Wei, Xiuling Zhang, Yuexing Zhang, Ze Chang. Construction of through-space charge transfer donor-acceptor coordination polymers through the combination of planar electron-deficient/rich ligands[J]. Chinese Chemical Letters, ;2026, 37(3): 110710. doi: 10.1016/j.cclet.2024.110710 shu

Construction of through-space charge transfer donor-acceptor coordination polymers through the combination of planar electron-deficient/rich ligands

Zhen-Wei Zhang ^{a, d, 1} ,
Da-Shuai Zhang ^{a, d, *,} ,
Wei Wang ^{a, d} ,
Xiao-Ting Liu ^c ,
Hui Hu ^a ,
Yong-Zheng Zhang ^a ,
Longlong Geng ^{a, d} ,
Bin Li ^a ,
Yuchen Deng ^a ,
Rongmin Wei ^a ,
Xiuling Zhang ^{a, d} ,
Yuexing Zhang ^{a, *,} ,
Ze Chang ^{b, *,}

a.
Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology, Shandong Universities Engineering Research Center of Integrated Circuits Functional Materials and Expanded Applications, College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China
b.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
c.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
d.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, China

dashuai_74@163.com

zhangyuexing@sdu.edu.cn

changze@nankai.edu.cn

Received Date: 13 October 2024
Revised Date: 25 November 2024
Accepted Date: 3 December 2024
Available Online: 31 January 2025

Figures(7)

In this paper, a new series of donor-acceptor coordination polymers (DACPs), [Cd(dppz)(R-ndc)(H₂O)]_n (R = none, DZU-400; R = F, DZU-400-F; R = Br, DZU-400-Br; DZU is short for Dezhou University), [Cd(dppz)(adc)(H₂O)]_n (DZU-401), and {[Cd(dppz)(adb)_0.5(HCOO)(H₂O)]}_n (DZU-402), have been successfully constructed through the combination of electron-deficient dipyrido[3,2-a: 2′,3′-c]phenazine (dppz) as an acceptor and various dicarboxylic ligands (H₂ndc = 2,3-naphthalenedicarboxylic acid, F-H₂ndc = 6,7-difluoronaphthalene-2,3-dicarboxylic acid, Br-H₂ndc = 6,7-dibromonaphthalene-2,3-dicarboxylic acid, H₂adc = 9,10-anthracenedicarboxylic acid, and H₂adb = 4,4′-(anthracene-9,10-diyl)dibenzoic acid) with electron-rich planar aromatic rings as donors. Structural analyses reveal closely parallel arrangement of the planar acceptor and donor units in these DACPs, which could facilitate the through-space charge transfer (TSCT) interactions of the D-A systems and the corresponding luminescent properties. Interestingly, the DACPs show highly regulable donor dependent photoluminescence from blue to orange. Based on the TSCT based luminescence and the high thermal stability of the DACPs, their thermal-stimuli responsive emission properties were further studied. Photoluminescence intensity of the DACPs all present good linearity with temperature (298–473 K), as proved by variable temperature fluorescence spectra. Importantly, the temperature sensing process is reversible and recyclable, suggesting the promising applications of the DACPs as thermal-stimuli responsive materials.
- Donor-acceptor,
- Coordination polymers,
- Through-space charge transfer,
- Tunable luminescence,
- Temperature sensing
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