Citation: Zhen-Wei Zhang, Da-Shuai Zhang, Wei Wang, Xiao-Ting Liu, Hui Hu, Yong-Zheng Zhang, Longlong Geng, Bin Li, Yuchen Deng, Rongmin Wei, Xiuling Zhang, Yuexing Zhang, Ze Chang. Construction of through-space charge transfer donor-acceptor coordination polymers through the combination of planar electron-deficient/rich ligands[J]. Chinese Chemical Letters, ;2026, 37(3): 110710. doi: 10.1016/j.cclet.2024.110710 shu

Construction of through-space charge transfer donor-acceptor coordination polymers through the combination of planar electron-deficient/rich ligands

Zhen-Wei Zhang ^{a, d, 1} ,
Da-Shuai Zhang ^{a, d, *,} ,
Wei Wang ^{a, d} ,
Xiao-Ting Liu ^c ,
Hui Hu ^a ,
Yong-Zheng Zhang ^a ,
Longlong Geng ^{a, d} ,
Bin Li ^a ,
Yuchen Deng ^a ,
Rongmin Wei ^a ,
Xiuling Zhang ^{a, d} ,
Yuexing Zhang ^{a, *,} ,
Ze Chang ^{b, *,}

a.
Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology, Shandong Universities Engineering Research Center of Integrated Circuits Functional Materials and Expanded Applications, College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China
b.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
c.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
d.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, China

dashuai_74@163.com

zhangyuexing@sdu.edu.cn

changze@nankai.edu.cn

Received Date: 13 October 2024
Revised Date: 25 November 2024
Accepted Date: 3 December 2024
Available Online: 31 January 2025

Figures(7)

In this paper, a new series of donor-acceptor coordination polymers (DACPs), [Cd(dppz)(R-ndc)(H₂O)]_n (R = none, DZU-400; R = F, DZU-400-F; R = Br, DZU-400-Br; DZU is short for Dezhou University), [Cd(dppz)(adc)(H₂O)]_n (DZU-401), and {[Cd(dppz)(adb)_0.5(HCOO)(H₂O)]}_n (DZU-402), have been successfully constructed through the combination of electron-deficient dipyrido[3,2-a: 2′,3′-c]phenazine (dppz) as an acceptor and various dicarboxylic ligands (H₂ndc = 2,3-naphthalenedicarboxylic acid, F-H₂ndc = 6,7-difluoronaphthalene-2,3-dicarboxylic acid, Br-H₂ndc = 6,7-dibromonaphthalene-2,3-dicarboxylic acid, H₂adc = 9,10-anthracenedicarboxylic acid, and H₂adb = 4,4′-(anthracene-9,10-diyl)dibenzoic acid) with electron-rich planar aromatic rings as donors. Structural analyses reveal closely parallel arrangement of the planar acceptor and donor units in these DACPs, which could facilitate the through-space charge transfer (TSCT) interactions of the D-A systems and the corresponding luminescent properties. Interestingly, the DACPs show highly regulable donor dependent photoluminescence from blue to orange. Based on the TSCT based luminescence and the high thermal stability of the DACPs, their thermal-stimuli responsive emission properties were further studied. Photoluminescence intensity of the DACPs all present good linearity with temperature (298–473 K), as proved by variable temperature fluorescence spectra. Importantly, the temperature sensing process is reversible and recyclable, suggesting the promising applications of the DACPs as thermal-stimuli responsive materials.
- Donor-acceptor,
- Coordination polymers,
- Through-space charge transfer,
- Tunable luminescence,
- Temperature sensing
1. [1]
  J. Zhang, W. Xu, P. Sheng, G. Zhao, D. Zhu, Acc. Chem. Res. 50 (2017) 1654–1662. doi: 10.1021/acs.accounts.7b00124
2. [2]
  X. Li, X. Kong, G. Sun, Y. Li, eScience 3 (2023) 100171. doi: 10.1016/j.esci.2023.100171
3. [3]
  X. Wan, C. Li, M. Zhang, Y. Chen, Chem. Soc. Rev. 49 (2020) 2828–2842. doi: 10.1039/D0CS00084A
4. [4]
  L. Wang, W. Zhu, Adv. Sci. 11 (2024) 2307227. doi: 10.1002/advs.202307227
5. [5]
  S. Izumi, H.F. Higginbotham, A. Nyga, et al., J. Am. Chem. Soc. 142 (2020) 1482–1491. doi: 10.1021/jacs.9b11578
6. [6]
  Z. Chen, D. Zheng, R. Zhang, et al., Small Struct 4 (2023) 2300052. doi: 10.1002/sstr.202300052
7. [7]
  W. Tu, Z. Xiong, L. Wang, et al., Sci. China Chem. 67 (2024) 3121–3130. doi: 10.1007/s11426-024-2015-9
8. [8]
  Q. Li, Y. Wu, J. Cao, et al., Angew. Chem. Int. Ed. 61 (2022) e202202381. doi: 10.1002/anie.202202381
9. [9]
  X.F. Song, C. Jiang, N. Li, et al., Chem. Sci. 14 (2023) 12246–12254. doi: 10.1039/D3SC04264B
10. [10]
  J. Hu, Q. Li, X. Wang, et al., Angew. Chem. Int. Ed. 58 (2019) 8405–8409. doi: 10.1002/anie.201902264
11. [11]
  S. Shao, L. Wang, Acta Polym. Sin. 53 (2022) 784–795.
12. [12]
  J. Wang, J. Miao, C. Jiang, et al., Adv. Opt. Mater. 10 (2022) 2201071. doi: 10.1002/adom.202201071
13. [13]
  D.S. Zhang, Y.Z. Zhang, J. Gao, et al., Dalton Trans. 47 (2018) 14025–14032. doi: 10.1039/C8DT02858C
14. [14]
  X. Zhang, T. Li, J. Wei, et al., Dalton Trans. 51 (2022) 4790–4797. doi: 10.1039/D1DT03968G
15. [15]
  X. Zhang, R.H. Zhang, H. Hu, et al., Dalton Trans. 49 (2020) 2058–2062. doi: 10.1039/C9DT04736K
16. [16]
  X. Zhang, Y. Zhang, W. Zhou, et al., Chin. Chem. Lett. 34 (2023) 107368. doi: 10.1016/j.cclet.2022.03.091
17. [17]
  D.S. Zhang, Z.W. Zhang, F.C. Li, et al., Inorg. Chem. 63 (2024) 15915–15923. doi: 10.1021/acs.inorgchem.4c02251
18. [18]
  Y.Z. Zhang, X.D. Zhang, Y.K. Zhang, et al., Inorg. Chem. Front. 11 (2024) 8101–8109. doi: 10.1039/D4QI01796J
19. [19]
  M. Boone, F. Artizzu, J. Goura, et al., Coord. Chem. Rev. 501 (2024) 215525. doi: 10.1016/j.ccr.2023.215525
20. [20]
  Q. Zhang, C. Huang, Y. Zhang, et al., Chem. Eng. J. 482 (2024) 148854. doi: 10.1016/j.cej.2024.148854
21. [21]
  X. Li, K. Chen, R. Guo, Z. Wei, Chem. Rev. 123 (2023) 10432–10467. doi: 10.1021/acs.chemrev.3c00248
22. [22]
  N. Hanikel, M.S. Prévot, O.M. Yaghi, Nat. Nanotechnol. 15 (2020) 348–355. doi: 10.1038/s41565-020-0673-x
23. [23]
  A. Bigham, N. Islami, A. Khosravi, et al., Small 33 (2024) 2311903.
24. [24]
  R.E. Sikma, N. Katyal, S.K. Lee, et al., J. Am. Chem. Soc. 143 (2021) 13710–13720. doi: 10.1021/jacs.1c05564
25. [25]
  T. Zhao, H. Wu, X. Wen, et al., Coord. Chem. Rev. 468 (2022) 214642. doi: 10.1016/j.ccr.2022.214642
26. [26]
  S. Yuan, J.S. Qin, J. Su, et al., Angew. Chem. Int. Ed. 57 (2018) 12578–12583. doi: 10.1002/anie.201808568
27. [27]
  X. Shi, G.A. Lee, S. Liu, et al., Mater. Today 65 (2023) 207–226. doi: 10.1016/j.mattod.2023.03.004
28. [28]
  C.Y. Lee, O.K. Farha, B.J. Hong, et al., J. Am. Chem. Soc. 133 (2011) 15858–15861. doi: 10.1021/ja206029a
29. [29]
  S. Mauree, V. Villemot, M. Hamel, et al., Adv. Funct. Mater. 33 (2023) 2302877. doi: 10.1002/adfm.202302877
30. [30]
  Y. Zhao, Y. Zhang, X. Cao, J. Li, X. Hou, Chem. Eng. J. 465 (2023) 143000. doi: 10.1016/j.cej.2023.143000
31. [31]
  S.E. Gilson, M. Fairley, P. Julien, et al., J. Am. Chem. Soc. 142 (2020) 13299–13304. doi: 10.1021/jacs.0c05272
32. [32]
  X.Y. Ren, F.Y. Chen, C.H. Zhang, et al., Chem. Eur. J. 30 (2024) e202402581. doi: 10.1002/chem.202402581
33. [33]
  D.S. Zhang, Q. Gao, Z. Chang, et al., Adv. Mater. 30 (2018) 1804715. doi: 10.1002/adma.201804715
34. [34]
  X.T. Liu, K. Wang, Z. Chang, et al., Angew. Chem. Int. Ed. 58 (2019) 13997 13997. doi: 10.1002/anie.201909271
35. [35]
  X.T. Liu, W. Hua, H.X. Nie, et al., Natl. Sci. Rev. 9 (2021) nwab222.
36. [36]
  X.T. Liu, B.B. Qian, T. Zhang, et al., Matter 5 (2022) 2918–2932. doi: 10.1016/j.matt.2022.06.005
37. [37]
  B. Zhang, J. Xu, C.T. Li, et al., Angew. Chem. Int. Ed. 62 (2023) e202303262. doi: 10.1002/anie.202303262
38. [38]
  K. Prasad, D. Samanta, R. Haldar, T.K. Maji, Inorg. Chem. 57 (2018) 2953–2956. doi: 10.1021/acs.inorgchem.7b02698
1. [1]
  Yue Mao , Zhonghang Chen , Tiankai Sun , Wenyue Cui , Peng Cheng , Wei Shi . Luminescent coordination polymers with mixed carboxylate and triazole ligands for rapid detection of chloroprene metabolite. Chinese Journal of Structural Chemistry, 2024, 43(9): 100353-100353. doi: 10.1016/j.cjsc.2024.100353
2. [2]
  Xiao Yu , Dongyue Cui , Mengmeng Wang , Zhaojin Wang , Mengzhu Wang , Deshuang Tu , Vladimir Bregadze , Changsheng Lu , Qiang Zhao , Runfeng Chen , Hong Yan . Boron cluster-based TADF emitter via through-space charge transfer enabling efficient orange-red electroluminescence. Chinese Chemical Letters, 2025, 36(3): 110520-. doi: 10.1016/j.cclet.2024.110520
3. [3]
  Manlin Lu , Sheng Liao , Jiayu Li , Zidong Yu , Ningjiu Zhao , Zuoti Xie , Shunli Chen , Li Dang , Ming-De Li . Face-to-face π-π interactions and electron communication boosting efficient reverse intersystem crossing in through-space charge transfer molecules. Chinese Chemical Letters, 2025, 36(6): 110066-. doi: 10.1016/j.cclet.2024.110066
4. [4]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
5. [5]
  Shuqi Chen , Cankun Zhang , Xiaonuo Dong , Hui-Jun Zhang , Jianbin Lin . Synthesis and photophysical properties of alternating donor-acceptor conjugated nanorings. Chinese Chemical Letters, 2025, 36(6): 110354-. doi: 10.1016/j.cclet.2024.110354
6. [6]
  Xinyi Zhao , Yuai Duan , Zihan Liu , Hua Geng , Yaping Li , Zhongfeng Li , Tianyu Han . Mapping sweat pores for biometric identification based on a donor-acceptor hydrophilic fluorescent probe. Chinese Chemical Letters, 2025, 36(8): 110617-. doi: 10.1016/j.cclet.2024.110617
7. [7]
  Junying Zhang , Ruochen Li , Haihua Wang , Wenbing Kang , Xing-Dong Xu . Photo-induced tunable luminescence from an aggregated amphiphilic ethylene-pyrene derivative in aqueous media. Chinese Chemical Letters, 2024, 35(6): 109216-. doi: 10.1016/j.cclet.2023.109216
8. [8]
  Jiahao Li , Bin Pan , Anruo Mao , Likui Wang , Dawei Wang . Construction of effective and recyclable non-noble metal coordination polymers and their multiple applications in water. Chinese Chemical Letters, 2026, 37(1): 111165-. doi: 10.1016/j.cclet.2025.111165
9. [9]
  Yuliang Yang , Jingyi Zhang , Yu Wang , Huan Chen , Yijian Gao , Xiliang Li , Yingpeng Wan , Qi Zhao , Ning Li , Shengliang Li . Quintuple-acceptor engineering of anti-quenching conjugated oligomers for highly efficient NIR-Ⅱb imaging and phototheranostics. Chinese Chemical Letters, 2025, 36(11): 110834-. doi: 10.1016/j.cclet.2025.110834
10. [10]
  Jiawei Li , Cheng Chen , Mingyan Wu . Donor-acceptor type organic cocrystals for deep-red circularly polarized luminescence and two-photon excited emission. Chinese Journal of Structural Chemistry, 2025, 44(3): 100513-100513. doi: 10.1016/j.cjsc.2025.100513
11. [11]
  Yang LIU , Jin TONG , Shuyan YU . Co(Ⅱ) coordination polymers: Structural characterization and fluorescence sensing of Al³⁺ in aqueous. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2399-2408. doi: 10.11862/CJIC.20250114
12. [12]
  Xintian Qu , Zeen Liu , Zhifan Wang , Dongyan Yu , Xueqiu Huang , Jie Yang , Jiecheng Ji , Xueqin Wei , Cheng Yang . Achieving strong and tunable circularly polarized luminescence through pillar[5]arenes insertion in BINOL-Py-based chromophore. Chinese Chemical Letters, 2025, 36(11): 111024-. doi: 10.1016/j.cclet.2025.111024
13. [13]
  Rong-Nan Yi , Wei-Min He . Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions. Chinese Chemical Letters, 2024, 35(11): 110194-. doi: 10.1016/j.cclet.2024.110194
14. [14]
  Zhaoyue Lü , Tiantian Chai , Yichao Jin , Xiao Wang , Ye Zou , Lijiang Zhang , Jiankang Feng , Mengtong Zhang , Shuo Wang , Chichong Lu , Guofan Jin . Asymmetrical carbazole-benzonitrile-based TADF emitters designed by alternate donor-acceptor strategy. Chinese Chemical Letters, 2025, 36(6): 110817-. doi: 10.1016/j.cclet.2025.110817
15. [15]
  Hongping Zhao , Weiming Yuan . Merging catalytic electron donor-acceptor complex and copper catalysis: Enantioselective radical carbocyanation of alkenes. Chinese Chemical Letters, 2025, 36(10): 110894-. doi: 10.1016/j.cclet.2025.110894
16. [16]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
17. [17]
  Zhendong Liu , Sainan Liu , Bin Liu , Qi Meng , Meng Yuan , Chunzheng Yang , Yulong Bian , Ping'an Ma , Jun Lin . Fe(Ⅲ)-juglone nanoscale coordination polymers for cascade chemodynamic therapy through synergistic ferroptosis and apoptosis strategy. Chinese Chemical Letters, 2024, 35(11): 109626-. doi: 10.1016/j.cclet.2024.109626
18. [18]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
19. [19]
  Gaofeng WANG , Shuwen SUN , Lixin Meng , Dequn PENG . Syntheses and fluorescent sensing properties of two coordination polymers based on 9, 9′-dihexyl-2, 7-di(pyridin-4-yl)fluorene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 331-339. doi: 10.11862/CJIC.20250260
20. [20]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(21)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142